首页
400-620-6333
对甲苯磺酰氯（PTSC）
规格或纯度:
CP,98%
- CAS编号: 98-59-9
- 分子式: C7H7ClO2S
- 分子量: 190.65
- Beilstein号: 607898
- EC号: 202-684-8
- MDL号: MFCD00007450
- PubChem编号: 7397
有货
切换导航
搜索
基本描述
| 规格或纯度 | CP,98% |
|---|---|
| 英文名称 | p-Toluenesulfonyl chloride(PTSC) |
| 别名 | 4-甲苯磺酰氯;PTSC |
| 英文别名 | Tosyl chloride; Toluene-4-sulfonyl chloride; PTSC |
| 应用 | 有机合成，染料、测定伯、仲胺类、酚类。 |
| 运输条件 | 常规运输 |
| 产品介绍 |
有刺激性恶臭,不溶于水，易溶于醇、醚、苯，蒸汽压 0.13kPa(88℃) 有机合成，染料、测定伯、仲胺类、酚类。 |
名称和标识符
| EC号 | 202-684-8 |
|---|---|
| IUPAC Name | 4-methylbenzenesulfonyl chloride |
| INCHI | InChI=1S/C7H7ClO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3 |
| InChi Key | YYROPELSRYBVMQ-UHFFFAOYSA-N |
| Canonical SMILES | CC1=CC=C(C=C1)S(=O)(=O)Cl |
| 分子式 |
C7H7ClO2S |
| UN Number | 3261 |
| PubChem CID | 7397 |
| Class | 8 |
| Packing Group | III |
| Beilstein号 | 607898 |
| 分子量 | 190.65 |
化学和物理性质
| 密度 | 1 |
|---|---|
| 敏感性 | 对湿度敏感 |
| 沸点 | 145°C/2.0kPa |
| 熔点 | 71°C |
| 闪点(℉) | 262.4 °F |
| 闪点(℃) | 128 °C |
安全信息
| 一般危化品 | 一般危化品 |
|---|---|
| 象形图 |
Corrosive 
Harmful |
| 信号词 | Danger |
| 危险声明 |
H315: Causes skin irritation H335: May cause respiratory irritation H314: Causes severe skin burns and eye damage H412: Harmful to aquatic life with long lasting effects H318: Causes serious eye damage H317: May cause an allergic skin reaction |
| 预防措施声明 | P261,P273,P280,P302+P352,P321,P405,P501,P264,P260,P271,P301+P330+P331,P304+P340,P363,P403+P233,P272,P333+P313,P362+P364,P264+P265,P305+P354+P338,P317,P332+P317,P302+P361+P354,P316,P319 |
| WGK Germany | 1 |
| RTECS | DB8929000 |
| Class | 8 |
| Merck Index | 9534 |
| 个人防护装备 | Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges |
参考文献
| 1. M Tomita,T Okuyama,S Watanabe,B Uno,S Kawai. (1991-05-03) High-performance liquid chromatographic determination of glyphosate and (aminomethyl)phosphonic acid in human serum after conversion into p-toluenesulphonyl derivatives.. Journal of chromatography, 566 ((1)): (239-243). [PMID:1885717] |
| 2. D Sandrock,H C Blossey,M Steinroeder,D L Munz. (1989-01-01) Contribution of different scintigraphic techniques to the management of medullary thyroid carcinoma.. Henry Ford Hospital medical journal, 37 ((3-4)): (173-174). [PMID:2576957] |
| 3. Y Tabata,S V Lonikar,F Horii,Y Ikada. (1986-05-01) Immobilization of collagen onto polymer surfaces having hydroxyl groups.. Biomaterials, 7 ((3)): (234-238). [PMID:3719044] |
| 4. J Kambayashi,T Nomura,T Fujimoto,G Kosaki. (1980-12-01) The analysis of platelet reaction, utilizing various inhibitors of platelet aggregation.. Nihon Ketsueki Gakkai zasshi : journal of Japan Haematological Society, 43 ((6)): (1145-1154). [PMID:6800180] |
| 5. . (1982-10-01) Para-toluenesulfonyl chloride.. American Industrial Hygiene Association journal, 43 ((10)): (B53-B54). [PMID:7148678] |
| 6. R J Schmidt. (1995-02-01) Tosyl chloride.. Contact dermatitis, 32 ((2)): (124-125). [PMID:7758322] |
| 7. T S Li,Y L Li,X T Liang. (1990-06-01) Studies of the synthesis of biomarkers. VII. Synthesis of 5 alpha-(17R,20R)-14,15-secocholestane.. Steroids, 55 ((6)): (263-265). [PMID:2385850] |
