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二碳酸二叔丁酯

规格或纯度: 99%
有货

库存信息

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库存信息

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货号 (SKU) 包装规格 是否现货 价格 数量
D106159-25g
25g 现货 Stock Image
D106159-100g
100g 现货 Stock Image
D106159-500g
500g 现货 Stock Image
D106159-2.5kg
2.5kg 现货 Stock Image

基本描述

规格或纯度 99%
英文名称 Di-tert-butyl dicarbonate
别名 Boc酸酐|二-叔丁基二碳酸酯|二叔丁基焦碳酸酯|焦碳酸二叔丁酯|Boc酸酐 二叔丁基二碳酸酯
英文别名 Di-tert-butyl dicarbonate|24424-99-5|BOC anhydride|Bis(tert-butoxycarbonyl)oxide|di-tert-Butyl pyrocarbonate|Di-tert-butyldicarbonate|Boc2O|tert-Butoxycarbonyl anhydride|BOC-anhydride|di-t-Butyl dicarbonate|Dicarbonic acid, bis(1,1-dimethylethyl) ester|Di
储存温度 2-8°C储存,避光,充氩
运输条件 冰袋运输
产品介绍

遇水分解成叔丁醇和CO2,因此瓶装试剂,在吸潮后会导致瓶内压力升高,包装开启时注意个人防护。氨基酸BOC试剂。有机合成中用来引入叔丁氧羰(BOC)保护基团,特别适用于氨基酸的氨基保护。 三叔丁氧羰基保护的肼可以在发色试剂中制备芴甲氧羰基?酯以监测固相醛类。 用于制备叔丁氧羰基保护的胺类的试剂。 用于引入叔丁氧羰基保护基团的试剂。 通过 Lewis 酸催化作用可以保护叔丁氧羰基衍生物等醇类。 通过叔丁氧羰基氨基丙炔与甲醛、二异丙胺以及溴化铜的?反应来制备氨甲基丙二烯,是许多牛血浆胺氧化酶灭活剂?的组分。

Aminomethyl allene was prepared by reaction of Boc propargyl amine with formaldehyde, diisopropylamine and copper bromide as part of a series of Bovine Plasma Amine Oxidase inactivators Protection of alcohols as Boc derivatives via Lewis acid catalysis. Reagent for the introduction of the Boc protecting group. Reagent for the preparation of Boc protected amines. Tris-Boc protected hydrazine allows preparation of Fmoc ester in a chromophoric reagent to monitor solid-phase aldehydes.

名称和标识符

EC号 246-240-1
IUPAC Name tert-butyl (2-methylpropan-2-yl)oxycarbonyl carbonate
INCHI InChI=1S/C10H18O5/c1-9(2,3)14-7(11)13-8(12)15-10(4,5)6/h1-6H3
InChi Key DYHSDKLCOJIUFX-UHFFFAOYSA-N
Canonical SMILES CC(C)(C)OC(=O)OC(=O)OC(C)(C)C
WGK Germany 3
RTECS HT0230000
PubChem CID 90495
UN Number 2929
Packing Group II
分子量 218.25
Beilstein号 1911173

化学和物理性质

溶解性 Miscible with decalin, toluene, carbon tetrachloride, tetrahydrofuran, dioxane, alcohols, acetone, acetonitrile and dimethylformamide. Immiscible with water.
密度 0.913
敏感性 对热敏感;易吸潮;对光敏感;对湿度敏感
折光率 1.409
闪点(℉) 98.6 °F
闪点(℃) 37℃
沸点 56-57 °C/0.5 mmHg
熔点 23°C

安全和危险性(GHS)

象形图
ghs06

Toxic

ghs08

Health Hazard

ghs05

Corrosive

ghs02

Flammable

信号词 Danger
危险声明 H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
H318: Causes serious eye damage
H225: Highly Flammable liquid and vapor
H317: May cause an allergic skin reaction
H228: Flammable solid
H226: Flammable liquid and vapor
H330: Fatal if inhaled
预防措施声明 P261,P305+P351+P338,P280,P370+P378,P210,P302+P352,P321,P405,P501,P233,P240,P264,P403+P235,P260,P284,P303+P361+P353,P271,P241,P304+P340,P403+P233,P272,P333+P313,P362+P364,P320,P242,P243,P264+P265,P305+P354+P338,P317,P337+P317,P332+P317,P316,P319
WGK Germany 3
RTECS HT0230000
Class 6.1 (3)
个人防护装备 Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

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