91高清自产国产拍,无码免费A级毛片大全,日本 欧美 国产中文字幕,99re热视频这里只有精品视频首页

正丁基锂

规格或纯度: 2.5 M in hexanes(23% solution)
有货

库存信息

关闭

库存信息

关闭
货号 (SKU) 包装规格 是否现货 价格 数量
B118688-100ml 100ml 现货 Stock Image
B118688-500ml 500ml 现货 Stock Image

基本描述

规格或纯度 2.5 M in hexanes(23% solution)
英文名称 n-Butyllithium solution
别名 1-丁基锂;正丁基锂 溶液;丁基锂
英文别名 n-BuLi;Butyl lithium;Butyllithium solution;Lithium-1-butanide;n-Butyllithium;Butyllithium
储存温度 2-8°C储存,充氩
运输条件 冰袋运输
产品介绍

本品(n-C4H9Li)为主要用于有机反应催化剂广泛用于药物中间体,液晶单体,农药及橡胶业的有机催化反应。


名称和标识符

分子式

C4H9Li

UN Number 1208
Class 3
Packing Group II
分子量 64.06

化学和物理性质

溶解性 Miscible with diethyl ether and cyclohexane.
密度 0.693
敏感性 空气和湿度敏感; 对热敏感

安全信息

一般危化品 一般危化品
象形图
ghs08

Health Hazard

ghs09

Environmental Hazard

ghs07

Harmful

ghs02

Flammable

信号词 Danger
危险声明 H315: Causes skin irritation
H373: Causes damage to organs through prolonged or repeated exposure
H411: Toxic to aquatic life with long lasting effects
H225: Highly Flammable liquid and vapor
H336: May cause drowsiness or dizziness
H304: May be fatal if swallowed and enters airways
H361: Suspected of damaging fertility or the unborn child
预防措施声明 P273,P280,P301+P310,P370+P378,P210,P405,P501,P312,P233,P240,P264,P403+P235,P260,P303+P361+P353,P201,P308+P313,P271,P241,P331,P270,P304+P340,P403+P233,P332+P313,P391,P202,P242,P243
Class 3

