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三甲基硅咪唑

规格或纯度: 用于GC衍生化, ≥98.0%

CAS编号: 18156-74-6
分子式: C₆H₁₂N₂Si
分子量: 140.26
Beilstein号: 606148
EC号: 242-040-3
MDL号: MFCD00005280
PubChem编号: 28925

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货号 (SKU)	包装规格	是否现货	价格	数量
T118634-5ml	5ml	现货
T118634-10×1ml	10×1ml	现货
T118634-25ml	25ml	现货
T118634-100ml	100ml	现货
T118634-500ml	500ml	现货

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五元杂环化合物元素分类的化合物硅化合物

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基本描述

规格或纯度	用于GC衍生化, ≥98.0%
英文名称	1-(Trimethylsilyl)imidazole
别名	N-三甲基硅烷基咪唑
英文别名	N-Trimethylsilylimidazole N-Trimethylsilylimidazole TMSI TMS-Imidazole TMS-Imidazole
应用	高效硅烷化试剂，特别适合用于醇、酰基咪唑类的合成，在氨基存在的条件下保护羟基基团。抗菌素中间体。
储存温度	2-8°C储存
运输条件	冰袋运输
产品介绍	高效硅烷化试剂，特别适合用于醇、酰基咪唑类的合成，在氨基存在的条件下保护羟基基团。抗菌素中间体。

名称和标识符

EC号	242-040-3
IUPAC Name	imidazol-1-yl(trimethyl)silane
INCHI	InChI=1S/C6H12N2Si/c1-9(2,3)8-5-4-7-6-8/h4-6H,1-3H3
InChi Key	YKFRUJSEPGHZFJ-UHFFFAOYSA-N
Canonical SMILES	C[Si](C)(C)N1C=CN=C1
分子式	C₆H₁₂N₂Si
PubChem CID	28925
Beilstein号	606148
分子量	140.26

化学和物理性质

密度	0.957
敏感性	对潮湿敏感，对热敏感
沸点	93-94°C/14mmHg
熔点	-42°C
折光率	n20/D 1.475
闪点(℉)	42.8 °F
闪点(℃)	6 °C

安全信息

象形图	Health Hazard Environmental Hazard Corrosive Harmful Flammable
信号词	Danger
危险声明	H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation H411: Toxic to aquatic life with long lasting effects H314: Causes severe skin burns and eye damage H302: Harmful if swallowed H318: Causes serious eye damage H225: Highly Flammable liquid and vapor H400: Very toxic to aquatic life H226: Flammable liquid and vapor H410: Very toxic to aquatic life with long lasting effects H360: May damage fertility or the unborn child H360D: May damage the unborn child
预防措施声明	P261,P305+P351+P338,P273,P280,P370+P378,P210,P302+P352,P321,P405,P501,P233,P240,P264,P403+P235,P260,P303+P361+P353,P271,P241,P270,P301+P330+P331,P304+P340,P363,P403+P233,P362+P364,P391,P330,P242,P243,P203,P264+P265,P301+P317,P305+P354+P338,P318,P317,P337+
WGK Germany	3
RTECS	NI8700000
Reaxy-Rn	606148
个人防护装备	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

