Cas(75-57-0), 四甲基氯化铵-阿拉丁试剂, 氯化四甲基铵;TMA,Tetramethylammonium chloride,

货号 (SKU)	包装规格	是否现货
T110540-100g	100g	现货
T110540-250g	250g	现货
T110540-500g	500g	现货
T110540-2.5kg	2.5kg	现货
T110540-5kg	5kg	期货

基本描述

规格或纯度	>98.0%(T)
英文名称	Tetramethylammonium chloride
别名	氯化四甲基铵;TMA
英文别名	TETRAMETHYLAMMONIUM CHLORIDE\|75-57-0\|Tetramethyl ammonium chloride\|Tetramine chloride\|USAF AN-8\|Methanaminium, N,N,N-trimethyl-, chloride\|N,N,N-Trimethylmethanaminium chloride\|9050-97-9\|tetramethylazanium chloride\|Ammonium, tetramethyl-, chloride\|tetramet
储存温度	充氩,干燥
运输条件	常规运输
产品介绍	易挥发。易吸湿。于230℃以上分解为三甲胺和氯甲烷。易溶于甲醇，溶于水和热乙醇，不溶于乙醚和氯仿。有毒，半数致死量(小鼠，腹腔)25mg/kg。有刺激性。 Tetramethylammonium chloride (TMAC) is structurally similar to alkyltrimethylammonium salts. Oxidation of TMAC yields formaldehyde and trimethlamine. It is considered as poor phase-transfer catalyst for most reactions as it is insoluble in organic media. However, it is highly suitable as phase-transfer catalyst for fluorination of chlorobenzaldehydes along with alkali metal fluorides which yield 1,2,2,2-tetrafluoroethyldifluoromethyl ether.极谱分析试剂。 Tetramethylammonium chloride (TMAC) is structurally similar to alkyltrimethylammonium salts. Oxidation of TMAC yields formaldehyde and trimethlamine. It is considered as poor phase-transfer catalyst for most reactions as it is insoluble in organic media. However, it is highly suitable as phase-transfer catalyst for fluorination of chlorobenzaldehydes along with alkali metal fluorides which yield 1,2,2,2-tetrafluoroethyldifluoromethyl ether. Tetramethylammonium chloride along with N-hydroxyphthalimide and xanthone may be used as an efficient chloride catalytic system for the aerobic oxidation of hydrocarbons to form the corresponding oxygenated compounds. It may also be used as a phase transfer catalyst for the synthesis of aryl fluorides via selective chloride/fluoride exchange reaction of activated aryl chlorides with potassium fluoride in solid-liquid phase.

名称和标识符

EC号	200-880-8
IUPAC Name	tetramethylazanium;chloride
INCHI	InChI=1S/C4H12N.ClH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChi Key	OKIZCWYLBDKLSU-UHFFFAOYSA-M
Canonical SMILES	C[N+](C)(C)C.[Cl-]
WGK Germany	1
PubChem CID	6379
分子量	109.6
Beilstein号	3911201

化学和物理性质

溶解性	Soluble in water. Insoluble in ether, and benzene
密度	1.17
敏感性	易吸湿
熔点	> 300 °C

安全和危险性（GHS）

象形图	Toxic Health Hazard Environmental Hazard Harmful
信号词	Danger
危险声明	H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation H301: Toxic if swallowed H311: Toxic in contact with skin H411: Toxic to aquatic life with long lasting effects H312: Harmful in contact with skin H300: Fatal if swallowed H370: Causes damage to organs
预防措施声明	P261,P305+P351+P338,P273,P280,P302+P352,P321,P405,P501,P264,P260,P271,P270,P304+P340,P403+P233,P362+P364,P391,P330,P361+P364,P264+P265,P301+P316,P317,P337+P317,P308+P316,P332+P317,P316,P319
WGK Germany	1
个人防护装备	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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参考文献

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四甲基氯化铵

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四甲基氯化铵

库存信息

库存信息

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基本描述

名称和标识符

化学和物理性质

安全和危险性（GHS）

相关文档

质检报告COA

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