参考文献

1. J P Parente,P Cardon,Y Leroy,J Montreuil,B Fournet,G Ricart.  (1985-08-15)  A convenient method for methylation of glycoprotein glycans in small amounts by using lithium methylsulfinyl carbanion..  Carbohydrate research,  141  ((1)):  (41-47).  [PMID:4042112]
2. Madeleine A Jacobson,Paul G Williard.  (2002-01-05)  Synthesis of 2,3-disubstituted pyrroles from 3,N-dilithio-N-(tert-butyldimethylsilyl)-2-buten-1-amine..  The Journal of organic chemistry,  67  ((1)):  (32-37).  [PMID:11777436]
3. Jennifer L Rutherford,Daniele Hoffmann,David B Collum.  (2002-01-10)  Consequences of correlated solvation on the structures and reactivities of RLi-diamine complexes: 1,2-addition and alpha-lithiation reactions of imines by TMEDA-solvated n-butyllithium and phenyllithium..  Journal of the American Chemical Society,  124  ((2)):  (264-271).  [PMID:11782178]
4. Lawrence M Pratt,Anthony Newman,Jason St Cyr,Harry Johnson,Benjamin Miles,April Lattier,Elizabeth Austin,Susan Henderson,Brad Hershey,Ming Lin,Yuvaraju Balamraju,Laurel Sammonds,Jeffery Cheramie,Jonathan Karnes,Ellen Hymel,Brittini Woodford,Carl Carter.  (2003-08-05)  Ketone enolization with lithium dialkylamides: the effects of structure, solvation, and mixed aggregates with excess butyllithium..  The Journal of organic chemistry,  68  ((16)):  (6387-6391).  [PMID:12895075]
5. Madeleine A Jacobson,Ivan Keresztes,Paul G Williard.  (2005-03-31)  On the mechanism of THF catalyzed vinylic lithiation of allylamine derivatives: structural studies using 2-D and diffusion-ordered NMR spectroscopy..  Journal of the American Chemical Society,  127  ((13)):  (4965-4975).  [PMID:15796563]
6. Mark A Forman,Caitlin Moran,Joseph P Herres,Jason Stairs,Emily Chopko,Anthony Pozzessere,Michael Kerrigan,Carisa Kelly,Lisa Lowchyj,Kerry Salandria,Annemarie Gallo,Elizabeth Loutzenhiser.  (2007-03-16)  Generation and reactions of Pentacyclo[4.3.0.0(2,4).0(3,8).0(5,7)]non-4-ene..  The Journal of organic chemistry,  72  ((8)):  (2996-3005).  [PMID:17358080]
7. Petra R?nnholm,Mikael S?dergren,G?ran Hilmersson.  (2007-08-19)  Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde..  Organic letters,  ((19)):  (3781-3783).  [PMID:17696545]
8. Deyu Li,Chengzao Sun,Jia Liu,Russell Hopson,Weibin Li,Paul G Williard.  (2008-02-26)  Aggregation studies of complexes containing a chiral lithium amide and n-Butyllithium..  The Journal of organic chemistry,  73  ((6)):  (2373-2381).  [PMID:18294002]
9. Bernhard J Ueberbacher,Herfried Griengl,Hansj?rg Weber.  (2008-07-16)  Ortho-lithiation of free ferrocenyl alcohols: a new method for the synthesis of planar chiral ferrocene derivatives..  Chemical communications (Cambridge, England),    ((28)(28)):  (3287-3289).  [PMID:18622446]
10. Przemys?aw J Boratyński,Ilona Turowska-Tyrk,Jacek Skarzewski.  (2008-08-09)  Stereoselective C9 carbon-carbon couplings of quinine: synthesis and conformational analysis of new C2-symmetric dimers..  The Journal of organic chemistry,  73  ((18)):  (7357-7360).  [PMID:18687001]
11. Michiko Sasaki,Hidaka Ikemoto,Masatoshi Kawahata,Kentaro Yamaguchi,Kei Takeda.  (2009-03-21)  [2,3]-Wittig rearrangement of enantiomerically enriched 3-substituted 1-propenyloxy-1-phenyl-2-propen-1-yl carbanions: effect of heteroatoms and conjugating groups on planarization of an alpha-oxy-benzylcarbanion through a double bond..  Chemistry (Weinheim an der Bergstrasse, Germany),  15  ((18)):  (4663-4666).  [PMID:19301333]
12. Subramanian Devaraj,Rajendra C Jagdhane,Mysore S Shashidhar.  (2009-06-11)  Relative reactivity of hydroxyl groups in inositol derivatives: role of metal ion chelation..  Carbohydrate research,  344  ((10)):  (1159-1166).  [PMID:19508911]
