氢化铝锂
- CAS编号: 16853-85-3(THF)
- 分子式: LiAlH4
- 分子量: 37.95
- MDL号: MFCD00011075
库存信息
库存信息
库存信息
库存信息
货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
---|---|---|---|---|
L130047-100ml | 100ml | 期货 | | |
L130047-500ml | 500ml | 现货 | | |
L130047-800ml | 800ml | 现货 | | |
L130047-1L | 1L | 现货 | |
货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
---|---|---|---|---|
L130047-100ml | 100ml | 期货 | | |
L130047-500ml | 500ml | 现货 | | |
L130047-800ml | 800ml | 现货 | | |
L130047-1L | 1L | 现货 | |
规格或纯度 | 2.5 M in THF |
---|---|
英文名称 | Lithium Aluminium Hydride |
别名 | 四氢铝锂 |
英文别名 | LAH; Lithium alanate; Lithium tetrahydroaluminate; Lithium tetrahydridoaluminate |
应用 | Reactant or reagent for: &bull The preparation of thermoplastic polyester polyamides from oleic acid &bull Lithium-polymer batteries &bull Hydrodefluorination of gem-difluoromethylene derivatives &bull Asymmetric aldol reactions &bull Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols |
储存温度 | 充氩 |
运输条件 | 常规运输 |
产品介绍 |
Lithium aluminum hydride can be used as a reactant or a reagent for a variety of experiments. For instance, it has been used for the preparation of thermoplastic polyester polyamides from oleic acid, Lithium-polymer batteries, hydrodefluorination of gem-difluoromethylene derivatives, asymmetric aldol reactions and synthesis of Li-Al-N-H composites with hydrogen absorption/ desorption properties. Additionally, Lithium aluminum hydride is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols.Reactant or reagent for: &bull The preparation of thermoplastic polyester polyamides from oleic acid &bull Lithium-polymer batteries &bull Hydrodefluorination of gem-difluoromethylene derivatives &bull Asymmetric aldol reactions &bull Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols Lithium aluminum hydride can be used as a reactant or a reagent for a variety of experiments. For instance, it has been used for the preparation of thermoplastic polyester polyamides from oleic acid, Lithium-polymer batteries, hydrodefluorination of gem-difluoromethylene derivatives, asymmetric aldol reactions and synthesis of Li-Al-N-H composites with hydrogen absorption/ desorption properties. Additionally, Lithium aluminum hydride is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols. |
分子式 |
LiAlH4 |
---|---|
UN Number | 2056 |
Class | 3 |
Packing Group | II |
分子量 | 37.95 |
密度 | 0.9 |
---|---|
敏感性 | 对空气和水分敏感 |
一般危化品 | 一般危化品 |
---|---|
象形图 |
Health Hazard Harmful Flammable |
信号词 | Danger |
危险声明 |
H319: Causes serious eye irritation H335: May cause respiratory irritation H351: Suspected of causing cancer H302: Harmful if swallowed H225: Highly Flammable liquid and vapor H336: May cause drowsiness or dizziness |
预防措施声明 | P261,P305+P351+P338,P280,P370+P378,P210,P405,P501,P233,P240,P264,P403+P235,P303+P361+P353,P201,P308+P313,P271,P241,P270,P304+P340,P337+P313,P403+P233,P202,P330,P301+P312,P242,P243 |
Class | 3 |
1. Vito Capriati,Saverio Florio,Renzo Luisi,Antonio Salomone. (2002-07-06) Oxiranyl anion-mediated synthesis of highly enantiomerically enriched styrene oxide derivatives.. Organic letters, 4 ((14)): (2445-2448). [PMID:12098268] |
2. Takahisa Nakane,Yoshiko Maeda,Hideharu Ebihara,Yoko Arai,Kazuo Masuda,Akihito Takano,Hiroyuki Ageta,Kenji Shiojima,Shao-Qing Cai,Osama Bashir Abdel-Halim. (2002-09-19) Fern constituents: triterpenoids from Adiantum capillus-veneris.. Chemical & pharmaceutical bulletin, 50 ((9)): (1273-1275). [PMID:12237552] |
3. Haruki Sashida,Kazuo Ohyanagi. (2004-01-08) Studies on tellurium-containing heterocycles. Part 20. Reactions of 2-benzoselenopyrylium salts and 2-benzotelluropyrylium salts with nucleophiles: formation of 1-functionalized 1H-isoselenochromenes and 1H-isotellurochromenes.. Chemical & pharmaceutical bulletin, 52 ((1)): (57-62). [PMID:14709869] |
4. Hideki Hashizume,Sehei Hirosawa,Ryuichi Sawa,Yasuhiko Muraoka,Daishiro Ikeda,Hiroshi Naganawa,Masayuki Igarashi. (2004-03-23) Tripropeptins, novel antimicrobial agents produced by Lysobacter sp.. The Journal of antibiotics, 57 ((1)): (52-58). [PMID:15032486] |
5. Takashi Ikegami,Woo-Sang Lee,Hiroyuki Nariai,Toshifumi Takeuchi. (2004-04-20) Covalent molecular imprinting of bisphenol A using its diesters followed by the reductive cleavage with LiAlH(4).. Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 804 ((1)): (197-201). [PMID:15093173] |
