Cas(670-54-2), 四氰基乙烯-阿拉丁试剂, 四氰乙烯,Tetracyanoethylene,

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货号 (SKU)	包装规格	是否现货
T113728-1g	1g	现货
T113728-5g	5g	现货
T113728-25g	25g	现货
T113728-100g	100g	现货

货号 (SKU)

包装规格

是否现货

价格

数量

T113728-1g

现货

T113728-5g

现货

T113728-25g

25g

现货

T113728-100g

100g

现货

基本描述

规格或纯度	AR
英文名称	Tetracyanoethylene
别名	NSC 24833, TCNE, 四氰乙烯, 四氰基代乙烯
英文别名	Ethylenetetracarbonitrile; Percyanoethylene; TCNE;NSC 24833
储存温度	2-8°C储存,充氩
运输条件	冰袋运输
产品介绍	易水解，形成氢氰酸（HCN）。微溶于醚、苯和四氯化碳。于聚苯乙炔衍生物的后官能化加成，以改变透氧性作为以下反应的反应物： ? 区域选择性[2+2]环加成反应，用于生产BODIPY染料和TCBD衍生物 ? 与炔的热力加成反应 ? 与亲核试剂的一锅法反应，形成芳香族氰基乙烯基化合物 ? 合成四氰乙烯钴薄膜 ? 通过灰霉菌（Botrytis cinerea）进行生物转化 Used for postfunctional addition to polyphenylacetylene derivatives to change the oxygen permeability. Reactant for: Regioselective [2+2] cycloaddition reaction for production of BODIPY dyes and TCBD derivatives Thermal addition reaction with alkynes One-pot reactions with nucleophilic reagents forming aromatic cyanovinyl compounds Synthesis of cobalt tetracyanoethylene films Biotransformation by Botrytis cinerea

名称和标识符

EC号	211-578-0
IUPAC Name	ethene-1,1,2,2-tetracarbonitrile
INCHI	InChI=1S/C6N4/c7-1-5(2-8)6(3-9)4-10
InChi Key	NLDYACGHTUPAQU-UHFFFAOYSA-N
Canonical SMILES	C(#N)C(=C(C#N)C#N)C#N
分子式	C₆N₄
UN Number	2811
PubChem CID	12635
Beilstein号	1679885
分子量	128.09

化学和物理性质

溶解性	Soluble in methanol, benzene, toluene, water (hydrolyses to form HCN), and ether (slightly).,
密度	1.348
敏感性	对光和湿度敏感
沸点	223°C
熔点	198°C

安全信息

一般危化品	一般危化品
象形图	Toxic Harmful
信号词	Danger
危险声明	H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation H312: Harmful in contact with skin H332: Harmful if inhaled H300: Fatal if swallowed H310: Fatal in contact with skin
预防措施声明	P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P262,P361+P364,P264+P265,P301+P316,P317,P337+P317,P332+P317,P316,P319
WGK Germany	3
RTECS	KM7300000
Reaxy-Rn	506867
Merck Index	9195
个人防护装备	Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges

参考文献

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3. Gerasimos S Armatas,Mercouri G Kanatzidis. (2008-08-06) Mesoporous compound semiconductors from the reaction of metal ions with deltahedral [Ge9]4- clusters.. Journal of the American Chemical Society, 130 ((34)): (11430-11436). [PMID:18680285]
4. Erol Asker,John Masnovi. (2008-09-19) Charge-transfer complexations of 1,n-di(9-ethylcarbazol-3-yl)alkanes with tetracyanoethylene and tetranitromethane.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71 ((5)): (1973-1978). [PMID:18799351]
5. Tsuyoshi Michinobu. (2008-10-07) Click-type reaction of aromatic polyamines for improvement of thermal and optoelectronic properties.. Journal of the American Chemical Society, 130 ((43)): (14074-14075). [PMID:18834195]
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9. M A Zayed,Abeer A El-Habeeb. (2010-04-01) Spectroscopic study of the reaction mechanism of buspirone interaction with iodine and tetracyanoethylene reagents and its applications.. Drug testing and analysis, 1 ((6)): (267-274). [PMID:20355205]
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11. Erol Asker,Ece Uzkara,Orhan Zeybek. (2011-06-28) Effects of methyl substituent on the charge-transfer complexations of dicarbazolylalkanes with p-chloranil, tetracyanoethylene and tetracyanoquinodimethane.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79 ((5)): (1731-1738). [PMID:21700488]
12. Adel Mostafa,Hassan S Bazzi. (2011-07-01) Synthesis and spectroscopic studies on charge-transfer molecular complexes formed in the reaction of imidazole and 1-benzylimidazole with σ- and π-acceptors.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79 ((5)): (1613-1620). [PMID:21715216]
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15. Dane Tomasino,Jing-Yin Chen,Minesob Kim,Choong-Shik Yoo. (2013-03-15) Pressure-induced phase transition and polymerization of tetracyanoethylene (TCNE).. The Journal of chemical physics, 138 ((9)): (094506-094506). [PMID:23485312]
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四氰基乙烯

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四氰基乙烯

库存信息

库存信息

库存信息

库存信息

基本描述

名称和标识符

化学和物理性质

安全信息

参考文献

相关文档

质检报告COA

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产品问答

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