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乙酰丙酮镍

规格或纯度: 95%

CAS编号: 3264-82-2
分子式: NiC₁₀H₁₄O₄
分子量: 256.91
Beilstein号: 4157970
EC号: 221-875-7
MDL号: MFCD00000024
PubChem编号: 9834912

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货号 (SKU)	包装规格	是否现货	价格	数量
N105676-10g	10g	现货
N105676-25g	25g	现货
N105676-100g	100g	现货
N105676-250g	250g	现货
N105676-500g	500g	现货

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C-X(非卤素)成键反应元素分类的化合物

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基本描述

规格或纯度	95%
英文名称	Nickel acetylacetonate
别名	双(2,4-戊二酮酸)镍(II);Ni(acac)2;2,4-戊二酮镍(II) 衍生物
英文别名	Bis(2,4-pentanedionato)nickel(II);Nickel 2,4-pentanedionate;Ni(acac)2;Acetylacetone Nickel(II) Salt Hydrate; Nickel(II) Acetylacetonate Hydrate;Bis(acetylacetonato)nickel(II);Nickel(II) acetylacetonate;Nickel(II) 2,4-pentanedionate;2,4-Pentanedione nickel
储存温度	充氩
运输条件	常规运输
产品介绍	溶于水，溶于乙醇、氯仿和苯，不溶于乙醚和轻石油有机反应的催化剂。 Catalyst and U.V. stabilizer.Nickel(II) 2,4-pentanedionate is used as a precursor to nickel bis(cyclooctadiene) catalyst. It is also used in the deposition of nickel(II) oxide thin film by sol-gel techniques on conductive glass substrates. Further, it is used in organic synthesis to produce organometals. It is associated with dimethylgold(III) acetylacetonate is used in gold on nickel plating.

名称和标识符

EC号	221-875-7
IUPAC Name	nickel(2+);(Z)-4-oxopent-2-en-2-olate
INCHI	InChI=1S/2C5H8O2.Ni/c21-4(6)3-5(2)7;/h23,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
InChi Key	BMGNSKKZFQMGDH-FDGPNNRMSA-L
Canonical SMILES	CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].[Ni+2]
分子式	NiC₁₀H₁₄O₄
关联CAS	120156-44-7
PubChem CID	9834912
Beilstein号	4157970
分子量	256.91

化学和物理性质

溶解性	Soluble in water, alcohol, toluene.
敏感性	对湿度敏感
熔点	226-235°C

安全信息

象形图	Health Hazard Harmful
信号词	Danger
危险声明	H302: Harmful if swallowed H317: May cause an allergic skin reaction H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled H350: May cause cancer
预防措施声明	P261,P280,P302+P352,P321,P405,P501,P264,P284,P270,P304+P340,P272,P333+P313,P362+P364,P330,P203,P301+P317,P318,P342+P316
WGK Germany	3
RTECS	SA2100000
Reaxy-Rn	4157970
Merck Index	6500
个人防护装备	Eyeshields,Faceshields,Gloves,type P2 (EN 143) respirator cartridges

