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三甲基膦

规格或纯度: 97%
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库存信息

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库存信息

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库存信息

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货号 (SKU) 包装规格 是否现货 价格 数量
T101175-1g
1g 现货 Stock Image
T101175-5g
5g 期货 Stock Image
T101175-25g
25g 现货 Stock Image
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膦配体

基本描述

规格或纯度 97%
英文名称 Trimethylphosphine
别名 三甲基膦|PMe3
英文别名 Trimethylphosphine|594-09-2|trimethylphosphane|Trimethyl phosphine|Phosphine, trimethyl-|Trimethylphosphorus|PMe3|Me3P|(CH3)3P|5FL6SQK9H3|MFCD00008510|trimethylphospine|EINECS 209-823-1|Trimethylphosphine, 97%|UNII-5FL6SQK9H3|CHEBI:35890|DTXSID00208120|P(
储存温度 2-8°C储存,充氩
运输条件 冰袋运输
产品介绍

富电子膦配体,可用于偶联反应。

Usually used in Mitsunobu reaction; transformation of azides into carbamates, aziridines from azidoalcohols; iminophosphoranes and aza-Wittig reaction.

Product Application
It is used in the preparation of organic phosphorus compounds and? frequently-used phosphine ligand. It? is also a highly basic ligand that forms complexes with most metals.? In addition,? it can react with bromomethyl-benzene to get benzyl-trimethyl-phosphonium; bromide.??

名称和标识符

EC号 209-823-1
IUPAC Name trimethylphosphane
INCHI InChI=1S/C3H9P/c1-4(2)3/h1-3H3
InChi Key YWWDBCBWQNCYNR-UHFFFAOYSA-N
Canonical SMILES CP(C)C
WGK Germany 3
PubChem CID 68983
UN Number 1993
分子量 76.08
Beilstein号 969138

化学和物理性质

溶解性 Soluble in water
密度 0.738
敏感性 对空气和湿度敏感.
折光率 1.428
闪点(℉) -22℉
闪点(℃) -30 °C
沸点 38-40 °C
熔点 -86°C

安全和危险性(GHS)

象形图
ghs07

Harmful

ghs02

Flammable

信号词 Danger
危险声明 H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
H225: Highly Flammable liquid and vapor
预防措施声明 P261,P305+P351+P338,P280,P370+P378,P210,P302+P352,P321,P405,P501,P233,P240,P264,P403+P235,P303+P361+P353,P271,P241,P304+P340,P403+P233,P362+P364,P242,P243,P264+P265,P337+P317,P332+P317,P319
WGK Germany 3
个人防护装备 Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

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参考文献

1. C Brunel,A Bondon,G Simonneaux.  (1992-07-06)  Electron-transfer self-exchange kinetics of trimethylphosphine horse-heart myoglobin..  Biochimica et biophysica acta,  1101  ((1)):  (73-78).  [PMID:1633178]
2. G Simonneaux,A Bondon,P Sodano.  (1990-04-19)  Proton hyperfine resonance assignments in trimethylphosphine ligated ferrimyoglobin using saturation transfer spectroscopy..  Biochimica et biophysica acta,  1038  ((2)):  (199-203).  [PMID:2158824]
3. A Bondon,G Simonneaux.  (1990-08-31)  31P-NMR investigation of trimethylphosphine binding to [alpha Fe(II), beta Mn(II)] hybrid hemoglobin. A model for partially liganded species..  Biophysical chemistry,  37  ((1-3)):  (407-411).  [PMID:2285801]
4. A Bondon,P Sodano,G Simonneaux,C T Craescu.  (1987-08-21)  Phosphines as a new structural probe of hemoglobin. 1H-NMR evidence for perturbations in the beta heme pocket induced by a thiol reagent..  Biochimica et biophysica acta,  914  ((3)):  (289-293).  [PMID:3620477]
5. C Brunel,A Bondon,G Simonneaux.  (1993-06-01)  Trimethylphosphine binding to horse-heart and sperm-whale myoglobins. Kinetics, proton magnetic resonance assignment and nuclear Overhauser effect investigation of the heme pocket..  European journal of biochemistry,  214  ((2)):  (405-414).  [PMID:8513790]
6. Izumi Sakamoto,Hiroto Kaku,Tetsuto Tsunoda.  (2003-04-04)  Preparation of (cyanomethylene)trimethylphosphorane as a new Mitsunobu-type reagent..  Chemical & pharmaceutical bulletin,  51  ((4)):  (474-476).  [PMID:12673012]
7. Alessandro A Boezio,Geoffrey Solberghe,Caroline Lauzon,André B Charette.  (2003-04-12)  Orthoacylimines: a new class of chiral auxiliaries for nucleophilic addition of organolithium reagents to imines..  The Journal of organic chemistry,  68  ((8)):  (3241-3245).  [PMID:12688797]
8. Joey L Methot,William R Roush.  (2003-10-24)  Synthetic studies toward FR182877. Remarkable solvent effect in the vinylogous morita-baylis-hillman cyclization..  Organic letters,  ((22)):  (4223-4226).  [PMID:14572290]
9. Judy Szeto,Vardhineedi Sriramurthy,Ohyun Kwon.  (2011-09-22)  Phosphine-initiated general base catalysis: facile access to benzannulated 1,3-diheteroatom five-membered rings via double-Michael reactions of allenes..  Organic letters,  13  ((20)):  (5420-5423).  [PMID:21932819]
10. William Levason,Mark E Light,Gillian Reid,Wenjian Zhang.  (2014-05-16)  Soft diphosphine and diarsine complexes of niobium(V) and tantalum(V) fluorides: synthesis, properties, structures and comparisons with the corresponding chlorides..  Dalton transactions (Cambridge, England : 2003),  43  ((25)):  (9557-9566).  [PMID:24827987]
11. Jana Leppin,Christoph F?rster,Katja Heinze.  (2014-11-14)  Molybdenum complex with bulky chelates as a functional model for molybdenum oxidases..  Inorganic chemistry,  53  ((23)):  (12416-12427).  [PMID:25394287]
12. Christiaan Ridings,Gunther G Andersson.  (2015-02-14)  Change of surface structure upon foam film formation..  Chemphyschem : a European journal of chemical physics and physical chemistry,  16  ((4)):  (733-738).  [PMID:25677129]
13. Crispin Lichtenberg,Demyan E Prokopchuk,Mario Adelhardt,Liliana Viciu,Karsten Meyer,Hansj?rg Grützmacher.  (2015-09-17)  Reactivity of an All-Ferrous Iron-Nitrogen Heterocubane under Reductive and Oxidative Conditions..  Chemistry (Weinheim an der Bergstrasse, Germany),  21  ((44)):  (15797-15805).  [PMID:26374167]
14. A Bondon,P Petrinko,P Sodano,G Simonneaux.  (1986-07-25)  31P chemical shifts as structural probes for heme environments. 31P-NMR study of the binding of trimethyl phosphine to various hemoglobins and myoglobins..  Biochimica et biophysica acta,  872  ((1-2)):  (163-166).  [PMID:3730395]
15. Raúl García-Rodríguez,Haitao Liu.  (2012-01-10)  Mechanistic study of the synthesis of CdSe nanocrystals: release of selenium..  Journal of the American Chemical Society,  134  ((3)):  (1400-1403).  [PMID:22225464]

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