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基本描述
| 规格或纯度 | 1.3M in n-hexane |
|---|---|
| 英文名称 | sec-Butyllithium solution |
| 别名 | 2-丁基锂 |
| 英文别名 | Lithium-2-butanide; s-BuLi;sec-Butyllithium |
| 储存温度 | 2-8°C储存,充氩 |
| 运输条件 | 冰袋运输 |
| 产品介绍 |
以正己烷为溶剂。一般配制成摩尔浓度为1.0M—1.3M不等的稀溶液，其质量百分比浓度在9%—13%之间，广泛用于药物中间体，液晶单体，农药及橡胶业的有机催化反应。 有机催化反应 |
名称和标识符
| 分子式 |
C4H9Li |
|---|---|
| UN Number | 1208 |
| Class | 3 |
| Packing Group | II |
| 分子量 | 64.06 |
化学和物理性质
| 密度 | 0.769 |
|---|---|
| 敏感性 | 对热,空气和湿度敏感 |
安全信息
| 一般危化品 | 一般危化品 |
|---|---|
| 象形图 |
Health Hazard 
Environmental Hazard 
Harmful 
Flammable |
| 信号词 | Danger |
| 危险声明 |
H315: Causes skin irritation H373: Causes damage to organs through prolonged or repeated exposure H411: Toxic to aquatic life with long lasting effects H225: Highly Flammable liquid and vapor H336: May cause drowsiness or dizziness H304: May be fatal if swallowed and enters airways H361: Suspected of damaging fertility or the unborn child |
| 预防措施声明 | P273,P280,P301+P310,P370+P378,P210,P405,P501,P312,P233,P240,P264,P403+P235,P260,P303+P361+P353,P201,P308+P313,P271,P241,P331,P304+P340,P403+P233,P332+P313,P391,P202,P242,P243 |
| Class | 3 |
参考文献
| 1. Arash Nikoubashman,Raleigh L Davis,Brian T Michal,Paul M Chaikin,Richard A Register,Athanassios Z Panagiotopoulos. (2014-08-12) Thin films of homopolymers and cylinder-forming diblock copolymers under shear.. ACS nano, 8 ((8)): (8015-8026). [PMID:25107567] |
| 2. Adeem Mahmood,Hamad Z Alkhathlan,Saima Parvez,Merajuddin Khan,Sohail A Shahzad. (2015-06-02) Chelation-assisted substrate-controlled asymmetric lithiation-allylboration of chiral carbamate 1,2,4-butanetriol acetonide.. Molecules (Basel, Switzerland), 20 ((6)): (9890-9905). [PMID:26029858] |
| 3. Nikos Petzetakis,Cara M Doherty,Aaron W Thornton,X Chelsea Chen,Pepa Cotanda,Anita J Hill,Nitash P Balsara. (2015-06-25) Membranes with artificial free-volume for biofuel production.. Nature communications, 6 (): (7529-7529). [PMID:26104672] |
| 4. Cheng Chen,Pullaiah Kattanguru,Olesya A Tomashenko,Rafa? Karpowicz,Gabriela Siemiaszko,Ahanjit Bhattacharya,Vinícius Calasans,Yvan Six. (2017-06-16) Synthesis of functionalised azepanes and piperidines from bicyclic halogenated aminocyclopropane derivatives.. Organic & biomolecular chemistry, 15 ((25)): (5364-5372). [PMID:28617508] |
| 5. Nicholas R Andreychuk,Tara Dickie,David J H Emslie,Hilary A Jenkins. (2018-03-16) Thorium(iv) alkyl and allyl complexes of a rigid NON-donor pincer ligand with flanking 1-adamantyl substituents.. Dalton transactions (Cambridge, England : 2003), 47 ((14)): (4866-4876). [PMID:29541736] |
| 6. Dane Christie,Richard A Register,Rodney D Priestley. (2018-05-04) Direct Measurement of the Local Glass Transition in Self-Assembled Copolymers with Nanometer Resolution.. ACS central science, 4 ((4)): (504-511). [PMID:29721533] |
