Cas(7772-99-8), 无水氯化亚锡-阿拉丁试剂, 氯化亚锡;,Tin chloride,

货号 (SKU)	包装规格	是否现货	价格	数量
T121824-10g	10g	期货
T121824-50g	50g	期货

基本描述

规格或纯度	≥99.99% metals basis
英文名称	Tin(II) chloride
别名	氯化亚锡;
英文别名	Stannous chloride; Tin dichloride;
应用	已有一项研究使用氯化亚锡将羟基氧化物还原成相应的醇。氯化亚锡可用于： · 催化重氮砜、重氮氧化膦和重氮膦酸盐与醛加成，分别形成β-酮砜、β-酮膦氧化物和β-酮膦酸盐。 · 与三苯甲基氯一起用于催化甲硅烷基烯醇醚与缩醛或醛的羟醛反应以及甲硅烷基烯醇醚与 α,β-不饱和酮的迈克尔反应。 · 在钯催化剂存在下，作为烯丙醇与胺的烯丙基胺化反应的促进剂。
储存温度	充氩
运输条件	常规运输
产品介绍	氯化亚锡（SnCl2）被广泛用作还原剂。它在不同的科学领域发挥着重要作用。由于它在熔融状态下具有出色的催化作用，因此它被用于煤的加氢液化。它是用于半导体层化学气相沉积（CVD）的理想原材料。它可以通过使用其二水合物与乙酸酐反应来制备。它在酸性介质中表现出还原性。[1]它参与还原下列化合物： · 芳香族硝基化合物 · 腈 · 氰基甲硅烷基醚 · 有机叠氮化物将氰基硼氢化钠与SnCl2 以2：1的比例混合，得到还原剂混合物。该试剂可用于还原叔胺、烯丙基和苄基卤化物。已有一项研究使用氯化亚锡将羟基氧化物还原成相应的醇。氯化亚锡可用于： · 催化重氮砜、重氮氧化膦和重氮膦酸盐与醛加成，分别形成β-酮砜、β-酮膦氧化物和β-酮膦酸盐。 · 与三苯甲基氯一起用于催化甲硅烷基烯醇醚与缩醛或醛的羟醛反应以及甲硅烷基烯醇醚与 α,β-不饱和酮的迈克尔反应。 · 在钯催化剂存在下，作为烯丙醇与胺的烯丙基胺化反应的促进剂。 in(II) chloride (Stannous chloride, SnCl2) is widely employed as reducing reagent. It plays significant role in diverse fields of science. Since it exhibits superior catalytic action in molten state, it is employed for the hydroliquefaction of coals. It is a promising raw material for the chemical vapour deposition (CVD) of semiconducting layers. It can be prepared by reacting its dihydrate form with acetic anhydride. It exhibits reducing properties in acidic media. It participates in the reduction of the following compounds: · aromatic nitro compounds · nitriles · cyanosilyl ethers · organic azides On mixing sodium cyanoborohydride with SnCl2 in a 2:1 ratio, a reducing reagent mixture is obtained. This reagent is useful for the reduction of tertiary, allyl and benzyl halides.

名称和标识符

EC号	231-868-0
IUPAC Name	dichlorotin
INCHI	InChI=1S/2ClH.Sn/h2*1H;/q;;+2/p-2
InChi Key	AXZWODMDQAVCJE-UHFFFAOYSA-L
Canonical SMILES	Cl[Sn]Cl
分子式	SnCl₂
PubChem CID	24479
分子量	189.62

化学和物理性质

溶解性	Soluble in water, alkalies, alcohol, methyl ethyl ketone, methyl acetate and acetone.Insoluble in xylene.
密度	3.95
敏感性	空气及湿度敏感
沸点	652 °C
熔点	246°C

安全信息

象形图	Health Hazard Environmental Hazard Corrosive Harmful
信号词	Danger
危险声明	H319: Causes serious eye irritation H335: May cause respiratory irritation H373: Causes damage to organs through prolonged or repeated exposure H314: Causes severe skin burns and eye damage H412: Harmful to aquatic life with long lasting effects H302: Harmful if swallowed H318: Causes serious eye damage H317: May cause an allergic skin reaction H312: Harmful in contact with skin H400: Very toxic to aquatic life H332: Harmful if inhaled H410: Very toxic to aquatic life with long lasting effects H290: May be corrosive to metals H302+H332: Harmful if swallowed or if inhaled
预防措施声明	P261,P305+P351+P338,P273,P280,P302+P352,P321,P405,P501,P264,P260,P271,P270,P301+P330+P331,P304+P340,P363,P403+P233,P272,P333+P313,P362+P364,P391,P330,P234,P390,P406,P264+P265,P301+P317,P305+P354+P338,P317,P337+P317,P302+P361+P354,P316,P319
WGK Germany	1
RTECS	XP8700000
Merck Index	8783
个人防护装备	Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

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