| 规格或纯度 | 97% |
|---|---|
| 英文名称 | (1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) |
| 别名 | (R)-AMAC (R,R)-AMAC |
| 英文别名 | (R)-AMAC (R,R)-AMAC |
| 储存温度 | 充氩 |
| 运输条件 | 常规运输 |
| 产品介绍 |
Catalyst used for the enantioselective reduction of ketones, hetero Diels-Alder reaction, carbonylene reaction, 1,3-dipolar cycloaddition · Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds Catalyst for: Enantioselective borohydride reduction Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride Stereoselective borohydride reduction of diketones to diols Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones |
| IUPAC Name | (E)-3-[[(1R,2R)-2-[[(E)-2-acetyl-3-oxidobut-2-enylidene]amino]-1,2-bis(2,4,6-trimethylphenyl)ethyl]iminomethyl]-4-oxopent-2-en-2-olate;cobalt(2+) |
|---|---|
| INCHI | InChI=1S/C32H40N2O4.Co/c1-17-11-19(3)29(20(4)12-17)31(33-15-27(23(7)35)24(8)36)32(34-16-28(25(9)37)26(10)38)30-21(5)13-18(2)14-22(30)6;/h11-16,31-32,35,37H,1-10H3;/q;+2/p-2/b27-23+,28-25+,33-15?,34-16?;/t31-,32-;/m1./s1 |
| InChi Key | PHCQQLMRNZRDJA-SGIDGJHMSA-L |
| Canonical SMILES | CC1=CC(=C(C(=C1)C)C(C(C2=C(C=C(C=C2C)C)C)N=CC(=C(C)[O-])C(=O)C)N=CC(=C(C)[O-])C(=O)C)C.[Co+2] |
| 分子式 |
C32H38CoN2O4 |
| PubChem CID | 10120770 |
| 分子量 | 573.6 |
| 敏感性 | 对空气敏感 |
|---|---|
| 熔点 | 246-250°C |
| 比旋光度 | [α]/D 291°, c = 0.1 in chloroform |
| 象形图 |
Harmful |
|---|---|
| 信号词 | Warning |
| 危险声明 |
H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation H302: Harmful if swallowed H312: Harmful in contact with skin H332: Harmful if inhaled |
| 预防措施声明 | P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P317,P317,P337+P317,P332+P317,P319 |
| WGK Germany | 2 |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
首页
400-620-6333
危险品化学品经营许可证（带存储）