| 8. E V Dolgaia,S L Mironov,N Kh Pogorelaia. (1985-01-01) [Surface charge of mouse neuroblastoma cells and changes during growth and morphologic differentiation of the cell population].. Neirofiziologiia = Neurophysiology, 17 ((2)): (168-174). [PMID:4000300] |
| 9. I M Kung,F F Wang,Y C Chang,Y J Wang. (1995-05-01) Surface modifications of alginate/poly(L-lysine) microcapsular membranes with poly(ethylene glycol) and poly(vinyl alcohol).. Biomaterials, 16 ((8)): (649-655). [PMID:7548616] |
| 10. P D Robinson,D H Hua,L A Good,H Wang,C Y Meyers. (1993-06-15) (4S,5S)-4-methyl-5-phenyl-1,3-oxazolidin-2-one.. Acta crystallographica. Section C, Crystal structure communications, 49 (( Pt 6)): (1238-1240). [PMID:8397978] |
| 11. A H Ismail,A A Ismail. (2001-08-08) Synthesis of 1,2-unsaturated pyranosylphosphonate nucleosides from 3,4,6-tri-O-acetyl-D-glycal.. Die Pharmazie, 56 ((7)): (534-535). [PMID:11487970] |
| 12. Katsunori Teranishi. (2002-03-23) Direct regioselective 2-O-(p-toluenesulfonylation) of sucrose.. Carbohydrate research, 337 ((7)): (613-619). [PMID:11909594] |
| 13. Maxim V Khrolenko,Piotr P Wieczorek. (2005-10-20) Determination of glyphosate and its metabolite aminomethylphosphonic acid in fruit juices using supported-liquid membrane preconcentration method with high-performance liquid chromatography and UV detection after derivatization with p-toluenesulphonyl chloride.. Journal of chromatography. A, 1093 ((1-2)): (111-117). [PMID:16233876] |
| 14. Katarzyna Dziarkowska,Jan Ake J?nsson,Piotr P Wieczorek. (2007-12-18) Single hollow fiber SLM extraction of polyamines followed by tosyl chloride derivatization and HPLC determination.. Analytica chimica acta, 606 ((2)): (184-193). [PMID:18082649] |
| 15. Ho Law,Juan M Benito,José M García Fernández,Laszlo Jicsinszky,Serge Crouzy,Jacques Defaye. (2011-05-20) Copper(II)-complex directed regioselective mono-p-toluenesulfonylation of cyclomaltoheptaose at a primary hydroxyl group position: an NMR and molecular dynamics-aided design.. The journal of physical chemistry. B, 115 ((23)): (7524-7532). [PMID:21591775] |
| 16. Rui Ding,Yong He,Xiao Wang,Jingli Xu,Yurong Chen,Man Feng,Chuanmin Qi. (2011-07-05) Treatment of alcohols with tosyl chloride does not always lead to the formation of tosylates.. Molecules (Basel, Switzerland), 16 ((7)): (5665-5673). [PMID:21725279] |
| 17. Abdelaziz Houmam,Emad M Hamed. (2011-09-15) Application of the dissociative electron transfer theory and its extension to the case of in-cage interactions in the electrochemical reduction of arene sulfonyl chlorides.. Physical chemistry chemical physics : PCCP, 14 ((1)): (113-124). [PMID:21915407] |
| 18. Ana Bárbara Dias Pereira,Talisson Machado Veríssimo,Mariana Assíria de Oliveira,Ivaldo Ant?nio de Araujo,Ricardo José Alves,Fern?o Castro Braga. (2012-02-16) Development and validation of an HPLC-DAD method for quantification of bornesitol in extracts from Hancornia speciosa leaves after derivatization with p-toluenesulfonyl chloride.. Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 887-888 (): (133-137). [PMID:22333437] |
| 19. Haq Nawaz,Paulo Augusto R Pires,Omar A El Seoud. (2013-02-13) Kinetics and mechanism of imidazole-catalyzed acylation of cellulose in LiCl/N,N-dimethylacetamide.. Carbohydrate polymers, 92 ((2)): (997-1005). [PMID:23399120] |