13. Ke Kong,Daniel Romo,Changsuk Lee.  (2009-09-04)  Enantioselective total synthesis of the marine toxin (-)-gymnodimine employing a Barbier-type macrocyclization..  Angewandte Chemie (International ed. in English),  48  ((40)):  (7402-7405).  [PMID:19728353]
14. Michael A Tarselli,Glenn C Micalizio.  (2009-10-09)  Aliphatic imines in titanium-mediated reductive cross-coupling: unique reactivity of Ti(O-i-Pr)4/n-BuLi..  Organic letters,  11  ((20)):  (4596-4599).  [PMID:19810765]
15. Stefan Marchart,Alexey Gromov,Johann Mulzer.  (2010-02-11)  Total synthesis of the antibiotic branimycin..  Angewandte Chemie (International ed. in English),  49  ((11)):  (2050-2053).  [PMID:20146291]
16. Christian Unkelbach,Hannah S Rosenbaum,Carsten Strohmann.  (2012-09-21)  Direct benzylic metalation of a phenethylamine derivative: potassium as the key to both generation and stabilization of a labile anion..  Chemical communications (Cambridge, England),  48  ((86)):  (10612-10614).  [PMID:22992791]
17. Carl Redshaw,Oliver Rowe,David L Hughes,Anna-Marie Fuller,Ilich A Ibarra,Simon M Humphrey.  (2013-01-03)  New structural motifs in lithium and zinc calix[4]arene chemistry..  Dalton transactions (Cambridge, England : 2003),  42  ((6)):  (1983-1986).  [PMID:23280484]
18. Shigeo Hayashi, Naomi Ueno, Akio Murase, Junji Takada,.  (2014-02-13)  Design, synthesis and structure-activity relationship studies of novel and diverse cyclooxygenase-2 inhibitors as anti-inflammatory drugs..  Journal of enzyme inhibition and medicinal chemistry,  29  ((6)):  ( 846-867 ).  [PMID:24517373]
19. Mostafa Shahin,Nazila Safaei-Nikouei,Afsaneh Lavasanifar.  (2014-06-01)  Polymeric micelles for pH-responsive delivery of cisplatin..  Journal of drug targeting,  22  ((7)):  (629-637).  [PMID:24878378]
20. Hiroki Mandai,Kazuhiro Omori,Daisuke Yamamoto,Toki Tsumura,Kyouta Murota,Satoshi Yamamoto,Koichi Mitsudo,Soichiro Ibaragi,Akira Sasaki,Hiroshi Maeda,Shogo Takashiba,Seiji Suga.  (2014-08-26)  Synthetic (+)-terrein suppresses interleukin-6/soluble interleukin-6 receptor induced-secretion of vascular endothelial growth factor in human gingival fibroblasts..  Bioorganic & medicinal chemistry,  22  ((19)):  (5338-5344).  [PMID:25151086]
21. Hyojung Cha,Hyoung Nam Kim,Tae Kyu An,Moon Sung Kang,Soon-Ki Kwon,Yun-Hi Kim,Chan Eon Park.  (2014-08-26)  Effects of cyano-substituents on the molecular packing structures of conjugated polymers for bulk-heterojunction solar cells..  ACS applied materials & interfaces,  ((18)):  (15774-15782).  [PMID:25153511]
22. André M Bienfait,Christoph Sch?dle,C?cilia Maichle-M?ssmer,Karl W T?rnroos,Reiner Anwander.  (2014-10-17)  Europium bis(dimethylsilyl)amides including mixed-valent Eu3[N(SiHMe2)2]6[μ-N(SiHMe2)2]2..  Dalton transactions (Cambridge, England : 2003),  43  ((46)):  (17324-17332).  [PMID:25318830]
23. B J Reeves,D M Shircliff,J L Shott,B M Boardman.  (2014-11-13)  Synthesis and investigation of cobalt chalcogenide clusters with thienyl phosphine ligands as new acceptor materials for P3HT..  Dalton transactions (Cambridge, England : 2003),  44  ((2)):  (718-724).  [PMID:25388872]
24. Akram Ayoub,Jadson Moreira Pereira,Laurie-Eve Rioux,Sylvie L Turgeon,Martin Beaulieu,Véronique J Moulin.  (2015-01-21)  Role of seaweed laminaran from Saccharina longicruris on matrix deposition during dermal tissue-engineered production..  International journal of biological macromolecules,  75  ():  (13-20).  [PMID:25603140]
25. Paolo Boggio,Antonio Toppino,Simonetta Geninatti Crich,Diego Alberti,Domenica Marabello,Claudio Medana,Cristina Prandi,Paolo Venturello,Silvio Aime,Annamaria Deagostino.  (2015-02-04)  The hydroboration reaction as a key for a straightforward synthesis of new MRI-NCT agents..  Organic & biomolecular chemistry,  13  ((11)):  (3288-3297).  [PMID:25645198]