参考文献

1. Huizhang Guo,Xiang Liu,Chengdong Bai,Yuanzhi Chen,Laisen Wang,Mingsen Zheng,Quanfeng Dong,Dong-Liang Peng. (2014-12-17) Effect of component distribution and nanoporosity in CuPt nanotubes on electrocatalysis of the oxygen reduction reaction.. ChemSusChem, 8 ((3)): (486-494). [PMID:25505002]
2. Sophie Carenco,Cheng-Hao Wu,Andrey Shavorskiy,Selim Alayoglu,Gabor A Somorjai,Hendrik Bluhm,Miquel Salmeron. (2015-03-03) Synthesis and Structural Evolution of Nickel-Cobalt Nanoparticles Under H2 and CO2.. Small (Weinheim an der Bergstrasse, Germany), 11 ((25)): (3045-3053). [PMID:25727527]
3. Kosuke Suzuki,Rinta Sato,Takuo Minato,Masahiro Shinoe,Kazuya Yamaguchi,Noritaka Mizuno. (2015-05-23) A cascade approach to hetero-pentanuclear manganese-oxide clusters in polyoxometalates and their single-molecule magnet properties.. Dalton transactions (Cambridge, England : 2003), 44 ((32)): (14220-14226). [PMID:26000986]
4. Lin Chen,Lilin Lu,Hengli Zhu,Yueguang Chen,Yu Huang,Yadong Li,Leyu Wang. (2017-01-11) Improved ethanol electrooxidation performance by shortening Pd-Ni active site distance in Pd-Ni-P nanocatalysts.. Nature communications, 8 (): (14136-14136). [PMID:28071650]
5. Maogang Gong,Jingming Zhang,Shenqiang Ren. (2018-06-05) Magnetic field-directed hybrid anisotropic nanocomposites.. Nanotechnology, 29 ((34)): (345602-345602). [PMID:29862984]
6. Huiming Li,Siqi Lu,Jingyao Sun,Jiajing Pei,Di Liu,Yanrong Xue,Junjie Mao,Wei Zhu,Zhongbin Zhuang. (2018-06-06) Phase-Controlled Synthesis of Nickel Phosphide Nanocrystals and Their Electrocatalytic Performance for the Hydrogen Evolution Reaction.. Chemistry (Weinheim an der Bergstrasse, Germany), 24 ((45)): (11748-11754). [PMID:29870074]
7. Yueping Zhao,Lu Tao,Wei Dang,Linlin Wang,Meirong Xia,Bo Wang,Minmin Liu,Faming Gao,Jiujun Zhang,Yufeng Zhao. (2019-03-29) High-Indexed PtNi Alloy Skin Spiraled on Pd Nanowires for Highly Efficient Oxygen Reduction Reaction Catalysis.. Small (Weinheim an der Bergstrasse, Germany), 15 ((17)): (e1900288-e1900288). [PMID:30920760]
8. Olli Pitk?nen,Jarkko Tolvanen,Imre Szenti,ákos Kukovecz,Jari Hannu,Heli Jantunen,Krisztian Kordas. (2019-05-07) Lightweight Hierarchical Carbon Nanocomposites with Highly Efficient and Tunable Electromagnetic Interference Shielding Properties.. ACS applied materials & interfaces, 11 ((21)): (19331-19338). [PMID:31059215]
9. Thomas Klein,Guido Kickelbick. (2020-03-12) Synthesis of submicron aluminum particles via thermal decomposition of alkyl aluminum precursors in the presence of metal seeds and their application in the formation of ruthenium aluminides.. Nanotechnology, 31 ((26)): (265605-265605). [PMID:32160597]
10. Husileng Lee,Xiujuan Wu,Licheng Sun. (2020-04-02) Homogeneous Electrochemical Water Oxidation at Neutral pH by Water-Soluble NiII Complexes Bearing Redox Non-innocent Tetraamido Macrocyclic Ligands.. ChemSusChem, 13 ((12)): (3277-3282). [PMID:32233069]
11. Bowen Yu,Shiliang Wang,Qiankun Zhang,Yuehui He,Han Huang,Jin Zou. (2014-07-24) Ni3C-assisted growth of carbon nanofibres 300 °C by thermal CVD.. Nanotechnology, 25 ((32)): (325602-325602). [PMID:25053710]
12. Jongsik Park,Young Jin Sa,Hionsuck Baik,Taehyun Kwon,Sang Hoon Joo,Kwangyeol Lee. (2017-06-10) Iridium-Based Multimetallic Nanoframe@Nanoframe Structure: An Efficient and Robust Electrocatalyst toward Oxygen Evolution Reaction.. ACS nano, 11 ((6)): (5500-5509). [PMID:28599106]
13. Jongsik Park,Mrinal Kanti Kabiraz,Hyukbu Kwon,Suhyun Park,Hionsuck Baik,Sang-Il Choi,Kwangyeol Lee. (2017-10-13) Radially Phase Segregated PtCu@PtCuNi Dendrite@Frame Nanocatalyst for the Oxygen Reduction Reaction.. ACS nano, 11 ((11)): (10844-10851). [PMID:29024581]

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