| 20. Jiangxiu Niu,Aidong Wang,Zhongcheng Ke,Zubiao Zheng. (2014-05-09) Glucose transporter and folic acid receptor-mediated Pluronic P105 polymeric micelles loaded with doxorubicin for brain tumor treating.. Journal of drug targeting, 22 ((8)): (712-723). [PMID:24806516] |
| 21. André R Fajardo,Alexandre Guerry,Elizandra A Britta,Celso V Nakamura,Edvani C Muniz,Redouane Borsali,Sami Halila. (2014-05-27) Sulfated glycosaminoglycan-based block copolymer: preparation of biocompatible chondroitin sulfate-b-poly(lactic acid) micelles.. Biomacromolecules, 15 ((7)): (2691-2700). [PMID:24857763] |
| 22. Ayman M Atta,Hamad A Al-Lohedan,Abdelrahman O Ezzat. (2014-05-27) Synthesis of silver nanoparticles by green method stabilized to synthetic human stomach fluid.. Molecules (Basel, Switzerland), 19 ((5)): (6737-6753). [PMID:24858265] |
| 23. Lachlan M Blair,Elizabeth A Colby Davie,Jonathan Sperry. (2014-07-24) Total synthesis of putative montamine and a proposed structural reassignment.. Organic & biomolecular chemistry, 12 ((35)): (6878-6884). [PMID:25054306] |
| 24. Wei Li,Lili Sun,Lijun Pan,Zuopin Lan,Tao Jiang,Xiaolan Yang,Jianchun Luo,Ronghua Li,Liqing Tan,Shurong Zhang,Mingan Yu. (2014-10-14) Dendrimer-like assemblies based on organoclays as multi-host system for sustained drug delivery.. European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 88 ((3)): (706-717). [PMID:25308929] |
| 25. Tsurng-Juhn Huang,Hong Chuang,Yu-Chuan Liang,Hui-Hsien Lin,Jia-Cherng Horng,Yu-Cheng Kuo,Chia-Wen Chen,Fu-Yuan Tsai,Shih-Chieh Yen,Shih-Ching Chou,Ming-Hua Hsu. (2014-12-03) Design, synthesis, and bioevaluation of paeonol derivatives as potential anti-HBV agents.. European journal of medicinal chemistry, 90 (): (428-435). [PMID:25461891] |
| 26. Lihua Zhi,Zhiyi Wang,Jian Liu,Weisheng Liu,Haoli Zhang,Fengjuan Chen,Baodui Wang. (2015-06-24) White emission magnetic nanoparticles as chemosensors for sensitive colorimetric and ratiometric detection, and degradation of ClO? and SCN? in aqueous solutions based on a logic gate approach.. Nanoscale, 7 ((27)): (11712-11719). [PMID:26102484] |
| 27. Ho-Joong Kim,Yongju Kim,Sung Cho,Myongsoo Lee. (2015-07-07) Self-Assembly of a Tripod Aromatic Rod into Stacked Planar Networks.. Chemistry (Weinheim an der Bergstrasse, Germany), 21 ((33)): (11836-11842). [PMID:26147242] |
| 28. Dries Vandamme,Samuel Eyley,Guy Van den Mooter,Koenraad Muylaert,Wim Thielemans. (2015-07-27) Highly charged cellulose-based nanocrystals as flocculants for harvesting Chlorella vulgaris.. Bioresource technology, 194 (): (270-275). [PMID:26210139] |
| 29. Samuel Eyley,Dries Vandamme,Sanjaya Lama,Guy Van den Mooter,Koenraad Muylaert,Wim Thielemans. (2015-08-08) CO? controlled flocculation of microalgae using pH responsive cellulose nanocrystals.. Nanoscale, 7 ((34)): (14413-14421). [PMID:26248574] |
| 30. Zachary C Kennedy,Carmen E Lisowski,Dumitru S Mitaru-Berceanu,James E Hutchison. (2015-10-27) Influence of Ligand Shell Composition upon Interparticle Interactions in Multifunctional Nanoparticles.. Langmuir : the ACS journal of surfaces and colloids, 31 ((46)): (12742-12752). [PMID:26497061] |
