Cas(1313-13-9), 二氧化锰-阿拉丁试剂, 二氧化锰;氧化锰(Ⅳ)，过氧化锰,Manganese dioxide,

货号 (SKU)	包装规格	是否现货
M101135-500g	500g	现货
M101135-2.5kg	2.5kg	现货
M101135-10kg	10kg	现货

基本描述

规格或纯度	AR,85%
英文名称	Manganese dioxide
别名	氧化锰(Ⅳ)，过氧化锰
英文别名	Manganese(IV) oxide manganese binoxide
运输条件	常规运输
产品介绍	渐溶于冷盐酸并放出氯气，不溶于水、硝酸和冷硫酸。有过氧化氢或草酸存在时，能溶于稀硫酸或硝酸。致死量(兔，肌肉)45mg/kg。有氧化性。与有机物摩擦或撞击能引起燃烧。有刺激性。

名称和标识符

EC号	215-202-6
Canonical SMILES	[O-2].[O-2].[Mn+4];O=[Mn]=O
分子式	MnO₂
PubChem CID	14801
分子量	86.94

化学和物理性质

密度	5.02
熔点	535°C

安全信息

象形图	Harmful
危险声明	H302: Harmful if swallowed H332: Harmful if inhaled
WGK Germany	1
RTECS	OP0350000
个人防护装备	dust mask type N95 (US),Eyeshields,Gloves

