Cas(17392-83-5), D-(+)-乳酸甲酯-阿拉丁试剂, (R)-乳酸甲酯,Methyl D-(+)-Lactate,

货号 (SKU)	包装规格	是否现货
M132799-5g	5g	现货
M132799-25g	25g	现货
M132799-100g	100g	现货
M132799-500g	500g	现货

基本描述

规格或纯度	≥98.0%(GC)
英文名称	Methyl D-(+)-Lactate
别名	(R)-乳酸甲酯
英文别名	D-(+)-Lactic Acid Methyl Ester
储存温度	充氩
运输条件	常规运输

名称和标识符

IUPAC Name	methyl (2R)-2-hydroxypropanoate
INCHI	InChI=1S/C4H8O3/c1-3(5)4(6)7-2/h3,5H,1-2H3/t3-/m1/s1
InChi Key	LPEKGGXMPWTOCB-GSVOUGTGSA-N
Canonical SMILES	CC(C(=O)OC)O
分子式	C₄H₈O₃
UN Number	3272
PubChem CID	637514
Class	3
Packing Group	III
Beilstein号	3(4)449
分子量	104.11

化学和物理性质

溶解性	Completely miscible with water and decomposed by contact with water; Miscible with alcohol
密度	1.1
敏感性	对湿度敏感
沸点	144-145 °C (lit.)
折光率	1.41
比旋光度	[α]D：8°
闪点(℉)	120.2 °F
闪点(℃)	56°C(lit.)

安全信息

一般危化品	一般危化品
象形图	Harmful Flammable
信号词	Warning
危险声明	H319: Causes serious eye irritation H335: May cause respiratory irritation H226: Flammable liquid and vapor
预防措施声明	P261,P305+P351+P338,P280,P370+P378,P210,P405,P501,P233,P240,P403+P235,P303+P361+P353,P271,P241,P304+P340,P403+P233,P242,P243,P264+P265,P337+P317,P319
WGK Germany	1
Reaxy-Rn	1720588
Class	3
个人防护装备	Eyeshields， Faceshields， full-face respirator (US)， Gloves， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter

参考文献

1. C H Sotak,J R Alger. (1991-02-01) A pitfall associated with lactate detection using stimulated-echo proton spectroscopy.. Magnetic resonance in medicine, 17 ((2)): (533-538). [PMID:2062220]
2. A Knüttel,R Kimmich. (1989-02-01) Single-scan volume-selective spectral editing by homonuclear polarization transfer.. Magnetic resonance in medicine, 9 ((2)): (254-260). [PMID:2716508]
3. K Bodenh?fer,A Hierlemann,J Seemann,G Gauglitz,B Koppenhoefer,W G?pel. (1997-06-05) Chiral discrimination using piezoelectric and optical gas sensors.. Nature, 387 ((6633)): (577-580). [PMID:9177343]
4. N Oi,M Horiba,H Kitahara,T Doi,T Tani,T Sakakibara. (1980-12-19) Direct separation of alpha-hydroxycarboxylic acid ester enantiomers by gas chromatography with optically active copper(II) complexes.. Journal of chromatography, 202 ((2)): (305-308). [PMID:7462369]
5. L A Nafie,T B Freedman. (1998-12-23) Vibrational circular dichroism: an incisive tool for stereochemical applications.. Enantiomer, 3 ((4-5)): (283-297). [PMID:9861702]
6. Katia Le Barbu-Debus,Francoise Lahmani,Anne Zehnacker-Rentien,Nikhil Guchhait. (2006-02-17) Laser-induced fluorescence and single vibronic level emission spectroscopy of chiral (R)-1-aminoindan and some of its clusters in a supersonic jet.. Physical chemistry chemical physics : PCCP, 8 ((8)): (1001-1006). [PMID:16482343]
7. Thomas B Adler,Nicole Borho,Markus Reiher,Martin A Suhm. (2006-05-04) Chirality-induced switch in hydrogen-bond topology: tetrameric methyl lactate clusters in the gas phase.. Angewandte Chemie (International ed. in English), 45 ((21)): (3440-3445). [PMID:16671143]
8. Philipp Zielke,Martin A Suhm. (2006-06-16) Concerted proton motion in hydrogen-bonded trimers: a spontaneous Raman scattering perspective.. Physical chemistry chemical physics : PCCP, 8 ((24)): (2826-2830). [PMID:16775637]
9. Nicole Borho,Martin A Suhm,Katia Le Barbu-Debus,Anne Zehnacker. (2006-09-27) Intra- vs. intermolecular hydrogen bonding: dimers of alpha-hydroxyesters with methanol.. Physical chemistry chemical physics : PCCP, 8 ((38)): (4449-4460). [PMID:17001413]
10. Nicole Borho,Yunjie Xu. (2007-03-10) Rotational spectrum of a chiral alpha-hydroxyester: conformation stability and internal rotation barrier heights of methyl lactate.. Physical chemistry chemical physics : PCCP, 9 ((11)): (1324-1328). [PMID:17347705]
11. Petra Kurzawski,Anja Bogdanski,Volker Schurig,Reinhard Wimmer,Andreas Hierlemann. (2007-12-22) Opposite signs of capacitive microsensor signals upon exposure to the enantiomers of methyl propionate compounds.. Angewandte Chemie (International ed. in English), 47 ((5)): (913-916). [PMID:18098249]
12. Changhua Xu,Siu Choon Ng,Hardy Sze On Chan. (2008-07-12) Self-assembly of perfunctionalized beta-cyclodextrins on a quartz crystal microbalance for real-time chiral recognition.. Langmuir : the ACS journal of surfaces and colloids, 24 ((16)): (9118-9124). [PMID:18616230]
13. Petra Kurzawski,Anja Bogdanski,Volker Schurig,Reinhard Wimmer,Andreas Hierlemann. (2009-02-05) Direct determination of the enantiomeric purity or enantiomeric composition of methylpropionates using a single capacitive microsensor.. Analytical chemistry, 81 ((5)): (1969-1975). [PMID:19191479]
14. Esben Taarning,Shunmugavel Saravanamurugan,Martin Spangsberg Holm,Jianmin Xiong,Ryan M West,Claus Hviid Christensen. (2009-06-30) Zeolite-catalyzed isomerization of triose sugars.. ChemSusChem, 2 ((7)): (625-627). [PMID:19562790]
15. K Le Barbu-Debus,M Broquier,A Mahjoub,A Zehnacker-Rentien. (2009-12-03) Chiral recognition in jet-cooled complexes of (1R,2S)-(+)-cis-1-amino-2-indanol and methyl lactate: on the importance of the CH...pi interaction.. Physical chemistry chemical physics : PCCP, 11 ((35)): (7589-7598). [PMID:19950497]
16. Jun-Ho Choi,Sangheon Cheon,Minhaeng Cho. (2010-02-23) Calculations of vibrationally resonant sum- and difference-frequency-generation spectra of chiral molecules in solutions: three-wave-mixing vibrational optical activity.. The Journal of chemical physics, 132 ((7)): (074506-074506). [PMID:20170236]
17. Huoming Li,Jinlong Wu,Jialu Luo,Wei-Min Dai. (2010-08-31) A concise total synthesis of amphidinolide T2.. Chemistry (Weinheim an der Bergstrasse, Germany), 16 ((38)): (11530-11534). [PMID:20803588]
18. Emma L Whitelaw,Matthew G Davidson,Matthew D Jones. (2011-08-13) Group 4 salalen complexes for the production and degradation of polylactide.. Chemical communications (Cambridge, England), 47 ((36)): (10004-10006). [PMID:21833423]
19. Debora Scuderi,Katia Le Barbu-Debus,A Zehnacker. (2011-09-21) The role of weak hydrogen bonds in chiral recognition.. Physical chemistry chemical physics : PCCP, 13 ((40)): (17916-17929). [PMID:21931904]
20. Filip de Clippel,Michiel Dusselier,Ruben Van Rompaey,Pieter Vanelderen,Jan Dijkmans,Ekaterina Makshina,Lars Giebeler,Steffen Oswald,Gino V Baron,Joeri F M Denayer,Paolo P Pescarmona,Pierre A Jacobs,Bert F Sels. (2012-05-04) Fast and selective sugar conversion to alkyl lactate and lactic acid with bifunctional carbon-silica catalysts.. Journal of the American Chemical Society, 134 ((24)): (10089-10101). [PMID:22550936]
21. K Bodenh?fer,A Hierlemann,M Juza,V Schurig,W G?pel. (1997-10-10) Chiral discrimination of inhalation anesthetics and methyl propionates by thickness shear mode resonators: new insights into the mechanisms of enantioselectivity by cyclodextrins.. Analytical chemistry, 69 ((19)): (4017-4031). [PMID:9322439]
22. Nicole Borho,Martin A Suhm. (2003-12-20) Self-organization of lactates in the gas phase.. Organic & biomolecular chemistry, 1 ((23)): (4351-4358). [PMID:14685340]

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D-(+)-乳酸甲酯

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基本描述

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化学和物理性质

安全信息

参考文献

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D-(+)-乳酸甲酯

库存信息

库存信息

库存信息

库存信息

基本描述

名称和标识符

化学和物理性质

安全信息

参考文献

相关文档

质检报告COA

产品问答

产品问答

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