| 31. Zrinka Rajic,Artak Tovmasyan,Otávio L de Santana,Isabelle N Peixoto,Ivan Spasojevic,Silmar A do Monte,Elizete Ventura,Júlio S Rebou?as,Ines Batinic-Haberle. (2017-01-29) Challenges encountered during development of Mn porphyrin-based, potent redox-active drug and superoxide dismutase mimic, MnTnBuOE-2-PyP. Journal of inorganic biochemistry, 169 (): (50-60). [PMID:28131001] |
| 32. Salvatore Lombardo,Samuel Eyley,Christina Schütz,Hans van Gorp,Sabine Rosenfeldt,Guy Van den Mooter,Wim Thielemans. (2017-05-13) Thermodynamic Study of the Interaction of Bovine Serum Albumin and Amino Acids with Cellulose Nanocrystals.. Langmuir : the ACS journal of surfaces and colloids, 33 ((22)): (5473-5481). [PMID:28494586] |
| 33. Vadahanambi Sridhar,Hyun Park. (2020-07-08) Extraction of Microfibrillar Cellulose From Waste Paper by NaOH/Urethane Aqueous System and Its Utility in Removal of Lead from Contaminated Water.. Materials (Basel, Switzerland), 13 ((12)): (). [PMID:32630461] |
| 34. Sandu Cibotaru,Andreea-Isabela Sandu,Dalila Belei,Luminita Marin. (2020-08-19) Water soluble PEGylated phenothiazines as valuable building blocks for bio-materials.. Materials science & engineering. C, Materials for biological applications, 116 (): (111216-111216). [PMID:32806288] |
| 35. J M Sánchez-Montero,J V Sinisterra,A Ballesteros. (1989-11-01) DNase activity of micrococcal endonuclease insolubilized on corn cob.. Applied biochemistry and biotechnology, 22 ((2)): (205-214). [PMID:2558618] |
| 36. H Egg,H Leibetseder,A Patzak,L Steinkellner. (1987-03-01) [Degradation reactions of oral antidiabetics. 2. Reaction of arylsulfonylureas with 4-toluenesulfonyl chloride].. Archiv der Pharmazie, 320 ((3)): (253-257). [PMID:3579526] |
| 37. K L Watsky,K Reynolds,D Berube,F J Bayer. (1993-10-01) Occupational contact dermatitis from tosyl chloride in a chemist.. Contact dermatitis, 29 ((4)): (211-212). [PMID:8281788] |
| 38. Hassan Y Aboul-Enein,Mohamed O I Refaie,Hayam El-Gazzar,Magda Abd El-Aziz. (2003-08-15) Chemical modification of milk xanthine oxidase with different modifiers.. Preparative biochemistry & biotechnology, 33 ((3)): (173-187). [PMID:12916809] |
| 39. Rince Wong,Sarah J Dolman. (2007-04-21) Isothiocyanates from tosyl chloride mediated decomposition of in situ generated dithiocarbamic acid salts.. The Journal of organic chemistry, 72 ((10)): (3969-3971). [PMID:17444687] |
| 40. Silje B Torsetnes,Maren S Levern?s,Marianne N Broughton,Elisabeth Paus,Trine G Halvorsen,Léon Reubsaet. (2014-06-20) Multiplexing determination of small cell lung cancer biomarkers and their isovariants in serum by immunocapture LC-MS/MS.. Analytical chemistry, 86 ((14)): (6983-6992). [PMID:24945626] |
| 41. Yubo Wang,Jose Enrico Q Quinsaat,Tomoko Ono,Masatoshi Maeki,Manabu Tokeshi,Takuya Isono,Kenji Tajima,Toshifumi Satoh,Shin-Ichiro Sato,Yutaka Miura,Takuya Yamamoto. (2020-12-02) Enhanced dispersion stability of gold nanoparticles by the physisorption of cyclic poly(ethylene glycol).. Nature communications, 11 ((1)): (6089-6089). [PMID:33257670] |
产品问答
产品问答
上海阿拉丁生化科技股份有限公司
? 2016 ALADDIN-E.COM . 版权所有,未经授权禁止拷贝本站资料,如有违反,将追究法律责任
危险品化学品经营许可证（带存储）