Cas(57981-02-9), 邻-(2,3,4,5,6-五氟苄基)羟胺盐酸盐-阿拉丁试剂, 邻-(2,3,4,5,6-五氟苄基)羟胺盐酸盐,O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride,

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货号 (SKU)	包装规格	是否现货
P113762-250mg	250mg	现货
P113762-1g	1g	现货
P113762-5g	5g	现货

货号 (SKU)

包装规格

是否现货

价格

数量

P113762-250mg

250mg

现货

P113762-1g

现货

P113762-5g

现货

基本描述

规格或纯度	≥98%
英文名称	O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride
别名	PFBHA·HCl;O-(2,3,4,5,6-五氟苄基)羟胺盐酸盐
英文别名	PFBHA·HCl
应用	用于肟制备；质谱气相分析含羰基化合物(如酮类股醇,碳水化合物) 的灵敏性试剂
储存温度	充氩
运输条件	常规运输
产品介绍	用于肟制备；质谱气相分析含羰基化合物(如酮类股醇,碳水化合物) 的灵敏性试剂 for Oxime Preparation

名称和标识符

EC号	261-057-7
IUPAC Name	O-[(2,3,4,5,6-pentafluorophenyl)methyl]hydroxylamine;hydrochloride
INCHI	InChI=1S/C7H4F5NO.ClH/c8-3-2(1-14-13)4(9)6(11)7(12)5(3)10;/h1,13H2;1H
InChi Key	HVMVKNXIMUCYJA-UHFFFAOYSA-N
Canonical SMILES	C(C1=C(C(=C(C(=C1F)F)F)F)F)ON.Cl
分子式	C₇H₄F₅NO·HCl
PubChem CID	122307
Beilstein号	4031190
分子量	249.57

化学和物理性质

溶解性	可溶于水
熔点	212-218°C

安全信息

象形图	Harmful
信号词	Warning
危险声明	H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation
预防措施声明	P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319
WGK Germany	3
个人防护装备	Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter

参考文献

1. D A Cancilla,S S Que Hee. (1992-12-25) O-(2,3,4,5,6-pentafluorophenyl)methylhydroxylamine hydrochloride: a versatile reagent for the determination of carbonyl-containing compounds.. Journal of chromatography, 627 ((1-2)): (1-16). [PMID:1487522]
2. Y W Lin,S S Hee. (2000-11-04) Regulated workplace ketones and their interference in the PFBHA method for aldehydes.. Applied occupational and environmental hygiene, 15 ((11)): (855-862). [PMID:11062931]
3. S Friedfeld,M Fraser,D Lancaster,D Leleux,D Rehle,F Tittel. (2002-01-05) Field intercomparison of a novel optical sensor for formaldehyde quantification.. Geophysical research letters, 27 ((14)): (2093-2096). [PMID:11760771]
4. Beatriz Cancho,Francesc Ventura,M Teresa Galceran. (2002-02-01) Determination of aldehydes in drinking water using pentafluorobenzylhydroxylamine derivatization and solid-phase microextraction.. Journal of chromatography. A, 943 ((1)): (1-13). [PMID:11820270]
5. R S Spaulding,M J Charles. (2002-05-16) Comparison of methods for extraction, storage, and silylation of pentafluorobenzyl derivatives of carbonyl compounds and multi-functional carbonyl compounds.. Analytical and bioanalytical chemistry, 372 ((7-8)): (808-816). [PMID:12012193]
6. Giuseppe Pieraccini,Gianluca Bartolucci,Marco Pacenti,Stefano Dugheri,Pierpaolo Boccalon,Leonardo Focardi. (2002-06-14) Gas chromatographic determination of glutaraldehyde in the workplace atmosphere after derivatization with 0-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine on a solid-phase microextraction fibre.. Journal of chromatography. A, 955 ((1)): (117-124). [PMID:12061557]
7. Chunhui Deng,Jie Zhang,Xiaofeng Yu,Wei Zhang,Xiangmin Zhang. (2004-09-24) Determination of acetone in human breath by gas chromatography-mass spectrometry and solid-phase microextraction with on-fiber derivatization.. Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 810 ((2)): (269-275). [PMID:15380724]
8. Chunhui Deng,Ning Li,Weimin Zhu,Ji Qian,Xiaofeng Yang,Xiangmin Zhang. (2005-03-10) Rapid determination of C6-aldehydes in tomato plant emission by gas chromatography-mass spectrometry and solid-phase microextraction with on-fiber derivatization.. Journal of separation science, 28 ((2)): (172-176). [PMID:15754825]
9. J R Wells. (2005-10-06) Gas-phase chemistry of (alpha-terpineol with ozone and OH radical: rate constants and products.. Environmental science & technology, 39 ((18)): (6937-6943). [PMID:16201614]
10. E Gómez Alvarez,J Viidanoja,A Mu?oz,K Wirtz,J Hjorth. (2008-01-19) Experimental confirmation of the dicarbonyl route in the photo-oxidation of toluene and benzene.. Environmental science & technology, 41 ((24)): (8362-8369). [PMID:18200864]
11. S W Liou,C Y Chen,T T Yang,J M Lin. (2008-03-18) Determination of particulate-bound formaldehyde from burning incense by solid phase microextraction.. Bulletin of environmental contamination and toxicology, 80 ((4)): (324-328). [PMID:18344073]
12. Bruce D Pacolay,Jason E Ham,James E Slaven,J R Wells. (2008-08-09) Feasibility of detection and quantification of gas-phase carbonyls in indoor environments using PFBHA derivatization and solid-phase microextraction (SPME).. Journal of environmental monitoring : JEM, 10 ((7)): (853-860). [PMID:18688453]
13. Catherine Tessini,Niels Müller,Claudia Mardones,Dietrich Meier,Alex Berg,Dietrich von Baer. (2011-12-14) Chromatographic approaches for determination of low-molecular mass aldehydes in bio-oil.. Journal of chromatography. A, 1219 (): (154-160). [PMID:22153285]
14. Elena Gómez Alvarez,Mónica Vázquez Moreno,Sasho Gligorovski,Henri Wortham,Miguel Valcárcel Cases. (2012-01-24) Characterisation and calibration of active sampling Solid Phase Microextraction applied to sensitive determination of gaseous carbonyls.. Talanta, 88 (): (252-258). [PMID:22265495]
15. Yun-Gon Kim,Hyung-Yeon Park,Dongwon Yoo,Changmin Sung,Eunjung Song,Jae-Hun Lee,Yun-Hui Choi,Yong-Hyun Kim,Chang-Soo Lee,Kyungmoon Park,Byung-Gee Kim,Yung-Hun Yang. (2012-03-31) Selective derivatization of nucleotide diphosphate (NDP)-4-keto sugars for electrospray ionization-mass spectrometry (ESI-MS).. Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 893-894 (): (177-181). [PMID:22459405]