参考文献

1. M A Andrews. (1989-12-01) Capillary gas-chromatographic analysis of monosaccharides: improvements and comparisons using trifluoroacetylation and trimethylsilylation of sugar O-benzyl- and O-methyl-oximes.. Carbohydrate research, 194 (): (1-19). [PMID:2620295]
2. J A De Schutter,P De Moerloose. (1988-03-11) Polar contributions of the stationary phase to the reversed-phase ion-pair high-performance liquid chromatographic separation of quaternary ammonium drugs.. Journal of chromatography, 437 ((1)): (83-95). [PMID:3372675]
3. P A Andrews,N R Bachur,S M Musser,J Wright,P S Callery. (1987-08-07) Silylated N,O-ketals from the reaction of ketones with N-trimethylsilylimidazole.. Journal of chromatography, 419 (): (271-274). [PMID:3667784]
4. S Kulkarni,S Abdel-Baky,P W Le Quesne,P Vouros. (1989-01-01) Reaction of trimethylsilylimidazole with 5,10 beta-epoxy-3-ketosteroids: enolization and aromatization of the A-ring.. Steroids, 53 ((1-2)): (131-147). [PMID:2772965]
5. Qin Zhao,Fang Wei,Neng Xiao,Qiong-Wei Yu,Bi-Feng Yuan,Yu-Qi Feng. (2012-04-24) Dispersive microextraction based on water-coated Fe?O? followed by gas chromatography-mass spectrometry for determination of 3-monochloropropane-1,2-diol in edible oils.. Journal of chromatography. A, 1240 (): (45-51). [PMID:22520640]
6. Gregori Casals,Josep Marcos,Oscar J Pozo,José Alcaraz,María Jesús Martínez de Osaba,Wladimiro Jiménez. (2014-05-02) Microwave-assisted derivatization: application to steroid profiling by gas chromatography/mass spectrometry.. Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 960 (): (8-13). [PMID:24780701]
7. Toshiaki Yoshida. (2014-05-06) Biomarkers for monitoring profluthrin exposure: urinary excretion kinetics of profluthrin metabolites in rats.. Environmental toxicology and pharmacology, 37 ((3)): (1123-1128). [PMID:24792126]
8. Susanne Pribbenow,Katarina Jewgenow,Astrid Vargas,Rodrigo Serra,Sergey Naidenko,Martin Dehnhard. (2014-07-30) Validation of an enzyme immunoassay for the measurement of faecal glucocorticoid metabolites in Eurasian (Lynx lynx) and Iberian lynx (Lynx pardinus).. General and comparative endocrinology, 206 (): (166-177). [PMID:25066418]
9. Wei Wang,Jia Guo,Junnan Zhang,Jie Peng,Tianxing Liu,Zhihong Xin. (2014-10-14) Isolation, identification and antioxidant activity of bound phenolic compounds present in rice bran.. Food chemistry, 171 (): (40-49). [PMID:25308640]
10. Jessica Zampolli,Elena Collina,Marina Lasagni,Patrizia Di Gennaro. (2014-11-18) Biodegradation of variable-chain-length n-alkanes in Rhodococcus opacus R7 and the involvement of an alkane hydroxylase system in the metabolism.. AMB Express, 4 (): (73-73). [PMID:25401074]
11. Toshiaki Yoshida. (2015-01-15) 4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl alcohol as a urinary biomarker for monitoring of metofluthrin, a fluorine-containing pyrethroid, in exposed rats.. Biomarkers : biochemical indicators of exposure, response, and susceptibility to chemicals, 20 ((1)): (71-76). [PMID:25585926]
12. Takatoshi Wakabayashi,Benesh Joseph,Shuhei Yasumoto,Tomoyoshi Akashi,Toshio Aoki,Kazuo Harada,Satoru Muranaka,Takeshi Bamba,Eiichiro Fukusaki,Yasutomo Takeuchi,Koichi Yoneyama,Toshiya Muranaka,Yukihiro Sugimoto,Atsushi Okazawa. (2015-03-31) Planteose as a storage carbohydrate required for early stage of germination of Orobanche minor and its metabolism as a possible target for selective control.. Journal of experimental botany, 66 ((11)): (3085-3097). [PMID:25821071]
13. Tuula M Jyske,Jussi-Petteri Suuronen,Andrey V Pranovich,Tapio Laakso,Ugai Watanabe,Katsushi Kuroda,Hisashi Abe. (2015-06-25) Seasonal variation in formation, structure, and chemical properties of phloem in Picea abies as studied by novel microtechniques.. Planta, 242 ((3)): (613-629). [PMID:26105650]
14. K M H?ld,D G Wilkins,D J Crouch,D E Rollins,R A Maes. (1996-10-01) Detection of stanozolol in hair by negative ion chemical ionization mass spectrometry.. Journal of analytical toxicology, 20 ((6)): (345-349). [PMID:8889668]
15. Lukas Schmidt,Thomas G?en. (2015-12-19) Human metabolism of α-pinene and metabolite kinetics after oral administration.. Archives of toxicology, 91 ((2)): (677-687). [PMID:26679931]

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