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化学和生化试剂
高端化学
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膦配体
1,3-双(二苯膦基)丙烷

1,3-双(二苯膦基)丙烷

规格或纯度: 97%

CAS编号: 6737-42-4
分子式: C₂₇H₂₆P₂
分子量: 412.44
Beilstein号: 2821785
EC号: 229-791-2
MDL号: MFCD00003050
PubChem编号: 81219

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货号 (SKU)	包装规格	是否现货	价格	数量
B111136-5g	5g	现货
B111136-10g	10g	现货
B111136-25g	25g	现货
B111136-100g	100g	现货
B111136-500g	500g	现货
B111136-1kg	1kg	现货

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元素分类的化合物磷化合物

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基本描述

规格或纯度	97%
英文名称	1,3-Bis(diphenylphosphino)propane
别名	1,3-双(二苯基膦基)丙烷；三亚甲基双(二苯基膦)；双-二苯基膦丙烷
英文别名	dppp;Trimethylenebis(diphenylphosphine)
储存温度	充氩
运输条件	常规运输

名称和标识符

EC号	229-791-2
IUPAC Name	3-diphenylphosphanylpropyl(diphenyl)phosphane
INCHI	InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChi Key	LVEYOSJUKRVCCF-UHFFFAOYSA-N
Canonical SMILES	C1=CC=C(C=C1)P(CCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4
分子式	C₂₇H₂₆P₂
PubChem CID	81219
Beilstein号	2821785
分子量	412.44

化学和物理性质

溶解性	Insoluble in water.
敏感性	对空气敏感
熔点	57-63°C

安全信息

象形图	Harmful
信号词	Warning
危险声明	H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation
预防措施声明	P261,P305+P351+P338,P280,P302+P352,P405,P501,P264,P271,P337+P313,P403+P233,P332+P313,P304+P340+P312
WGK Germany	3
Reaxy-Rn	2821785
个人防护装备	dust mask type N95 (US),Eyeshields,Gloves

参考文献

1. Heyan Jiang,Diya Geng,Dapeng Liu,Nicholas Lanigan,Xiaosong Wang. (2017-03-24) Flexibility and Stability of Metal Coordination Macromolecules.. Chemistry (Weinheim an der Bergstrasse, Germany), 23 ((34)): (8280-8285). [PMID:28334462]
2. Zelinda Engelbrecht,Kariska Potgieter,Zanele Mpela,Rehana Malgas-Enus,Reinout Meijboom,Marianne J Cronje. (2017-05-23) A Comparison of the Toxicity of Mono, Bis, Tris and Tetrakis Phosphino Silver Complexes on SNO Esophageal Cancer Cells.. Anti-cancer agents in medicinal chemistry, 18 ((3)): (394-400). [PMID:28530542]
3. Jeong Eon Park,Mei Jing Piao,Kyoung Ah Kang,Kristina Shilnikova,Yu Jae Hyun,Sei Kwan Oh,Yong Joo Jeong,Sungwook Chae,Jin Won Hyun. (2017-05-31) A Benzylideneacetophenone Derivative Induces Apoptosis of Radiation-Resistant Human Breast Cancer Cells via Oxidative Stress.. Biomolecules & therapeutics, 25 ((4)): (404-410). [PMID:28554201]
4. Wanessa Carvalho Pires,Benedicto Augusto Vieira Lima,Flávia de Castro Pereira,Aliny Pereira Lima,Francyelli Mello-Andrade,Hugo Delleon Silva,Monize Martins da Silva,Legna Colina-Vegas,Javier Ellena,Alzir A Batista,Elisangela de Paul Silveira-Lacerda. (2017-08-11) Ru(II)/diphenylphosphine/pyridine-6-thiolate complexes induce S-180 cell apoptosis through intrinsic mitochondrial pathway involving inhibition of Bcl-2 and p53/Bax activation.. Molecular and cellular biochemistry, 438 ((1-2)): (199-217). [PMID:28795366]
5. Noora Svahn,Artur J Moro,Catarina Roma-Rodrigues,Rakesh Puttreddy,Kari Rissanen,Pedro V Baptista,Alexandra R Fernandes,Jo?o Carlos Lima,Laura Rodríguez. (2018-08-01) The Important Role of the Nuclearity, Rigidity, and Solubility of Phosphane Ligands in the Biological Activity of Gold(I) Complexes.. Chemistry (Weinheim an der Bergstrasse, Germany), 24 ((55)): (14654-14667). [PMID:30063270]
6. Mohammed Zain Aldin,Anthony Maho,Guillermo Zaragoza,Albert Demonceau,Lionel Delaude. (2018-09-19) Synthesis, characterization, and catalytic evaluation of ruthenium-diphosphine complexes bearing xanthate ligands.. Dalton transactions (Cambridge, England : 2003), 47 ((39)): (13926-13938). [PMID:30226523]
7. Vivianne S Velozo-Sá,Luciano R Pereira,Aliny P Lima,Francyelli Mello-Andrade,Manuela R M Rezende,Rebeca M Goveia,Wanessa C Pires,Monize M Silva,Katia M Oliveira,Antonio G Ferreira,Javier Ellena,Victor M Deflon,Cesar Koppe Grisolia,Alzir A Batista,Elisangela P Silveira-Lacerda. (2019-02-07) In vitro cytotoxicity and in vivo zebrafish toxicity evaluation of Ru(ii)/2-mercaptopyrimidine complexes.. Dalton transactions (Cambridge, England : 2003), 48 ((18)): (6026-6039). [PMID:30724926]
8. Renxuan Xie,Albree R Weisen,Youngmin Lee,Melissa A Aplan,Abigail M Fenton,Ashley E Masucci,Fabian Kempe,Michael Sommer,Christian W Pester,Ralph H Colby,Enrique D Gomez. (2020-02-16) Glass transition temperature from the chemical structure of conjugated polymers.. Nature communications, 11 ((1)): (893-893). [PMID:32060331]
9. Nathália Cristina Campanella,Mariana da Silva Demartini,Claudia Torres,Eduardo Tonon de Almeida,Cibele Marli Ca??o Paiva Gouvêa. (2012-04-07) The cytotoxic and growth inhibitory effects of palladium(II) complexes on MDA-MB-435 cells.. Genetics and molecular biology, 35 ((1)): (159-163). [PMID:22481890]
10. Inmaculada Mena,Pilar García-Ordu?a,Víctor Polo,Fernando J Lahoz,Miguel A Casado,Luis A Oro. (2017-08-19) Reactivity of the parent amido complexes of iridium with olefins: C-NH. Dalton transactions (Cambridge, England : 2003), 46 ((34)): (11459-11468). [PMID:28820211]

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