| 7. Leixing Chen,Benjamin W Rawe,Kaoru Adachi,Derek P Gates. (2018-11-15) Phosphorus-Containing Block Copolymers from the Sequential Living Anionic Copolymerization of a Phosphaalkene with Methyl Methacrylate.. Chemistry (Weinheim an der Bergstrasse, Germany), 24 ((68)): (18012-18019). [PMID:30426585] |
| 8. Sneha B Chakrapani,Michael J Minkler,Bryan S Beckingham. (2019-01-19) Low-field 1H-NMR spectroscopy for compositional analysis of multicomponent polymer systems.. The Analyst, 144 ((5)): (1679-1686). [PMID:30656299] |
| 9. Leonard I Atanase,Gerard Riess. (2019-04-29) Micellization of poly(2-vinylpyrridine)-b-poly(cyclohexyl methacrylate) (P2VP-b-PCHMA) block copolymers and their interpolymer complex formation in non-aqueous medium.. Journal of colloid and interface science, 549 (): (171-178). [PMID:31029844] |
| 10. Sarah Saleem,Sofia Rangou,Clarissa Abetz,Volkan Filiz,Volker Abetz. (2020-01-01) Isoporous Membranes from Novel Polystyrene-b-poly(4-vinylpyridine)-b-poly(solketal methacrylate) (PS-b-P4VP-b-PSMA) Triblock Terpolymers and Their Post-Modification.. Polymers, 12 ((1)): (). [PMID:31888039] |
| 11. Lukasz Otulakowski,Andrzej Dworak,Aleksander Forys,Mariusz Gadzinowski,Stanislaw Slomkowski,Teresa Basinska,Barbara Trzebicka. (2020-01-17) Micellization of Polystyrene-b-Polyglycidol in Dioxane and Water/Dioxane Solutions.. Polymers, 12 ((1)): (). [PMID:31941035] |
| 12. Dimitrios Moschovas,Gkreti-Maria Manesi,Andreas Karydis-Messinis,George Zapsas,Konstantinos Ntetsikas,Nikolaos E Zafeiropoulos,Alexey A Piryazev,Edwin L Thomas,Nikos Hadjichristidis,Dimitri A Ivanov,Apostolos Avgeropoulos. (2020-08-06) Alternating Gyroid Network Structure in an ABC Miktoarm Terpolymer Comprised of Polystyrene and Two Polydienes.. Nanomaterials (Basel, Switzerland), 10 ((8)): (). [PMID:32751589] |
| 13. Qinghui Wang,Xiaoyu Ding,Yuhui Wang,Qian Du,Tianguo Xu,Bin Du,Hanchun Yao. (2018-03-20) The ratiometric fluorescence nanoparticle based on SiRB for pH detection of tumor.. European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences, 118 (): (32-39). [PMID:29551530] |
| 14. Ségolène Antoine,Karim Aissou,Muhammad Mumtaz,Siham Telitel,Gilles Pécastaings,Anne-Laure Wirotius,Cyril Brochon,Eric Cloutet,Guillaume Fleury,Georges Hadziioannou. (2018-03-27) Core-Shell Double Gyroid Structure Formed by Linear ABC Terpolymer Thin Films.. Macromolecular rapid communications, 39 ((9)): (e1800043-e1800043). [PMID:29578265] |
| 15. Elaine Rahmstorf,Volker Abetz. (2018-09-06) Supramolecular Networks from Block Copolymers Based on Styrene and Isoprene Using Hydrogen Bonding Motifs-Part 1: Synthesis and Characterization.. Materials (Basel, Switzerland), 11 ((9)): (). [PMID:30181473] |
| 16. Jason V Chari,Francesca M Ippoliti,Neil K Garg. (2019-03-07) Concise Approach to Cyclohexyne and 1,2-Cyclohexadiene Precursors.. The Journal of organic chemistry, 84 ((6)): (3652-3655). [PMID:30840455] |
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