参考文献

1. Mohammad Mahdi Najafpour. (2011-03-02) A soluble form of nano-sized colloidal manganese(IV) oxide as an efficient catalyst for water oxidation.. Dalton transactions (Cambridge, England : 2003), 40 ((15)): (3805-3807). [PMID:21359392]
2. Rui Zhai,Yazhen Wan,Lin Liu,Xiang Zhang,Weiqiang Wang,Jindun Liu,Bing Zhang. (2012-03-02) Hierarchical MnO? nanostructures: synthesis and their application in water treatment.. Water science and technology : a journal of the International Association on Water Pollution Research, 65 ((6)): (1054-1059). [PMID:22378002]
3. Xihong Lu,Teng Zhai,Xianghui Zhang,Yongqi Shen,Longyan Yuan,Bin Hu,Li Gong,Jian Chen,Yihua Gao,Jun Zhou,Yexiang Tong,Zhong Lin Wang. (2012-03-10) WO3–x@Au@MnO2 core–shell nanowires on carbon fabric for high-performance flexible supercapacitors.. Advanced materials (Deerfield Beach, Fla.), 24 ((7)): (938-944). [PMID:22403832]
4. Yoshika Sekine,Mitsuru Fukuda,Yosuke Takao,Takahiro Ozano,Hikaru Sakuramoto,Kuan Wei Wang. (2012-03-24) Simultaneous removal of formaldehyde and benzene in indoor air with a combination of sorption- and decomposition-type air filters.. Environmental technology, 33 ((15-16)): (1983-1989). [PMID:22439587]
5. Yong Long,Jun-feng Hui,Peng-peng Wang,Shi Hu,Biao Xu,Guo-lei Xiang,Jing Zhuang,Xing-qiang Lü,Xun Wang. (2012-05-04) α-MnO2 nanowires as building blocks for the construction of 3D macro-assemblies.. Chemical communications (Cambridge, England), 48 ((47)): (5925-5927). [PMID:22552214]
6. Xin Zhao,Lili Zhang,Shanthi Murali,Meryl D Stoller,Qinghua Zhang,Yanwu Zhu,Rodney S Ruoff. (2012-05-05) Incorporation of manganese dioxide within ultraporous activated graphene for high-performance electrochemical capacitors.. ACS nano, 6 ((6)): (5404-5412). [PMID:22554307]
7. Michael K L Chu,Jian Chen,Claudia R Gordijo,Simon Chiang,Alexander Ivovic,Khajag Koulajian,Adria Giacca,Xiao Yu Wu,Yu Sun. (2012-05-09) In vitro and in vivo testing of glucose-responsive insulin-delivery microdevices in diabetic rats.. Lab on a chip, 12 ((14)): (2533-2539). [PMID:22565220]
8. Y Wang,I Zhitomirsky. (2012-06-02) Bio-inspired catechol chemistry for electrophoretic nanotechnology of oxide films.. Journal of colloid and interface science, 380 ((1)): (8-15). [PMID:22652591]
9. Marita Skarpeli-Liati,Sarah G Pati,Jakov Bolotin,Soren N Eustis,Thomas B Hofstetter. (2012-06-12) Carbon, hydrogen, and nitrogen isotope fractionation associated with oxidative transformation of substituted aromatic N-alkyl amines.. Environmental science & technology, 46 ((13)): (7189-7198). [PMID:22681573]
10. Abhinav M Gaikwad,Alla M Zamarayeva,Jamesley Rousseau,Howie Chu,Irving Derin,Daniel A Steingart. (2012-07-05) Highly stretchable alkaline batteries based on an embedded conductive fabric.. Advanced materials (Deerfield Beach, Fla.), 24 ((37)): (5071-5076). [PMID:22760812]
11. Geraldine S C Turner,Graham A Mills,Peter R Teasdale,Jonathan L Burnett,Sean Amos,Gary R Fones. (2012-07-24) Evaluation of DGT techniques for measuring inorganic uranium species in natural waters: Interferences, deployment time and speciation.. Analytica chimica acta, 739 (): (37-46). [PMID:22819048]
12. Alexandra V Soldatova,Cristina Butterfield,Oyeyemi F Oyerinde,Bradley M Tebo,Thomas G Spiro. (2012-08-16) Multicopper oxidase involvement in both Mn(II) and Mn(III) oxidation during bacterial formation of MnO(2).. Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 17 ((8)): (1151-1158). [PMID:22892957]
13. Xing Liu,Qi Wang,Huihui Zhao,Lichun Zhang,Yingying Su,Yi Lv. (2012-08-18) BSA-templated MnO2 nanoparticles as both peroxidase and oxidase mimics.. The Analyst, 137 ((19)): (4552-4558). [PMID:22900262]
14. Wen-Hui Kuan,Yen-Chuan Chan. (2012-09-25) pH-dependent mechanisms of methylene blue reacting with tunneled manganese oxide pyrolusite.. Journal of hazardous materials, 239-240 (): (152-159). [PMID:22999656]
15. Si-Hyun Do,Sung-Ho Kong. (2012-10-04) The oxidation of toluene sorbed on activated carbon in the presence of H(2)O(2) and manganese oxide.. Water science and technology : a journal of the International Association on Water Pollution Research, 66 ((11)): (2349-2354). [PMID:23032764]
16. S Z Takács,Andrea Szabó,G Oszlánczi,P Pusztai,A Sápi,Z Kónya,A Papp. (2012-11-09) Repeated simultaneous cortical electrophysiological and behavioral recording in rats exposed to manganese-containing nanoparticles.. Acta biologica Hungarica, 63 ((4)): (426-440). [PMID:23134600]
17. Yongmin He,Wanjun Chen,Xiaodong Li,Zhenxing Zhang,Jiecai Fu,Changhui Zhao,Erqing Xie. (2012-12-20) Freestanding three-dimensional graphene/MnO2 composite networks as ultralight and flexible supercapacitor electrodes.. ACS nano, 7 ((1)): (174-182). [PMID:23249211]
18. Jun Zhang,Xianghong Liu,Lixue Zhang,Bingqiang Cao,Shihua Wu. (2013-01-24) Reactive template synthesis of polypyrrole nanotubes for fabricating metal/conducting polymer nanocomposites.. Macromolecular rapid communications, 34 ((6)): (528-532). [PMID:23341240]
19. Xing Wu,Lingtian Xie,Liying Xu,Shaofeng Wang,Yongfeng Jia. (2013-01-29) Effects of sediment composition on cadmium bioaccumulation in the clam Meretrix meretrix Linnaeus.. Environmental toxicology and chemistry, 32 ((4)): (841-847). [PMID:23355485]