16. Yoichi Noya,Koh-Ichi Seki,Hiroshi Asano,Yosuke Mai,Takahiro Horinouchi,Tsunehito Higashi,Koji Terada,Chizuru Hatate,Akimasa Hoshi,Prabha Nepal,Mika Horiguchi,Yuji Kuge,Soichi Miwa. (2013-08-29) Identification of stable cytotoxic factors in the gas phase extract of cigarette smoke and pharmacological characterization of their cytotoxicity.. Toxicology, 314 ((1)): (1-10). [PMID:23981515]
17. Raya Ahmed,Kelly L Miners,Julio Lahoz-Beneytez,Rhiannon E Jones,Laureline Roger,Christina Baboonian,Yan Zhang,Eddie C Y Wang,Marc K Hellerstein,Joseph M McCune,Duncan M Baird,David A Price,Derek C Macallan,Becca Asquith,Kristin Ladell. (2020-12-17) CD57+ Memory T Cells Proliferate In\xa0Vivo.. Cell reports, 33 ((11)): (108501-108501). [PMID:33326780]
18. K T Koshy,D G Kaiser,A L VanDerSlik. (1975-02-01) 0-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride as a sensitive derivatizing agent for the electron capture gas liquid chromatographic analysis of keto steroids.. Journal of chromatographic science, 13 ((2)): (97-104). [PMID:1150849]
19. B A Gallasch,G Spiteller. (2000-10-12) Synthesis of 9,12-dioxo-10(Z)-dodecenoic acid, a new fatty acid metabolite derived from 9-hydroperoxy-10,12-octadecadienoic acid in lentil seed (Lens culinaris Medik.). Lipids, 35 ((9)): (953-960). [PMID:11026615]
20. S Strassnig,T Wenzl,E P Lankmayr. (2000-10-24) Microwave-assisted derivatization of volatile carbonyl compounds with O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine.. Journal of chromatography. A, 891 ((2)): (267-273). [PMID:11043787]
21. P Spiteller,W Kern,J Reiner,G Spiteller. (2001-04-28) Aldehydic lipid peroxidation products derived from linoleic acid.. Biochimica et biophysica acta, 1531 ((3)): (188-208). [PMID:11325611]
22. Petr Vesely,Lance Lusk,Gabriela Basarova,John Seabrooks,David Ryder. (2003-11-13) Analysis of aldehydes in beer using solid-phase microextraction with on-fiber derivatization and gas chromatography/mass spectrometry.. Journal of agricultural and food chemistry, 51 ((24)): (6941-6944). [PMID:14611150]
23. T Gabrio,A Bertsch. (2004-09-25) Determination of carbonyl compounds in pool water with O-(2,3,4,5,6-pentafluorobenzyl)hydroxyamine hydrochloride and gas chromatographic-tandem mass spectrometric analysis.. Journal of chromatography. A, 1046 ((1-2)): (293-296). [PMID:15387201]
24. Chunhui Deng,Ning Li,Xiaochuan Wang,Xiangmin Zhang,Jia Zeng. (2005-02-09) Rapid determination of acetone in human blood by derivatization with pentafluorobenzyl hydroxylamine followed by headspace liquid-phase microextraction and gas chromatography/mass spectrometry.. Rapid communications in mass spectrometry : RCM, 19 ((5)): (647-653). [PMID:15700238]
25. Fabienne Reisen,Sara M Aschmann,Roger Atkinson,Janet Arey. (2005-07-29) 1,4-hydroxycarbonyl products of the OH radical initiated reactions of C5-C8 n-alkanes in the presence of NO.. Environmental science & technology, 39 ((12)): (4447-4453). [PMID:16047780]
26. Birgit Schulze,Ryan Lauchli,Mesmin Mekem Sonwa,Annika Schmidt,Wilhelm Boland. (2005-11-26) Profiling of structurally labile oxylipins in plants by in situ derivatization with pentafluorobenzyl hydroxylamine.. Analytical biochemistry, 348 ((2)): (269-283). [PMID:16307716]
27. Riccardo Flamini,Antonio Dalla Vedova,Annarita Panighel,Nicola Perchiazzi,Stefano Ongarato. (2005-12-02) Monitoring of the principal carbonyl compounds involved in malolactic fermentation of wine by solid-phase microextraction and positive ion chemical ionization GC/MS analysis.. Journal of mass spectrometry : JMS, 40 ((12)): (1558-1564). [PMID:16320303]
28. Vicente Ferreira,Laura Culleré,Natalia Loscos,Juan Cacho. (2006-05-20) Critical aspects of the determination of pentafluorobenzyl derivatives of aldehydes by gas chromatography with electron-capture or mass spectrometric detection: Validation of an optimized strategy for the determination of oxygen-related odor-active aldehydes in wine.. Journal of chromatography. A, 1122 ((1-2)): (255-265). [PMID:16709416]
29. Julián Zapata,Laura Mateo-Vivaracho,Juan Cacho,Vicente Ferreira. (2010-01-28) Comparison of extraction techniques and mass spectrometric ionization modes in the analysis of wine volatile carbonyls.. Analytica chimica acta, 660 ((1-2)): (197-205). [PMID:20103163]

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O-(2,3,4,5,6-五氟苄基)羟胺盐酸盐

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O-(2,3,4,5,6-五氟苄基)羟胺盐酸盐

库存信息

库存信息

库存信息

基本描述

名称和标识符

化学和物理性质

安全信息

参考文献

相关文档

质检报告COA

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