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草酰氯 溶液
规格或纯度:
2.0 M in methylene chloride
- CAS编号: 79-37-8(methylene chloride)
- 分子式: C2O2Cl2
- 分子量: 126.93
- MDL号: MFCD00000704
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基本描述
| 规格或纯度 | 2.0 M in methylene chloride |
|---|---|
| 英文名称 | Oxalyl chloride solution |
| 别名 | 乙二酰二氯溶液 |
| 英文别名 | Oxalic Acid Dichloride solution；Oxalyl Dichloride solution |
| 储存温度 | 2-8°C储存,充氩 |
| 运输条件 | 冰袋运输 |
| 产品介绍 |
应用： 草酰氯一般用作二甲基亚砜活化剂 和氯化剂，将羧酸转化为酸性氯化物。 Application： Oxalyl chloride is generally used as a dimethyl sulfoxide activator and a chlorinating agent to convert carboxylic acid to acid chlorides. |
名称和标识符
| 分子式 |
C2O2Cl2 |
|---|---|
| UN Number | 3129 |
| Packing Group | I |
| 分子量 | 126.93 |
化学和物理性质
| 溶解性 | Reacts with water. |
|---|---|
| 密度 | 1.335 |
| 敏感性 | 对湿气敏感 |
安全信息
| 一般危化品 | 一般危化品 |
|---|---|
| 象形图 |
Toxic 
Health Hazard 
Corrosive 
Flammable |
| 信号词 | Danger |
| 危险声明 |
H331: Toxic if inhaled H351: Suspected of causing cancer H260: In contact with water releases flammable gases which may ignite spontaneously H314: Causes severe skin burns and eye damage H302: Harmful if swallowed H336: May cause drowsiness or dizziness H372: Causes damage to organs through prolonged or repeated exposure H370: Causes damage to organs |
| 预防措施声明 | P280,P223,P231+P232,P370+P378,P405,P501,P264,P260,P303+P361+P353,P201,P271,P270,P301+P330+P331,P363,P403+P233,P308+P311,P202,P402+P404,P335+P334,P301+P312+P330,P304+P340+P310,P305+P351+P338+P310 |
参考文献
| 1. S J Barbee,J J Stone,R J Hilaski. (1995-01-01) Acute inhalation toxicology of oxalyl chloride.. American Industrial Hygiene Association journal, 56 ((1)): (74-76). [PMID:7872205] |
| 2. Taisuke Itaya,Takehiko Iida,Itaru Natsutani,Masashi Ohba. (2002-02-05) Reactions of oxalyl chloride with 1,2-cycloalkanediols in the presence of triethylamine.. Chemical & pharmaceutical bulletin, 50 ((1)): (83-86). [PMID:11824590] |
| 3. Peter J Manley,Mark T Bilodeau. (2002-08-31) A mild method for the formation and in situ reaction of imidoyl chlorides: conversion of pyridine-1-oxides to 2-aminopyridine amides.. Organic letters, 4 ((18)): (3127-3129). [PMID:12201733] |
| 4. Beno?t Heurtaux,Claude Lion,Thierry Le Gall,Charles Mioskowski. (2005-02-12) Uncatalyzed reaction of silyl ketene acetals with oxalyl chloride: a straightforward preparation of symmetrical pulvinic acids.. The Journal of organic chemistry, 70 ((4)): (1474-1477). [PMID:15704989] |
| 5. Tsutomu Kimura,Toshiaki Murai. (2005-08-11) Enantiomerically pure P-chiral phosphinoselenoic chlorides: inversion of configuration at the P-chirogenic center in the synthesis and reaction of these substances.. Chemical communications (Cambridge, England), ((32)(32)): (4077-4079). [PMID:16091805] |
| 6. Haoyu Liu, Kevin J Edgar,. (2014-09-27) Synthesis and characterization of neutral and anionic cellulosic amphiphiles.. Carbohydrate polymers, (): ( 480-489 ). [PMID:25256510] |
| 7. Mariana C F C B Dami?o,Kerly F M Pasqualoto,Adilson K Ferreira,Sarah F Teixeira,Ricardo A Azevedo,José A M Barbuto,Fanny Palace-Berl,Gilberto C Franchi-Junior,Alexandre E Nowill,Maurício T Tavares,Roberto Parise-Filho. (2014-10-07) Novel capsaicin analogues as potential anticancer agents: synthesis, biological evaluation, and in silico approach.. Archiv der Pharmazie, 347 ((12)): (885-895). [PMID:25283529] |
| 8. T B R Papa,V D Pinho,E S P do Nascimento,W G Santos,A C B Burtoloso,L H Skibsted,D R Cardoso. (2014-11-05) Astaxanthin diferulate as a bifunctional antioxidant.. Free radical research, 49 ((1)): (102-111). [PMID:25363553] |
| 9. Homa Homayoni,Ke Jiang,Xiaoju Zou,Marius Hossu,Leila Hossein Rashidi,Wei Chen. (2015-02-01) Enhancement of protoporphyrin IX performance in aqueous solutions for photodynamic therapy.. Photodiagnosis and photodynamic therapy, 12 ((2)): (258-266). [PMID:25636780] |
| 10. Nadia Malek Saied,Najoua Mejri,Radhia El Aissi,Eric Benoist,Mouldi Saidi. (2015-05-21) Preparation and biodistribution of 1-((2-methoxyphenyl) piperazine)ferrocenecarboxamide labeled with technetium-99m as a potential brain receptor imaging agent.. European journal of medicinal chemistry, 97 (): (280-288). [PMID:25993108] |
| 11. Tejia Zhang, Lauren Barclay, Loren D Walensky, Alan Saghatelian,. (2015-06-11) Regulation of mitochondrial ceramide distribution by members of the BCL-2 family.. Journal of lipid research, 56 ((8)): ( 1501-1510 ). [PMID:26059977] |
| 12. Gordon Sproul. (2015-08-08) Abiogenic Syntheses of Lipoamino Acids and Lipopeptides and their Prebiotic Significance.. Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life, 45 ((4)): (427-437). [PMID:26248658] |
| 13. Madhumanchi Sreenu,Rachapudi Badari Narayana Prasad,Pombala Sujitha,Chityal Ganesh Kumar. (2015-11-03) Synthesis, Surface Active Properties and Cytotoxicity of Sodium N-Acyl Prolines.. Journal of oleo science, 64 ((11)): (1175-1184). [PMID:26521810] |
| 14. Ali Behbahani,Mehdi Ardjmand. (2015-11-04) Imidazole-Modified Nanoporous Silica for Lead Ion Solid Phase Extraction Prior to Determination from Industrial Wastewaters by Flame Atomic Absorption Spectrometry.. Journal of AOAC International, 98 ((5)): (1417-1422). [PMID:26525261] |
| 15. Christina Boersch,Eugen Merkul,Thomas J J Müller. (2011-09-13) Catalytic syntheses of N-heterocyclic ynones and ynediones by in situ activation of carboxylic acids with oxalyl chloride.. Angewandte Chemie (International ed. in English), 50 ((44)): (10448-10452). [PMID:21910193] |
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