2,2,6,6-四甲基哌啶-1-氧自由基

稳定的硝酰自由基

规格或纯度: 98%

CAS编号: 2564-83-2
分子式: C₉H₁₈NO
分子量: 156.25
Beilstein号: 1422418
EC号: 219-888-8
MDL号: MFCD00009599
PubChem编号: 2724126

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货号 (SKU)	包装规格	是否现货
T106827-5g	5g	现货
T106827-10g	10g	现货
T106827-25g	25g	现货
T106827-100g	100g	现货
T106827-500g	500g	现货
T106827-2.5kg	2.5kg	现货

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光谱试剂卡宾可控自由基聚合试剂聚合物/高分子试剂自由基

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基本描述

规格或纯度	98%
英文名称	TEMPO
别名	2,2,6,6-四甲基哌啶氧化物；2,2,6,6-四甲基哌啶-N-氧化物自由基；2,2,6,6-四甲基哌啶氧化物自由基
英文别名	TEMPO free radical; 2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical; 2,2,6,6-Tetramethylpiperidinooxy; 2,2,6,6-Tetramethylpiperidine 1-oxyl
生化机理	广泛用作自由基陷阱，与电子自旋共振光谱结合用作生物系统的结构探针，以及用作将伯醇氧化为醛的催化剂。
储存温度	2-8°C储存,充氩
运输条件	冰袋运输
备注	如果有可能，您尽量在使用的当天配置溶液，并在当天使用完它。但是，如果您需要预先配制储备溶液，我们建议您将溶液等份保存在-20°C的密封小瓶中。通常，它们最多可以使用一个月。在使用前和打开样品瓶之前，我们建议您让您的产品在室温下平衡至少1小时。需要更多关于溶解度，用法和处理的建议吗？请访问我们的常见问题（FAQ）页面以获取更多详细信息。卖完停产，不再备货
产品介绍	接触反应氧化剂，用于碘苯二乙酰氧化橙花醇生成橙花醛。总之，铜/TEMPO用于1位醇生成醛的接触反应。 Catalytic oxidant for copper-catalyzed, greener oxidation of alcohols under aerobic conditions. Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air. TEMPO (2,2,6,6-Tetramethyl-1-piperidinyloxy) was used for trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene. TEMPO-mediated oxidation was employed for the carboxylation of water-resistant nanofibrillated cellulose (NFC) films.

名称和标识符

EC号	219-888-8
INCHI	InChI=1S/C9H18NO/c1-8(2)6-5-7-9(3,4)10(8)11/h5-7H2,1-4H3
InChi Key	QYTDEUPAUMOIOP-UHFFFAOYSA-N
Canonical SMILES	CC1(CCCC(N1[O])(C)C)C
分子式	C₉H₁₈NO
UN Number	3263
PubChem CID	2724126
Beilstein号	1422418
分子量	156.25

化学和物理性质

溶解性	Soluble in all organic solvents. Insoluble in water.
密度	1
敏感性	对热敏感；对空气敏感
沸点	193°C
熔点	39°C
闪点(℉)	152.6 °F
闪点(℃)	67℃

安全信息

象形图	Corrosive Harmful
信号词	Danger
危险声明	H335: May cause respiratory irritation H314: Causes severe skin burns and eye damage H412: Harmful to aquatic life with long lasting effects H318: Causes serious eye damage
预防措施声明	P261,P273,P280,P321,P405,P501,P264,P260,P271,P301+P330+P331,P304+P340,P363,P403+P233,P264+P265,P305+P354+P338,P317,P302+P361+P354,P316,P319
WGK Germany	3
RTECS	TN8991900
Reaxy-Rn	1422418
Merck Index	9140
个人防护装备	Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges

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