四氯化钛

规格或纯度: 99.99% metals basis

CAS编号: 7550-45-0
分子式: TiCl₄
分子量: 189.68
EC号: 231-441-9
MDL号: MFCD00011267
PubChem编号: 160960

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货号 (SKU)	包装规格	是否现货
T118447-25g	25g	现货
T118447-100g	100g	现货
T118447-500g	500g	现货
T118447-1kg	1kg	现货
T118447-2.5kg	2.5kg	现货

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基本描述

规格或纯度	99.99% metals basis
英文名称	Titanium tetrachloride
别名	氯化钛;TTC
英文别名	Titanium chloride; TTC
应用	活化四氢吡咯以提高通过修正的波沃反应转化成相应的 α,α-二甲胺的转化率。促进 (S)-2-苄氧-3-戊酮在 THF 或 DME 中的高选择性羟醛缩合反应。
储存温度	2-8°C储存,充氩
运输条件	冰袋运输
产品介绍	有刺鼻的酸气味。可溶于稀盐酸、乙醇。能从空气中吸湿,在空气中发白烟，浓的水溶液稳定，但有腐蚀性，稀的水溶液能析出不溶性的盐基性氯化物。能与氯仿和四氯化碳互溶，与溴互溶而成红色溶液。能与很多含氮、含氧有机物反应而呈黄、红或褐色。遇水分解，生成难溶性的羟基氯化物和氢氧化物，在潮湿空气中分解成二氧化钛和氯化氢，发生大量烟雾，有强烈的刺激性气味。活化四氢吡咯以提高通过修正的波沃反应转化成相应的 α,α-二甲胺的转化率。促进 (S)-2-苄氧-3-戊酮在 THF 或 DME 中的高选择性羟醛缩合反应。 Usually used to activate pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines;And also Promote a highly selective aldol reaction of (S)-2-benzyloxy-3-pentanone in THF or DME.

名称和标识符

EC号	231-441-9
INCHI	1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChi Key	XJDNKRIXUMDJCW-UHFFFAOYSA-J
Canonical SMILES	Cl[Ti](Cl)(Cl)Cl
分子式	TiCl₄
UN Number	1838
PubChem CID	160960
分子量	189.68

化学和物理性质

密度	1.73
敏感性	对湿度敏感
沸点	136.4°C
熔点	-24.1°C
折光率	1.6059

安全信息

一般危化品	一般危化品
象形图	Toxic Corrosive
信号词	Danger
危险声明	H335: May cause respiratory irritation H314: Causes severe skin burns and eye damage H330: Fatal if inhaled H313: May be harmful in contact with skin
预防措施声明	P305+P351+P338,P280,P310,P405,P501,P264,P284,P303+P361+P353,P271,P301+P330+P331,P304+P340,P403+P233,P362+P364
WGK Germany	1
RTECS	XR1925000
Reaxy-Rn	3903207
Reaxys-RN link address	3903207
Merck Index	9478
个人防护装备	Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

参考文献

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