| 规格或纯度 | 98% |
|---|---|
| 英文名称 | Bis(2,4-dinitrophenyl) oxalate |
| 别名 | DNPO；草酸双(2,4-二硝基苯基)酯； 2,4-二硝基苯基草酸酯 |
| 英文别名 | Bis(2,4-dinitrophenyl) oxalate; DNPO;2,4-Dinitrophenyl oxalate; Oxalic acid bis(2,4-dinitrophenyl) ester |
| 储存温度 | 充氩 |
| 运输条件 | 常规运输 |
| 产品介绍 |
Bis(2,4-dinitrophenyl) oxalate (DPNO) has been used in detection of fluorescent compound dansylalanine in buffer solution by flow injection analysis. Chemiluminescence produced in the oxidation of DNPO by hydrogen peroxide in the presence of a polycyclic aromatic hydrocarbon was monitored by spectroscopic methods. The kinetics of the imidazole-catalyzed decomposition of DNPO was investigated by the stopped-flow technique. |
| IUPAC Name | bis(2,4-dinitrophenyl) oxalate |
|---|---|
| INCHI | InChI=1S/C14H6N4O12/c19-13(29-11-3-1-7(15(21)22)5-9(11)17(25)26)14(20)30-12-4-2-8(16(23)24)6-10(12)18(27)28/h1-6H |
| InChi Key | CBZOGAWUNMFXFQ-UHFFFAOYSA-N |
| Canonical SMILES | C1=CC(=C(C=C1[N+](=O)[O-])[N+](=O)[O-])OC(=O)C(=O)OC2=C(C=C(C=C2)[N+](=O)[O-])[N+](=O)[O-] |
| 分子式 |
C14H6N4O12 |
| PubChem CID | 3080704 |
| Beilstein号 | 2318321 |
| 分子量 | 422.22 |
| 溶解性 | 可溶于苯、甲苯 |
|---|---|
| 敏感性 | 对光线和湿度敏感 |
| 熔点 | 189-190°C |
| 象形图 |
Harmful |
|---|---|
| 信号词 | Warning |
| 危险声明 |
H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation |
| 预防措施声明 | P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319 |
| WGK Germany | 3 |
| Reaxy-Rn | 2318321 |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
| 1. W Baeyens,J Bruggeman,C Dewaele,B Lin,K Imai. (1990-01-01) Optimization of an HPLC peroxyoxalate chemiluminescence detection system for some dansyl amino acids.. Journal of bioluminescence and chemiluminescence, 5 ((1)): (13-23). [PMID:2316391] |
| 2. T Kawasaki,K Imai,T Higuchi,O S Wong. (1990-05-01) Determination of fluorescent cyanobenz[f]isoindole derivatives of dopamine and norepinephrine using high performance liquid chromatography with chemiluminescence detection.. Biomedical chromatography : BMC, 4 ((3)): (113-118). [PMID:2383692] |
| 3. M L Grayeski,W R Seitz. (1984-02-01) Determination of fluorophor-labeled compounds based on peroxyoxalate chemiluminescence.. Analytical biochemistry, 136 ((2)): (277-284). [PMID:6721131] |
| 4. M B Talawar,R Sivabalan,B G Polke,U R Nair,G M Gore,S N Asthana. (2005-06-28) Establishment of process technology for the manufacture of dinitrogen pentoxide and its utility for the synthesis of most powerful explosive of today--CL-20.. Journal of hazardous materials, 124 ((1-3)): (153-164). [PMID:15979786] |
| 5. Andrew G. Hadd,John W. Birks. (1996-04-19) Kinetics and Mechanism of the Nucleophilic Substitution Reaction of Imidazole with Bis(2,4,6-trichlorophenyl) Oxalate and Bis(2,4-dinitrophenyl) Oxalate.. The Journal of organic chemistry, 61 ((8)): (2657-2663). [PMID:11667095] |
| 6. José Antonio Murillo Pulgarín,Luisa F García Bermejo,M Nieves Sánchez García,Ignacio Sánchez-Ferrer Robles. (2011-04-05) Kinetic-spectrometric three-dimensional chemiluminescence as an effective analytical tool. Application to the determination of benzo(a)pyrene.. Analytica chimica acta, 691 ((1-2)): (76-82). [PMID:21458634] |
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