26. Lin Zhu,Xiao Tang,Qi Yu,Wen Lv,Hong Yan,Qiang Zhao,Wei Huang.  (2015-02-11)  Tuning the optical properties of 2-thienylpyridyl iridium complexes through carboranes and anions..  Chemistry (Weinheim an der Bergstrasse, Germany),  21  ((12)):  (4721-4730).  [PMID:25663604]
27. Torben Steenbock,Alejandra Escribano,Jürgen Heck,Carmen Herrmann.  (2015-02-24)  Photoswitching Behavior of a Cyclohexene-Bridged versus a Cyclopentene-Bridged Dithienylethene System..  Chemphyschem : a European journal of chemical physics and physical chemistry,  16  ((7)):  (1491-1501).  [PMID:25704168]
28. Xudong Guo,Xin Zhang,Shuangqing Wang,Shayu Li,Rui Hu,Yi Li,Guoqiang Yang.  (2015-03-31)  Sensing for intracellular thiols by water-insoluble two-photon fluorescent probe incorporating nanogel..  Analytica chimica acta,  869  ():  (81-88).  [PMID:25818143]
29. E Ashley Gaulding,Benjamin T Diroll,E D Goodwin,Zachary J Vrtis,Cherie R Kagan,Christopher B Murray.  (2015-03-31)  Deposition of wafer-scale single-component and binary nanocrystal superlattice thin films via dip-coating..  Advanced materials (Deerfield Beach, Fla.),  27  ((18)):  (2846-2851).  [PMID:25820834]
30. Erik Selander, Julia Kubanek, Mats Hamberg, Mats X Andersson, Gunnar Cervin, Henrik Pavia,.  (2015-04-29)  Predator lipids induce paralytic shellfish toxins in bloom-forming algae..  Proceedings of the National Academy of Sciences of the United States of America,  112  ((20)):  ( 6395-6400 ).  [PMID:25918403]
31. Shouli Ming,Shijie Zhen,Kaiwen Lin,Li Zhao,Jingkun Xu,Baoyang Lu.  (2015-05-09)  Thiadiazolo[3,4-c]pyridine as an Acceptor toward Fast-Switching Green Donor-Acceptor-Type Electrochromic Polymer with Low Bandgap..  ACS applied materials & interfaces,  ((21)):  (11089-11098).  [PMID:25955881]
32. Holger Braunschweig,Charlotte Brückner,Mehmet Ali Celik,Klaus Dück,Florian Hupp,Thomas Kramer,Johannes Krebs,Ivo Krummenacher.  (2015-06-26)  Ansa-bridged bis(benzene) titanium complexes..  Chemistry (Weinheim an der Bergstrasse, Germany),  21  ((31)):  (11056-11064).  [PMID:26111216]
33. Yuqiang Ma,Bilu Liu,Anyi Zhang,Liang Chen,Mohammad Fathi,Chenfei Shen,Ahmad N Abbas,Mingyuan Ge,Matthew Mecklenburg,Chongwu Zhou.  (2015-07-01)  Reversible Semiconducting-to-Metallic Phase Transition in Chemical Vapor Deposition Grown Monolayer WSe2 and Applications for Devices..  ACS nano,  ((7)):  (7383-7391).  [PMID:26125321]
34. Thomas Pugh, Floriana Tuna, Liviu Ungur, David Collison, Eric J L McInnes, Liviu F Chibotaru, Richard A Layfield,.  (2015-07-02)  Influencing the properties of dysprosium single-molecule magnets with phosphorus donor ligands..  Nature communications,    ():  ( 7492-7492 ).  [PMID:26130418]
35. Chee Shan Lim,Zdeněk Sofer,Vlastimil Mazánek,Martin Pumera.  (2015-07-04)  Layered titanium diboride: towards exfoliation and electrochemical applications..  Nanoscale,  ((29)):  (12527-12534).  [PMID:26137856]
36. Xiaotian Hu,Lie Chen,Licheng Tan,Yong Zhang,Lin Hu,Bing Xie,Yiwang Chen.  (2015-07-17)  Versatile MoS2 Nanosheets in ITO-Free and Semi-transparent Polymer Power-generating Glass..  Scientific reports,  ():  (12161-12161).  [PMID:26177887]
37. Shigeki Kawai,Shohei Saito,Shinichiro Osumi,Shigehiro Yamaguchi,Adam S Foster,Peter Spijker,Ernst Meyer.  (2015-08-26)  Atomically controlled substitutional boron-doping of graphene nanoribbons..  Nature communications,  ():  (8098-8098).  [PMID:26302943]
38. Debabrata Jana,Shatabdi Boxi,Partha P Parui,Binay K Ghorai.  (2015-09-09)  Planar-rotor architecture based pyrene-vinyl-tetraphenylethylene conjugated systems: photophysical properties and aggregation behavior..  Organic & biomolecular chemistry,  13  ((43)):  (10663-10674).  [PMID:26347380]

相关文档

质检报告COA

请输入批号:


你可能也会对下面相关产品感兴趣!

产品问答

产品问答

登录提交问题 Hover me 请先登录再提交问题
您提交该产品问题后,我们会在1-2个工作日内给您答复,您可以登录"我的账号",然后点击"我的产品问答"查看答案

91高清自产国产拍,无码免费A级毛片大全,日本 欧美 国产中文字幕,99re热视频这里只有精品视频首页

品牌简介

{转码主词}