6. Masateru Nishihara,Hiroyuki Morii,Koji Matsuno,Mami Ohga,Karl O Stetter,Yosuke Koga. (2005-04-05) Structural analysis by reductive cleavage with LiAlH4 of an allyl ether choline-phospholipid, archaetidylcholine, from the hyperthermophilic methanoarchaeon Methanopyrus kandleri.. Archaea (Vancouver, B.C.), 1 ((2)): (123-131). [PMID:15803650] |
7. Damián E Bikiel,Florencia Di Salvo,Mariano C González Lebrero,Fabio Doctorovich,Darío A Estrin. (2005-07-19) Solvation and structure of LiAlH(4) in ethereal solvents.. Inorganic chemistry, 44 ((15)): (5286-5292). [PMID:16022527] |
8. Jungseok Heo,Chad A Mirkin. (2005-12-31) Pseudo-allosteric recognition of mandelic acid with an enantioselective coordination complex.. Angewandte Chemie (International ed. in English), 45 ((6)): (941-944). [PMID:16385593] |
9. Mitsuteru Numazawa,Wakako Handa. (2006-04-06) Reduction of 1,4-dien-3-one steroids with LiAl2H4 or NaB2H4: stereospecific deuterium-labeling at the c-1alpha position of a 4-en-3-one steroid.. Chemical & pharmaceutical bulletin, 54 ((4)): (554-556). [PMID:16595964] |
10. José M Concellón,Pablo L Bernad,Virginia del Solar,José Ramón Suárez,Santiago García-Granda,M Rosario Díaz. (2006-08-12) Synthesis of enantiopure (alphaS,betaS)- or (alphaR,betaS)-beta-amino alcohols by complete regioselective opening of aminoepoxides by organolithium reagents LiAlH4 or LiAlD4.. The Journal of organic chemistry, 71 ((17)): (6420-6426). [PMID:16901125] |
11. M Brett Runge,Martin T Mwangi,A Lee Miller,Mathew Perring,Ned B Bowden. (2007-12-18) Cascade reactions using LiAlH4 and grignard reagents in the presence of water.. Angewandte Chemie (International ed. in English), 47 ((5)): (935-939). [PMID:18081114] |
12. Shinya Tachibana,Takashi Gotou,Masato Nomura. (2008-01-17) Synthesis and physiological activity of thiophenes and furans with 3- and 4-methoxyacetophenone derivatives.. Journal of oleo science, 57 ((2)): (107-113). [PMID:18198467] |
13. Andreas Grubelnik,Luzia Wiesli,Patrick Furrer,Daniel Rentsch,Roland Hany,Veronika R Meyer. (2008-05-08) A simple HPLC-MS method for the quantitative determination of the composition of bacterial medium chain-length polyhydroxyalkanoates.. Journal of separation science, 31 ((10)): (1739-1744). [PMID:18461645] |
14. Byung-Hoon Jeong,Nam-Ho Kim,Jae-Kwang Jin,Jin-Kyu Choi,Yun-Jung Lee,Jae-Il Kim,Eun-Kyoung Choi,Richard I Carp,Yong-Sun Kim. (2009-07-17) Reduction of prion infectivity and levels of scrapie prion protein by lithium aluminum hydride: implications for RNA in prion diseases.. Journal of neuropathology and experimental neurology, 68 ((8)): (870-879). [PMID:19606066] |
15. Krishnananda Samanta,Bandana Chakravarti,Jitendra Kumar Mishra,Shailendra Kumar Dhar Dwivedi,Lakshma Vadithe Nayak,Preeti Choudhry,Hemant Kumar Bid,Rituraj Konwar,Naibedya Chattopadhyay,Gautam Panda. (2009-11-26) Anti-tumor activity of a new series of benzoxazepine derivatives in breast cancer.. Bioorganic & medicinal chemistry letters, 20 ((1)): (283-287). [PMID:19932024] |
16. Frédéric Hild,Pierre Haquette,Lydia Brelot,Samuel Dagorne. (2009-12-22) Synthesis and structural characterization of well-defined anionic aluminum alkoxide complexes supported by NON-type diamido ether tridentate ligands and their use for the controlled ROP of lactide.. Dalton transactions (Cambridge, England : 2003), ((2)(2)): (533-540). [PMID:20023991] |
17. Meganne Christian,Kondo-Francois Aguey-Zinsou. (2010-10-05) Destabilisation of complex hydrides through size effects.. Nanoscale, 2 ((12)): (2587-2590). [PMID:20886168] |
18. I-Chi Lee,Medel Manuel L Zulueta,Chi-Rung Shie,Susan D Arco,Shang-Cheng Hung. (2011-09-17) Deuterium-isotope study on the reductive ring opening of benzylidene acetals.. Organic & biomolecular chemistry, 9 ((22)): (7655-7658). [PMID:21922112] |
19. Hao Yao,Shigehito Isobe,Yongming Wang,Naoyuki Hashimoto,Somei Ohnuki. (2011-10-05) Plastic bag method for active sample loading into transmission electron microscope.. Journal of electron microscopy, 60 ((6)): (375-378). [PMID:21969338] |
20. Carlo Cassani,Rafael Martín-Rapún,Elena Arceo,Fernando Bravo,Paolo Melchiorre. (2013-01-19) Synthesis of 9-amino(9-deoxy)epi cinchona alkaloids, general chiral organocatalysts for the stereoselective functionalization of carbonyl compounds.. Nature protocols, 8 ((2)): (325-344). [PMID:23329005] |
21. Seiji Takeda,Shu-Ping Hui,Hirotoshi Fuda,Shigeki Jin,Toshihiro Sakurai,Atsushi Ishii,Koichi Mukasa,Kazuhisa Sueoka,Hitoshi Chiba. (2013-05-01) Evaluation of various electrode materials for detection of oxidized low-density lipoproteins.. Journal of biomedical nanotechnology, 9 ((2)): (303-306). [PMID:23627060] |