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4-氯苯乙烯

规格或纯度: >97.0%(GC) ,含500ppm TBC稳定剂
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货号 (SKU) 包装规格 是否现货 价格 数量
C121719-5g
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C121719-10g
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C121719-25g
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C121719-50g
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聚合物/高分子试剂 苯乙烯单体
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基本描述

规格或纯度 >97.0%(GC) ,含500ppm TBC稳定剂
英文名称 4-Chlorostyrene
别名 对氯苯乙烯
英文别名 4-Chlorostyrene|1073-67-2|1-Chloro-4-vinylbenzene|P-CHLOROSTYRENE|1-chloro-4-ethenylbenzene|Benzene, 1-chloro-4-ethenyl-|Parachlorostyrene|Styrene, p-chloro-|24991-47-7|para-chlorostyrene|MFCD00000632|T0J05U220F|NSC-18603|4-Chlorostyrene (stabilized with
应用 4-Chlorostyrene was used in the following studies: · Study of chemical and biochemical properties of the vinyl group of styrene by the development of structure activity relationships (SAR). · Preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). · To investigate the regioselectivity in the cationic Heck reaction of 4-substituted styrenes.
储存温度 2-8°C储存
运输条件 冰袋运输
产品介绍

4-氯苯乙烯是一种对位卤代苯乙烯衍生物。在过氧化苯甲酰（引发剂）存在下，它与丙烯腈（AN）接枝共聚到乙烯-丙烯-二烯三元共聚物（EPDM）上。

4-Chlorostyrene was used in the following studies:

· Study of chemical and biochemical properties of the vinyl group of styrene by the development of structure activity relationships (SAR).?

· Preparation of new bis(pyrazolyl)borato olefin complexes of copper(I).

· To investigate the regioselectivity in the cationic Heck reaction of 4-substituted styrenes.

4-Chlorostyrene is a para-halogenated styrene derivative. It undergoes graft copolymerization with acrylonitrile (AN) onto ethylene-propylene-diene terpolymer (EPDM) in the presence of benzoyl peroxide (initiator).
4-Chlorostyrene was used in the following studies: · Study of chemical and biochemical properties of the vinyl group of styrene by the development of structure activity relationships (SAR). · Preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). · To investigate the regioselectivity in the cationic Heck reaction of 4-substituted styrenes.

名称和标识符

EC号 214-028-8
IUPAC Name 1-chloro-4-ethenylbenzene
INCHI InChI=1S/C8H7Cl/c1-2-7-3-5-8(9)6-4-7/h2-6H,1H2
InChi Key KTZVZZJJVJQZHV-UHFFFAOYSA-N
Canonical SMILES C=CC1=CC=C(C=C1)Cl
分子式

H2C=CHC6H4Cl
PubChem CID 14085
Beilstein号 1098859
分子量 138.59

化学和物理性质

溶解性 Immiscible with water.
密度 1.09
敏感性 对光线敏感 ;对热敏感
沸点 191-192°C
熔点 -16°C
折光率 1.565
闪点(℉) 64°C
闪点(℃) 64°C

安全信息

象形图
ghs09

Environmental Hazard

ghs07

Harmful
信号词 Warning
危险声明 H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
H302: Harmful if swallowed
H312: Harmful in contact with skin
H400: Very toxic to aquatic life
H226: Flammable liquid and vapor
H332: Harmful if inhaled
H410: Very toxic to aquatic life with long lasting effects
预防措施声明 P261,P305+P351+P338,P273,P280,P370+P378,P210,P302+P352,P321,P405,P501,P233,P240,P264,P403+P235,P303+P361+P353,P271,P241,P270,P304+P340,P403+P233,P362+P364,P391,P330,P242,P243,P264+P265,P301+P317,P317,P337+P317,P332+P317,P319
WGK Germany 3
RTECS CZ0533000
Reaxy-Rn 1098859

参考文献

1. Guido Pampaloni,Riccardo Peloso,Claudia Graiff,Antonio Tiripicchio.  (2006-07-21)  Synthesis, characterization and olefin/CO exchange reactions of pyrazolylborato complexes of copper(I)..  Dalton transactions (Cambridge, England : 2003),    ((29)(29)):  (3576-3583).  [PMID:16855758]
2. Shuliang Yang, Li Peng, Changyan Cao, Fang Wei, Jian Liu, Ya-Nan Zhu, Chang Liu, Xiaoshi Wang, Weiguo Song,.  (2016-04-29)  Preparation of Magnetic Tubular Nanoreactors for Highly Efficient Catalysis..  Chemistry, an Asian journal,  11  ((19)):  ( 2797-2801 ).  [PMID:27123561]
3. Leire Ruiz-Rubio, Leyre Pérez-álvarez, Julia Sanchez-Bodón, Valeria Arrighi, José Luis Vilas-Vilela,.  (2019-01-10)  The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique..  Materials (Basel, Switzerland),  12  ((1) ):  ().  [PMID:30621027]
4. Wei Chen,Gui-Hua Liu,Kai Lin.  (2011-05-31)  [Determination of o-chlorostyrene in the air of workplace by gas chromatography]..  Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases,  29  ((2)):  (152-153).  [PMID:21619852]
5. Jou-Ku Chung,Shuijie Shen,Zhiteng Jiang,Wei Yuan,Jiang Zheng.  (2012-03-01)  Structure-toxicity relationship study of para-halogenated styrene analogues in CYP2E1 transgenic cells..  Toxicology letters,  210  ((3)):  (353-359).  [PMID:22366341]

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