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(1S,2S)-N,N'-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴(II)
- CAS编号: 259259-80-8
- 分子式: C32H38CoN2O4
- 分子量: 573.6
- MDL号: MFCD06797062
- PubChem编号: 135483535
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基本描述
| 英文名称 | (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) |
|---|---|
| 英文别名 | (S)-AMAC |
| 储存温度 | 充氩 |
| 运输条件 | 常规运输 |
| 产品介绍 |
Catalyst for: Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene Enantioselective borohydride reduction Preparation of ?-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones Preparation of ?-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones |
名称和标识符
| IUPAC Name | (E)-3-[[(1S,2S)-2-[[(E)-2-acetyl-3-hydroxybut-2-enylidene]amino]-1,2-bis(2,4,6-trimethylphenyl)ethyl]iminomethyl]-4-hydroxypent-3-en-2-one;cobalt |
|---|---|
| INCHI | InChI=1S/C32H40N2O4.Co/c1-17-11-19(3)29(20(4)12-17)31(33-15-27(23(7)35)24(8)36)32(34-16-28(25(9)37)26(10)38)30-21(5)13-18(2)14-22(30)6;/h11-16,31-32,35,37H,1-10H3;/b27-23+,28-25+,33-15?,34-16?;/t31-,32-;/m0./s1 |
| InChi Key | YQMKZEIIMHVFTI-VURWZECESA-N |
| Canonical SMILES | CC1=CC(=C(C(=C1)C)C(C(C2=C(C=C(C=C2C)C)C)N=CC(=C(C)O)C(=O)C)N=CC(=C(C)O)C(=O)C)C.[Co] |
| 分子式 |
C32H38CoN2O4 |
| PubChem CID | 135483535 |
| 分子量 | 573.6 |
化学和物理性质
| 敏感性 | 对空气敏感 |
|---|---|
| 熔点 | 242-246°C |
| 比旋光度 | [α]/D ?309°, c = 0.1 in chloroform |
安全信息
| 象形图 |
Health Hazard 
Harmful |
|---|---|
| 信号词 | Warning |
| 危险声明 |
H315: Causes skin irritation H319: Causes serious eye irritation H351: Suspected of causing cancer H302: Harmful if swallowed H312: Harmful in contact with skin H332: Harmful if inhaled |
| 预防措施声明 | P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P362+P364,P330,P203,P264+P265,P301+P317,P318,P317,P337+P317,P332+P317 |
| WGK Germany | 3 |
| 个人防护装备 | Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter |
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