tBuXPhos Pd G3
- CAS编号: 1447963-75-8
- 分子式: C42H59NO3PPdS
- 分子量: 794.37
- PubChem编号: 90645613
库存信息
库存信息
库存信息
库存信息
货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
---|---|---|---|---|
I167321-250mg | 250mg | 现货 | | |
I167321-1g | 1g | 现货 | | |
I167321-5g | 5g | 现货 | | |
I167321-10g | 10g | 现货 | |
货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
---|---|---|---|---|
I167321-250mg | 250mg | 现货 | | |
I167321-1g | 1g | 现货 | | |
I167321-5g | 5g | 现货 | | |
I167321-10g | 10g | 现货 | |
规格或纯度 | 97% |
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英文名称 | tBuXPhos Pd G3 |
别名 | [(2-二-叔-丁基膦-2′,4′,6′-三异丙基-1,1′-联苯)-2-(2′-氨基-1,1′-联苯)] 甲磺酸钯 (II) ];甲烷磺酸(2-二叔丁基膦基-2',4',6'-三异丙基-1,1'-联苯基)(2'-氨基-1,1'-联苯-2-基)钯(II) |
英文别名 | Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II); t BuXPhos-Pd-G3 |
储存温度 | 2-8°C储存,充氩 |
运输条件 | 冰袋运输 |
产品介绍 |
tBuXPhos Pd G3是第三代 (G3) Buchwald 预催化剂。它具有空气、水分和热稳定特性,高度可溶于各种常见的有机溶剂。它在溶液中有很长的寿命。tBuXPhos Pd G3 是 Buchwald-Hartwig 交叉偶联反应的优良试剂。它的一些独特特征包括催化剂负载量更低、反应时间更短、可有效形成活性催化物质和精确控制配体与钯的比例。 Description tBuXPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. tBuXPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio. Product class M-P, Homogeneous Catalysts, M-N, Buchwald Catalyst, Buchwald Catalyst 3rd Generation, Amino Ligands, Ferrocenyl Ligands - Achiral Reaction type Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Suzuki-Miyaura Coupling Reaction |
IUPAC Name | ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;methanesulfonic acid;palladium;2-phenylaniline |
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INCHI | InChI=1S/C29H45P.C12H10N.CH4O3S.Pd/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h13-21H,1-12H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1;; |
InChi Key | IKNBBVYTGIKLPA-UHFFFAOYSA-N |
Canonical SMILES | CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC=CC=C2P(C(C)(C)C)C(C)(C)C)C(C)C.CS(=O)(=O)O.C1=CC=C([C-]=C1)C2=CC=CC=C2N.[Pd] |
分子式 |
C42H59NO3PPdS |
PubChem CID | 90645613 |
分子量 | 794.37 |
敏感性 | 对湿度敏感 |
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熔点 | 130-140 °C |
象形图 |
Harmful |
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信号词 | Warning |
危险声明 |
H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation H412: Harmful to aquatic life with long lasting effects H302: Harmful if swallowed |
预防措施声明 | P261,P305+P351+P338,P273,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P317,P337+P317,P332+P317,P319 |