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化学和生化试剂
高端化学
催化剂
C-H活化催化剂
三(二亚苄- base丙酮)二钯(0)

三(二亚苄- base丙酮)二钯(0)

规格或纯度: 97%

CAS编号: 51364-51-3
分子式: C₅₁H₄₂O₃Pd₂
分子量: 915.74
MDL号: MFCD00013310
PubChem编号: 9811564

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货号 (SKU)	包装规格	是否现货	价格	数量
T118850-250mg	250mg	现货
T118850-1g	1g	现货
T118850-5g	5g	现货
T118850-10g	10g	期货
T118850-25g	25g	现货

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元素分类的化合物钯催化剂

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基本描述

规格或纯度	97%
英文名称	Tris(dibenzylideneacetone)dipalladium(0)
别名	[Pd2(dba)3] x dba;三(二亚苄基茚丙酮)二钯;Pd2dba3
英文别名	[Pd2(dba)3] x dba;Pd2dba3;Pd2(dba)3;Bis[tris(dibenzylideneacetone)palladium(0)]
储存温度	2-8°C储存,避光,充氩
运输条件	冰袋运输
产品介绍	Catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes. Catalyst for the carbonylation of β,β-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids. Catalyst for cross-coupling reactions.A cycloaddition catalyst. Catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes. Catalyst for the carbonylation of β,β-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids. Catalyst for cross-coupling reactions. A cycloaddition catalyst. Product class M-C, Homogeneous Catalysts, Diene/Dienyl Ligands Reaction type Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Carbonylation, Mizoroki Heck Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Oxidation, Reduction Chemical properties Chemical formula C51H42O3Pd2 Empirical formula [Pd2(dba)3] x dba Molecular weight 915.73 Metal Pd Theoretical metal content 16 Physical state crystalline Color dark purple Applications & references Palladium catalyzed conversion of aryl chlorides and triflates to nitroaromatics. Reference: J. Am. Chem. Soc. 2009, 131, 12898 (DOI: 10.1021/ja905768k) Site selective sp3 palladium catalyzed direct arylation for a rapid derivatization of heterocyclic compounds. Reference: J. Am. Chem. Soc. 2008, 130, 3266. (DOI: 10.1021/ja710451s) One-pot ketoindoline synthesis by Palladium catalyzed γ-arylation of β,γ-unsaturated ketones. Reference: Angew. Chem. Int. Ed. 2008, 47, 177. (DOI: 10.1002/anie.200704529) Asymmetric synthesis of indolines by Palladium catalyzed arylation of β,γ-unsaturated ketones. Reference: Angew. Chem. Int. Ed. 2008, 47, 177. (DOI: 10.1002/anie.200704529) Suzuki cross coupling of aryl chorides with arylboronic acids. Reference: Angew. Chem. Int. Ed. 1998, 37, 3387. (DOI: 10.1002/(SICI)1521-3773(19981231)37:24<3387::AID-ANIE3387>3.0.CO;2-P) Efficient method for Suzuki-Miyaura reaction of lithium triisopropyl 2-pyridylborates and aryl chlorides. Reference: Angew. Chem. Int. Ed. 2008, 48, 4695. (DOI: 10.1002/anie.200801465) Palladium catalyzed aminocarbonylation of aryl halides. Reference: J. Am. Chem. Soc. 2013, 135, 16841. (DOI: 10.1021/ja4098093)

名称和标识符

IUPAC Name	(1E,4E)-1,5-diphenylpenta-1,4-dien-3-one;palladium
INCHI	InChI=1S/3C17H14O.2Pd/c318-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h31-14H;;/b3*13-11+,14-12+;;
InChi Key	CYPYTURSJDMMMP-WVCUSYJESA-N
Canonical SMILES	C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.[Pd].[Pd]
分子式	C₅₁H₄₂O₃Pd₂
关联CAS	51364-51-3,60748-47-2
PubChem CID	9811564
分子量	915.74

化学和物理性质

溶解性	Soluble in water (reacts), chloroform, DMSO (11 mM), benzene, and toluene.
敏感性	对空气、光线和湿度敏感
熔点	152-155°C

安全信息

象形图	Environmental Hazard Harmful
信号词	Warning
危险声明	H411: Toxic to aquatic life with long lasting effects H317: May cause an allergic skin reaction
预防措施声明	P261,P273,P280,P302+P352,P321,P501,P272,P333+P313,P362+P364,P391
WGK Germany	2
个人防护装备	Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

参考文献

1. Martin Arthuis,Anne Lecup,Emmanuel Roulland. (2010-09-21) Pd(0)-Catalyzed carbonylation of 1,1-dichloro-1-alkenes, a new selective access to Z-α-chloroacrylates.. Chemical communications (Cambridge, England), 46 ((41)): (7810-7812). [PMID:20852783]
2. Xiaoqiang Shen,Alan M Hyde,Stephen L Buchwald. (2010-09-23) Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.. Journal of the American Chemical Society, 132 ((40)): (14076-14078). [PMID:20857936]
3. Anant R Kapdi,Adrian C Whitwood,David C Williamson,Jason M Lynam,Michael J Burns,Thomas J Williams,Alan J Reay,Jordan Holmes,Ian J S Fairlamb. (2013-05-25) The elusive structure of Pd2(dba)3. Examination by isotopic labeling, NMR spectroscopy, and X-ray diffraction analysis: synthesis and characterization of Pd2(dba-Z)3 complexes.. Journal of the American Chemical Society, 135 ((22)): (8388-8399). [PMID:23701049]
4. Zhouen Zhang,Hisashi Doi,Hiroko Koyama,Yasuyoshi Watanabe,Masaaki Suzuki. (2014-07-06) Efficient syntheses of [11C]zidovudine and its analogs by convenient one-pot palladium(0)-copper(I) co-mediated rapid C-[11C]methylation.. Journal of labelled compounds & radiopharmaceuticals, 57 ((8)): (540-549). [PMID:24992010]
5. George R Kracke, Monika R VanGordon, Yulia V Sevryugina, Peter J Kueffer, Kuanysh Kabytaev, Satish S Jalisatgi, M Frederick Hawthorne,. (2014-11-26) Carborane-derived local anesthetics are isomer dependent.. ChemMedChem, 10 ((1)): ( 62-67 ). [PMID:25420874]
6. Michael J Ardolino,James P Morken. (2015-08-19) Branched/linear selectivity in palladium-catalyzed allyl-allyl cross-couplings: The role of ligands.. Tetrahedron, 71 ((37)): (6409-6413). [PMID:26279591]
7. Matthew H Katcher,Abigail G Doyle. (2010-11-23) Palladium-catalyzed asymmetric synthesis of allylic fluorides.. Journal of the American Chemical Society, 132 ((49)): (17402-17404). [PMID:21087003]
8. Satoshi Suetsugu,Hiromi Nishiguchi,Chihiro Tsukano,Yoshiji Takemoto. (2014-01-28) Asymmetric synthesis of (-)-aurantioclavine via palladium-catalyzed intramolecular allylic amination.. Organic letters, 16 ((3)): (996-999). [PMID:24460216]

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