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叔丁基对苯醌

规格或纯度: ≥98.0%(GC)
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货号 (SKU) 包装规格 是否现货 价格 数量
I133400-5g
 5g 现货 Stock Image
I133400-25g
 25g 现货 Stock Image
I133400-100g
 100g 现货 Stock Image
I133400-500g
 500g 现货 Stock Image
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基本描述

规格或纯度 ≥98.0%(GC)
英文名称 2-tert-Butyl-1,4-benzoquinone
别名 特丁基对苯醌|2-叔丁基-1,4-苯醌
英文别名 2-tert-Butyl-1,4-benzoquinone|3602-55-9|tert-Butylquinone|2-tert-butylcyclohexa-2,5-diene-1,4-dione|2-tert-Butyl-p-benzoquinone|tert-Butyl-p-benzoquinone|tert-Butylbenzoquinone|tert-Butyl-1,4-benzoquinone|2-tert-Butyl-p-quinone|2-tert-Butyl-4-quinone|2-te
运输条件 常规运输

名称和标识符

IUPAC Name 2-tert-butylcyclohexa-2,5-diene-1,4-dione
INCHI InChI=1S/C10H12O2/c1-10(2,3)8-6-7(11)4-5-9(8)12/h4-6H,1-3H3
InChi Key NCCTVAJNFXYWTM-UHFFFAOYSA-N
Canonical SMILES CC(C)(C)C1=CC(=O)C=CC1=O
WGK Germany 3
RTECS DK3790000
PubChem CID 19211
分子量 164.2
Beilstein号 7(4)2100
Reaxy-Rn 1860944

化学和物理性质

熔点 57 °C

安全和危险性（GHS）

象形图
ghs06

Toxic

ghs09

Environmental Hazard

ghs07

Harmful
信号词 Danger
危险声明 H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
H301: Toxic if swallowed
H331: Toxic if inhaled
H400: Very toxic to aquatic life
H410: Very toxic to aquatic life with long lasting effects
预防措施声明 P261,P305+P351+P338,P273,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P391,P330,P264+P265,P301+P316,P337+P317,P332+P317,P316,P319
WGK Germany 3
RTECS DK3790000
Reaxy-Rn 1860944
个人防护装备 dust mask type N95 (US)， Eyeshields， Gloves

