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乙酰丙酮氧钒

规格或纯度: 95%

CAS编号: 3153-26-2
分子式: C₁₀H₁₄O₅V
分子量: 265.16
Beilstein号: 4138236
EC号: 221-590-8
MDL号: MFCD00000032
PubChem编号: 11821519

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货号 (SKU)	包装规格	是否现货	价格	数量
V109325-10g	10g	现货
V109325-25g	25g	现货
V109325-50g	50g	现货
V109325-100g	100g	现货
V109325-250g	250g	现货
V109325-500g	500g	期货

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元素分类的化合物过渡金属化合物

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基本描述

规格或纯度	95%
英文名称	Vanadyl acetylacetonate
别名	氧化二乙酰丙酮合钒
英文别名	Vanadyl triacetylacetonate Vanadium(IV)-oxy acetylacetonate VO(acac)2 Bis(2,4-pentanedionato)vanadium(IV) Oxide Acetylacetone Vanadium(IV)oxy Salt
运输条件	常规运输
产品介绍	几乎不溶于水，溶于甲醇(6.4 g/100 ml)、乙醇、醚、氯仿、丙酮、二氧六环、苯(0.9 g/100 ml)和吡啶。有机合成中的氧化催化剂；金属表面处理。

名称和标识符

EC号	221-590-8
IUPAC Name	(Z)-4-hydroxypent-3-en-2-one;oxovanadium
INCHI	InChI=1S/2C5H8O2.O.V/c21-4(6)3-5(2)7;;/h23,6H,1-2H3;;/b2*4-3-;;
InChi Key	FSJSYDFBTIVUFD-SUKNRPLKSA-N
Canonical SMILES	CC(=CC(=O)C)O.CC(=CC(=O)C)O.O=[V]
分子式	C₁₀H₁₄O₅V
PubChem CID	11821519
Beilstein号	4138236
分子量	265.16

化学和物理性质

溶解性	可溶于氯仿
密度	1
熔点	256-259°C
闪点(℉)	79 °C
闪点(℃)	79°C

安全信息

象形图	Harmful
信号词	Warning
危险声明	H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation H302: Harmful if swallowed
预防措施声明	P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P317,P337+P317,P332+P317,P319
WGK Germany	3
个人防护装备	dust mask type N95 (US),Eyeshields,Gloves

参考文献

1. N Farrell,S B Barczewski. (1987-08-01) Reactions of oxobis(acetylacetonato)-vanadium (IV) with some purine and pyrimidine bases and nucleosides.. Journal of inorganic biochemistry, 30 ((4)): (309-315). [PMID:3668527]
2. F Pautet,R Barret,M Daudon. (1985-03-01) [Oxidation of phenothiazine and its N-methyl derivative by the combination of iodobenzene and vanadium acetylacetonate].. Die Pharmazie, 40 ((3)): (202-203). [PMID:4023039]
3. Marvin W Makinen, Matthew J Brady,. (2002-01-30) Structural origins of the insulin-mimetic activity of bis(acetylacetonato)oxovanadium(IV).. The Journal of biological chemistry, 277 ((14)): ( 12215-12220 ). [PMID:11815612]
4. Devkumar Mustafi,Jesse Ward,Urszula Dougherty,Marc Bissonnette,John Hart,Stefan Vogt,Gregory S Karczmar. (2015-03-31) X-ray fluorescence microscopy demonstrates preferential accumulation of a vanadium-based magnetic resonance imaging contrast agent in murine colonic tumors.. Molecular imaging, 14 (): (). [PMID:25813904]
5. E Halevas,O Tsave,M P Yavropoulou,A Hatzidimitriou,J G Yovos,V Psycharis,C Gabriel,A Salifoglou. (2015-04-30) Design, synthesis and characterization of novel binary V(V)-Schiff base materials linked with insulin-mimetic vanadium-induced differentiation of 3T3-L1 fibroblasts to adipocytes. Structure-function correlations at the molecular level.. Journal of inorganic biochemistry, 147 (): (99-115). [PMID:25920352]
6. Taizo Yoshinaga,Masaki Saruyama,Anke Xiong,Yeilin Ham,Yongbo Kuang,Ryo Niishiro,Seiji Akiyama,Masanori Sakamoto,Takashi Hisatomi,Kazunari Domen,Toshiharu Teranishi. (2018-04-05) Boosting photocatalytic overall water splitting by Co doping into Mn3O4 nanoparticles as oxygen evolution cocatalysts.. Nanoscale, 10 ((22)): (10420-10427). [PMID:29616267]
7. Szymon Kowalski,Dariusz Wyrzykowski,Stanislaw Hac,Michal Rychlowski,Marek Witold Radomski,Iwona Inkielewicz-Stepniak. (2019-01-13) New Oxidovanadium(IV) Coordination Complex Containing 2-Methylnitrilotriacetate Ligands Induces Cell Cycle Arrest and Autophagy in Human Pancreatic Ductal Adenocarcinoma Cell Lines.. International journal of molecular sciences, 20 ((2)): (). [PMID:30634697]
8. Olga A Krysiak,Jo?o R C Junqueira,Felipe Conzuelo,Tim Bobrowski,Patrick Wilde,Andrzej Wysmolek,Wolfgang Schuhmann. (2020-02-13) Tuning Light-Driven Water Oxidation Efficiency of Molybdenum-Doped BiVO4 by Means of Multicomposite Catalysts Containing Nickel, Iron, and Chromium Oxides.. ChemPlusChem, 85 ((2)): (327-333). [PMID:32048799]
9. Mimi Liu,Cheng-Yu Lai,Meng Zhang,Daniela R Radu. (2020-12-12) Cascade synthesis and optoelectronic applications of intermediate bandgap Cu3VSe4 nanosheets.. Scientific reports, 10 ((1)): (21679-21679). [PMID:33303797]
10. Xinjian Shi,Isaac Herraiz-Cardona,Luca Bertoluzzi,Pilar Lopez-Varo,Juan Bisquert,Jong Hyeok Park,Sixto Gimenez. (2016-03-16) Understanding the synergistic effect of WO3-BiVO4 heterostructures by impedance spectroscopy.. Physical chemistry chemical physics : PCCP, 18 ((13)): (9255-9261). [PMID:26975634]
11. Jack S Shamie,Caihong Liu,Leon L Shaw,Vincent L Sprenkle. (2016-11-20) New Mechanism for the Reduction of Vanadyl Acetylacetonate to Vanadium Acetylacetonate for Room Temperature Flow Batteries.. ChemSusChem, 10 ((3)): (533-540). [PMID:27863095]
12. Tengfei Li,Takahito Kasahara,Jingfu He,Kevan E Dettelbach,Glenn M Sammis,Curtis P Berlinguette. (2017-09-01) Photoelectrochemical oxidation of organic substrates in organic media.. Nature communications, 8 ((1)): (390-390). [PMID:28855502]
13. Xinjian Shi,Samira Siahrostami,Guo-Ling Li,Yirui Zhang,Pongkarn Chakthranont,Felix Studt,Thomas F Jaramillo,Xiaolin Zheng,Jens K N?rskov. (2017-09-28) Understanding activity trends in electrochemical water oxidation to form hydrogen peroxide.. Nature communications, 8 ((1)): (701-701). [PMID:28951571]

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