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三甲基甲基环戊二烯铂(IV)

规格或纯度: 98%
有货

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库存信息

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货号 (SKU) 包装规格 是否现货 价格 数量
T118816-100mg 100mg 现货 Stock Image
T118816-500mg 500mg 现货 Stock Image
T118816-2.5g 2.5g 现货 Stock Image
大包装询价 添加到收藏夹 比较
main product photo

基本描述

规格或纯度 98%
英文名称 Trimethyl(methylcyclopentadienyl)platinum(IV)
别名 Umicore HS161;Umicore DePt01;MeCpPtMe3, HS161
英文别名 Umicore HS161;Umicore DePt01;MeCpPtMe3, HS161
储存温度 -20°C储存,充氩
运输条件 超低温冰袋运输
产品介绍


MeCpPtMe3 is a commonly used organometallic precursor for platinum.
MeCpPtMe3 was used for the deposition of ultrathin metallic layers of platinum by electron beam induced deposition, atomic sputtering.These deposits find application in microelectronics, catalysis, photonics and chemical sensing.


Application

MeCpPtMe3 is a homogeneous catalyst useful for hydrosilylation reactions.


Storage and Stability

Do not store above 4°C (39°F). Store in a tightly closed original container under dry inert gas protected from direct sunlight in a dry, cool and well-ventilated area.


Product class
M-C, Homogeneous Catalysts, Electronic Materials, PGM based Electronic Materials, Alkyl Ligands, Arene/Aryl Ligands

Reaction type
Hydrosilylation, Oxidation

Chemical properties

Chemical formula

C9H16Pt

Empirical formula

[Pt(Me)3(CpMe)]

Molecular weight

319.31

Metal

Pt

Theoretical metal content

61

Physical state

powder

Color

white


Applications & references

Platinum nanoparticles are formed by gas phase loading of the volatile platinum compounds on metal-organic frameworks and by subsequent reduction with 100 bar hydrogen. For instance, the Pt component shows high catalytic activity in solvent-free and base-free oxidation of alcohols in air at room temperature.


Reference: Chem. Eur. J. 2008, 14, 8204 (DOI: 10.1002/chem.200801043)

Trimethyl(methylcyclopentadienyl)platinum(IV) as an effective photoinitiator for hydrosilylation reactions.

Reference: Inorg. Chem. 2004, 43, 6869 (DOI: 10.1021/ic0496222)

Trimethyl(methylcyclopentadienyl)platinum(IV) is often used as ALD and CVD precursor.
Reference:? WO2010 033318 ; Electrochimica Acta 2012, 75, 101 (10.1016/j.electacta.2012.04.084)

名称和标识符

INCHI 1S/C6H7.3CH3.Pt/c1-6-4-2-3-5-6;;;;/h2,4H,3H2,1H3;3*1H3;
InChi Key AGQKROMSWCHOND-UHFFFAOYSA-N
Canonical SMILES C[Pt](C)C.C[C]1[CH][CH][CH][CH]1
分子式

C5H4CH3Pt(CH3)3
分子量 319.3

化学和物理性质

溶解性 Insoluble in water.
敏感性 对空气敏感
熔点 30-31°C

安全信息

象形图
ghs06

Toxic

ghs09

Environmental Hazard
信号词 Danger
危险声明 H317: May cause an allergic skin reaction
H400: Very toxic to aquatic life
H300+H310: Fatal if swallowed or in contact with skin
预防措施声明 P273,P280,P301+P310,P310,P264,P302+P350
WGK Germany 3
个人防护装备 Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
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