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参考文献

1. S W Cummings,B B Curtis,J A Peterson,R A Prough.  (1990-09-01)  The effect of the tert-butylquinone metabolite of butylated hydroxyanisole on cytochrome P-450 monooxygenase activity..  Xenobiotica; the fate of foreign compounds in biological systems,  20  ((9)):  (915-924).  [PMID:2122606]
2. K Morimoto,K Tsuji,T Iio,N Miyata,A Uchida,R Osawa,H Kitsutaka,A Takahashi.  (1991-04-01)  DNA damage in forestomach epithelium from male F344 rats following oral administration of tert-butylquinone, one of the forestomach metabolites of 3-BHA..  Carcinogenesis,  12  ((4)):  (703-708).  [PMID:2013134]
3. R M Vos,B Van Ommen,M S Hoekstein,J H De Goede,P J Van Bladeren.  (1989-01-01)  Irreversible inhibition of rat hepatic glutathione S-transferase isoenzymes by a series of structurally related quinones..  Chemico-biological interactions,  71  ((4)):  (381-392).  [PMID:2582541]
4. W H Kalus,R Münzner,W G Filby.  (1994-01-01)  The reaction of butylated hydroxyanisole and its metabolites with some arylamines: investigations of product mutagenicity..  Environmental health perspectives,  102  ((1)):  (96-99).  [PMID:9719675]
5. T Okubo,Y Yokoyama,K Kano,I Kano.  (2003-03-28)  Cell death induced by the phenolic antioxidant tert-butylhydroquinone and its metabolite tert-butylquinone in human monocytic leukemia U937 cells..  Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association,  41  ((5)):  (679-688).  [PMID:12659721]
6. Fa Zhang,Alan Chang,Ken Karaisz,Rong Feng,Jane Cai.  (2004-03-17)  Structural identification of extractables from rubber closures used for pre-filled semisolid drug applicator by chromatography, mass spectrometry, and organic synthesis..  Journal of pharmaceutical and biomedical analysis,  34  ((5)):  (841-849).  [PMID:15019018]
7. Malte Rolff,Julia Schottenheim,Gerhard Peters,Felix Tuczek.  (2010-07-24)  The first catalytic tyrosinase model system based on a mononuclear copper(I) complex: kinetics and mechanism..  Angewandte Chemie (International ed. in English),  49  ((36)):  (6438-6442).  [PMID:20652917]
8. Albert Braeuning,Silvia Vetter,Silvia Orsetti,Michael Schwarz.  (2012-04-03)  Paradoxical cytotoxicity of tert-butylhydroquinone in vitro: What kills the untreated cells?.  Archives of toxicology,  86  ((9)):  (1481-1487).  [PMID:22466069]
9. Toshiyuki Matsunaga,Satoshi Endo,Mayuko Takemura,Midori Soda,Keiko Yamamura,Kazuo Tajima,Takeshi Miura,Tomoyuki Terada,Ossama El-Kabbani,Akira Hara.  (2012-04-14)  Reduction of cytotoxic p-quinone metabolites of tert-butylhydroquinone by human aldo-keto reductase (AKR) 1B10..  Drug metabolism and pharmacokinetics,  27  ((5)):  (553-558).  [PMID:22498646]
10. Svetlana N Samovich, Anastasia A Sladkova, Roman L Sverdlov, Irina P Edimecheva, Oleg I Shadyro,.  (2019-04-22)  Effects of quinones and nitroazoles on free-radical fragmentation of glycerol-1-phosphate and 1,2-dimyristoyl-glycero-3-phosphatidyl-glycerol..  Chemistry and physics of lipids,    ():  ( 8-14 ).  [PMID:31005671]
11. Nan Shu,Lasse G Lorentzen,Michael J Davies.  (2019-04-27)  Reaction of quinones with proteins: Kinetics of adduct formation, effects on enzymatic activity and protein structure, and potential reversibility of modifications..  Free radical biology & medicine,  137  ():  (169-180).  [PMID:31026584]
12. Xianghe Meng,Chaosheng Xia,Qin Ye,Xiaohua Nie.  (2020-05-01)  tert-Butyl-p-benzoquinone induces autophagy by inhibiting the Akt/mTOR signaling pathway in RAW 264.7 cells..  Food & function,  11  ((5)):  (4193-4201).  [PMID:32352125]
13. B Bergmann,J K Dohrmann,R Kahl.  (1992-09-01)  Formation of the semiquinone anion radical from tert-butylquinone and from tert-butylhydroquinone in rat liver microsomes..  Toxicology,  74  ((2-3)):  (127-133).  [PMID:1325685]
14. A Sakai,N Miyata,A Takahashi.  (1990-11-01)  Initiating activity of 3-tert-butyl-4-hydroxyanisole (3-BHA) and its metabolites in two-stage transformation of BALB/3T3 cells..  Carcinogenesis,  11  ((11)):  (1985-1988).  [PMID:2225330]
15. W H Kalus,R Münzner,W G Filby.  (1990-03-01)  Isolation and characterization of some products of the BHA-nitrite reaction: examination of their mutagenicity..  Food additives and contaminants,  7  ((2)):  (223-233).  [PMID:2354741]
16. R Kahl,S Weinke,H Kappus.  (1989-12-01)  Production of reactive oxygen species due to metabolic activation of butylated hydroxyanisole..  Toxicology,  59  ((2)):  (179-194).  [PMID:2555935]
17. M Mizuno,A Ohara,G Danno,K Kanazawa,M Natake.  (1987-02-01)  Mutagens formed from butylated hydroxyanisole treated with nitrite under acidic conditions..  Mutation research,  176  ((2)):  (179-184).  [PMID:3100946]
18. C G Rogers,B G Boyes,T I Matula,G Neville,R Stapley.  (1993-03-01)  Cytotoxic and genotoxic properties of tert.-butyl-p-quinone (TBQ) in an in vitro assay system with Chinese hamster V79 cells and in strain D7 of Saccharomyces cerevisiae..  Mutation research,  299  ((1)):  (9-18).  [PMID:7679195]
19. P A Schilderman,E Rhijnsburger,I Zwingmann,J C Kleinjans.  (1995-03-01)  Induction of oxidative DNA damages and enhancement of cell proliferation in human lymphocytes in vitro by butylated hydroxyanisole..  Carcinogenesis,  16  ((3)):  (507-512).  [PMID:7697806]
20. J H Chung,Y N Cha,R J Rubin.  (1994-01-01)  Role of quinone reductase in in vivo ethanol metabolism and toxicity..  Toxicology and applied pharmacology,  124  ((1)):  (123-130).  [PMID:8291053]
21. Yu Miao,Yanling Wu,Yingjin Jin,Mengze Lei,Jixing Nan,Xue Wu.  (2020-01-15)  Benzoquinone derivatives with antioxidant activity inhibit activated hepatic stellate cells and attenuate liver fibrosis in TAA-induced mice..  Chemico-biological interactions,  317  ():  (108945-108945).  [PMID:31935363]
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