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1,2-双（二甲基瞵）乙烷
规格或纯度:
97%
- CAS编号: 23936-60-9
- 分子式: C6H16P2
- 分子量: 150.14
- Beilstein号: 1732994
- MDL号: MFCD00008511
- PubChem编号: 141059
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基本描述
| 规格或纯度 | 97% |
|---|---|
| 英文名称 | 1,2-Bis(dimethylphosphino)ethane |
| 别名 | 乙烯双(二甲膦)；1,2-双(二甲膦基)乙烷；1,2-双(二甲氧基磷基)-乙烷 |
| 英文别名 | DMPE ；Ethylenebis(dimethylphosphine)；Dimethyl-2-(dimethylphosphino)ethylphosphine |
| 储存温度 | 充氩 |
| 运输条件 | 常规运输 |
| 产品介绍 |
1,2-双（二甲基膦）乙烷 (dmpe) 是一种多齿膦配体。关于1，2-双（二甲基膦）乙烷的合成方法已有报道。它与 ZrCl 2 反应生成 ZrCl 4 (dmpe) 2 配合物。 1,2-双（二甲基膦）乙烷 (dmpe) 可作为配体用于 顺 芳基甲基 (dmpe) 镍 (II) 配合物的制备。 1,2-Bis(dimethylphosphino)ethane (dmpe) is a polydentate phosphine ligand. Synthesis of 1,2-bis(dimethylphosphino)ethane has been reported. It reacts with ZrCl2 to afford ZrCl4(dmpe)2 complexes. 1,2-Bis(dimethylphosphino)ethane (dmpe) may be employed as ligand in the preparation of cis-arylmethyl(dmpe) nickel(II) complexes. |
名称和标识符
| IUPAC Name | 2-dimethylphosphanylethyl(dimethyl)phosphane |
|---|---|
| INCHI | InChI=1S/C6H16P2/c1-7(2)5-6-8(3)4/h5-6H2,1-4H3 |
| InChi Key | ZKWQSBFSGZJNFP-UHFFFAOYSA-N |
| Canonical SMILES | CP(C)CCP(C)C |
| 分子式 |
C6H16P2 |
| UN Number | 1993 |
| PubChem CID | 141059 |
| Beilstein号 | 1732994 |
| 分子量 | 150.14 |
化学和物理性质
| 密度 | 0.9 |
|---|---|
| 敏感性 | 对空气敏感 |
| 沸点 | 180°C |
| 折光率 | 1.506-1.508 |
| 闪点(℉) | -16 °C |
| 闪点(℃) | -16°C |
安全信息
| 象形图 |
Harmful 
Flammable |
|---|---|
| 信号词 | Danger |
| 危险声明 |
H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation H225: Highly Flammable liquid and vapor H250: Catches fire spontaneously if exposed to air |
| 预防措施声明 | P261,P305+P351+P338,P280,P370+P378,P210,P302+P352,P321,P405,P501,P233,P240,P264,P403+P235,P222,P231,P303+P361+P353,P271,P241,P304+P340,P403+P233,P362+P364,P242,P243,P302+P335+P334,P264+P265,P337+P317,P332+P317,P319 |
| WGK Germany | 3 |
| Reaxy-Rn | 1732994 |
| 个人防护装备 | Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter |
参考文献
| 1. Quoc-Chon Le,Marie-Hélène Ropers,Hélène Terrisse,Bernard Humbert. (2014-09-23) Interactions between phospholipids and titanium dioxide particles.. Colloids and surfaces. B, Biointerfaces, 123 (): (150-157). [PMID:25242734] |
| 2. Mario Suwalsky,Pablo Zambrano,Fernando Villena,Marcela Manrique-Moreno,María José Gallardo,Malgorzata Jemiola-Rzeminska,Kazimierz Strzalka,Ana María Edwards,Sigrid Mennickent,Nathan Dukes. (2015-03-01) Morphological Effects Induced In Vitro by Propranolol on Human Erythrocytes.. The Journal of membrane biology, 248 ((4)): (683-693). [PMID:25724773] |
| 3. Mafumi Hishida,Asami Endo,Koyomi Nakazawa,Yasuhisa Yamamura,Kazuya Saito. (2015-05-11) Effect of n-alkanes on lipid bilayers depending on headgroups.. Chemistry and physics of lipids, 188 (): (61-67). [PMID:25957868] |
| 4. M Suwalsky,M Jemiola-Rzeminska,C Astudillo,M J Gallardo,J P Staforelli,F Villena,K Strzalka. (2015-08-25) An in vitro study on the antioxidant capacity of usnic acid on human erythrocytes and molecular models of its membrane.. Biochimica et biophysica acta, 1848 ((11 Pt A)): (2829-2838). [PMID:26299817] |
| 5. M A Morini,M B Sierra,V I Pedroni,L M Alarcon,G A Appignanesi,E A Disalvo. (2015-05-08) Influence of temperature, anions and size distribution on the zeta potential of DMPC, DPPC and DMPE lipid vesicles.. Colloids and surfaces. B, Biointerfaces, 131 (): (54-58). [PMID:25950496] |
| 6. Rudra N Purusottam,Lucile Sénicourt,Jean-Jacques Lacapère,Piotr Tekely. (2015-09-17) Probing the gel to liquid-crystalline phase transition and relevant conformation changes in liposomes by (13)C magic-angle spinning NMR spectroscopy.. Biochimica et biophysica acta, 1848 ((12)): (3134-3139). [PMID:26375416] |
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