20. Nicy Ajith,Aditi A Dalvi,Kallola K Swain,P S Remya Devi,Bhupesh B Kalekar,Rakesh Verma,A V R Reddy. (2013-02-06) Sorption of As(III) and As(V) on chemically synthesized manganese dioxide.. Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering, 48 ((4)): (422-428). [PMID:23379947]
21. Guangyu He,Yuan Yuan,Liang Wang,Haiqun Chen,Xiaoqiang Sun,Xin Wang. (2013-05-08) Facile synthesis of low-defect-density graphene/MnO2 composite and its electrochemical performance.. Journal of nanoscience and nanotechnology, 13 ((1)): (487-492). [PMID:23646759]
22. Emily Y Tsui,Theodor Agapie. (2013-06-08) Reduction potentials of heterometallic manganese-oxido cubane complexes modulated by redox-inactive metals.. Proceedings of the National Academy of Sciences of the United States of America, 110 ((25)): (10084-10088). [PMID:23744039]
23. Zhijiang Lu,Jay Gan. (2013-06-25) Oxidation of nonylphenol and octylphenol by manganese dioxide: kinetics and pathways.. Environmental pollution (Barking, Essex : 1987), 180 (): (214-220). [PMID:23792380]
24. Zhi-Rong Lin,Ling Zhao,Yuan-Hua Dong. (2013-07-11) Application of microwave-irradiated manganese dioxide in the removal of polychlorinated biphenyls from soil contaminated by capacitor oil.. Environmental technology, 34 ((5-8)): (637-644). [PMID:23837313]
25. Meng Xu,Hongjie Wang,Lei Di,Dan Qu,Yujia Zhai,Yili Wang. (2013-08-08) Removal of Pb(II) from aqueous solution by hydrous manganese dioxide: adsorption behavior and mechanism.. Journal of environmental sciences (China), 25 ((3)): (479-486). [PMID:23923420]
26. F Javier Pérez-Areales,Ornella Di Pietro,Alba Espargaró,Anna Vallverdú-Queralt,Carles Galdeano,Ilaria M Ragusa,Elisabet Viayna,Catherine Guillou,M Victòria Clos,Belén Pérez,Raimon Sabaté,Rosa M Lamuela-Raventós,F Javier Luque,Diego Mu?oz-Torrero. (2014-08-27) Shogaol-huprine hybrids: dual antioxidant and anticholinesterase agents with β-amyloid and tau anti-aggregating properties.. Bioorganic & medicinal chemistry, 22 ((19)): (5298-5307). [PMID:25156301]
27. Edyta Nalewajko-Sieliwoniuk,Julita Malejko,Monika Mozolewska,El?bieta Wo?yniec,Jolanta Nazaruk. (2014-12-02) Determination of polyphenolic compounds in Cirsium palustre (L.) extracts by high performance liquid chromatography with chemiluminescence detection.. Talanta, 133 (): (38-44). [PMID:25435224]
28. Jun Lu,Chun Zhan,Tianpin Wu,Jianguo Wen,Yu Lei,A Jeremy Kropf,Huiming Wu,Dean J Miller,Jeffrey W Elam,Yang-Kook Sun,Xinping Qiu,Khalil Amine. (2014-12-17) Effectively suppressing dissolution of manganese from spinel lithium manganate via a nanoscale surface-doping approach.. Nature communications, 5 (): (5693-5693). [PMID:25514346]
29. Xiao Liang,Connor Hart,Quan Pang,Arnd Garsuch,Thomas Weiss,Linda F Nazar. (2015-01-07) A highly efficient polysulfide mediator for lithium-sulfur batteries.. Nature communications, 6 (): (5682-5682). [PMID:25562485]
30. Toshihiro Takashima,Yuki Hotori,Hiroshi Irie. (2015-02-05) Development of optically transparent water oxidation catalysts using manganese pyrophosphate compounds.. Journal of photochemistry and photobiology. B, Biology, 152 ((Pt A)): (139-145). [PMID:25648929]
31. Cheng-Shiuan Li,Gér?me Melaet,Walter T Ralston,Kwangjin An,Christopher Brooks,Yifan Ye,Yi-Sheng Liu,Junfa Zhu,Jinghua Guo,Selim Alayoglu,Gabor A Somorjai. (2015-03-11) High-performance hybrid oxide catalyst of manganese and cobalt for low-pressure methanol synthesis.. Nature communications, 6 (): (6538-6538). [PMID:25754475]
32. Feng Yan,Guozhong Xing,Rongming Wang,Lin Li. (2015-03-17) Tailoring surface phase transition and magnetic behaviors in BiFeO3 via doping engineering.. Scientific reports, 5 (): (9128-9128). [PMID:25774619]
33. Chengsheng Ni,John T S Irvine. (2015-07-28) Calcium manganite as oxygen electrode materials for reversible solid oxide fuel cell.. Faraday discussions, 182 (): (289-305). [PMID:26212316]
34. Liling Jing,Mark G Moloney,Hao Xu,Lian Liu,Wenqiang Sun,Junying Li,Pengfei Yang. (2020-09-12) Carbene modification and reversible crosslinking of silver nanoparticles for controlled antibacterial activity.. Scientific reports, 10 ((1)): (14937-14937). [PMID:32913281]
35. Heng Lai,Jiaxin Li,Zhigao Chen,Zhigao Huang. (2012-05-02) Carbon nanohorns as a high-performance carrier for MnO2 anode in lithium-ion batteries.. ACS applied materials & interfaces, 4 ((5)): (2325-2328). [PMID:22545767]
36. Min-Sik Park,Jae-Hun Kim,Ki Jae Kim,Goojin Jeong,Young-Jun Kim. (2013-07-19) Morphological modification of alpha-MnO2 catalyst for use in Li/air batteries.. Journal of nanoscience and nanotechnology, 13 ((5)): (3611-3616). [PMID:23858913]
37. Shafeer Kalathil,Hoa Van Nguyen,Jae-Jin Shim,Mohammad Mansoob Khan,Jintae Lee,Moo Hwan Cho. (2013-11-20) Enhanced performance of a microbial fuel cell using CNT/MnO2 nanocomposite as a bioanode material.. Journal of nanoscience and nanotechnology, 13 ((11)): (7712-7716). [PMID:24245320]
38. Ross W Hogue,Sébastien Dhers,Ryan M Hellyer,Jingwei Luo,Garry S Hanan,David S Larsen,Anna L Garden,Sally Brooker. (2017-06-09) Self-Assembly of Cyclohelicate [M. Chemistry (Weinheim an der Bergstrasse, Germany), 23 ((57)): (14193-14199). [PMID:28593687]
39. Fengming Ma,Shihao Zhang,Pu Li,Bingxin Sun,Yufeng Xu,Dongbing Tao,Haitian Zhao,Shiwen Cui,Ruiyin Zhu,Baiqing Zhang. (2021-02-06) Investigation on the role of the free radicals and the controlled degradation of chitosan under solution plasma process based on radical scavengers.. Carbohydrate polymers, 257 (): (117567-117567). [PMID:33541628]