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4-溴苯乙酮

规格或纯度: 98%

CAS编号: 99-90-1
分子式: C₈H₇BrO
分子量: 199.04
Beilstein号: 386015
EC号: 202-799-3
MDL号: MFCD00000105
PubChem编号: 7466

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货号 (SKU)	包装规格	是否现货	价格	数量
B106981-25g	25g	现货
B106981-100g	100g	现货
B106981-500g	500g	现货
B106981-2.5kg	2.5kg	现货

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基本描述

规格或纯度	98%
英文名称	4'-Bromoacetophenone
别名	对溴苯乙酮\|1-乙酰基-4-溴苯
英文别名	4'-Bromoacetophenone\|99-90-1\|1-(4-Bromophenyl)ethanone\|p-Bromoacetophenone\|4-BROMOACETOPHENONE\|1-(4-bromophenyl)ethan-1-one\|Ethanone, 1-(4-bromophenyl)-\|1-Acetyl-4-bromobenzene\|Methyl p-bromophenyl ketone\|Acetophenone, 4'-bromo-\|p-Bromophenyl methyl keton
运输条件	常规运输
产品介绍	溶于乙醇、乙醚、冰醋酸、苯、二硫化碳和石油醚，不溶于水。易随水蒸气挥发。有机合成中间体。用于染料、医药及试剂。

名称和标识符

EC号	202-799-3
IUPAC Name	1-(4-bromophenyl)ethanone
INCHI	InChI=1S/C8H7BrO/c1-6(10)7-2-4-8(9)5-3-7/h2-5H,1H3
InChi Key	WYECURVXVYPVAT-UHFFFAOYSA-N
Canonical SMILES	CC(=O)C1=CC=C(C=C1)Br
WGK Germany	3
PubChem CID	7466
分子量	199.04
Beilstein号	386015
Reaxy-Rn	386015

化学和物理性质

溶解性	Soluble in Chloroform. Insoluble in water.
密度	1.6502
闪点(℉)	235.4 °F
闪点(℃)	>110℃
沸点	255.5°C
熔点	51°C

安全和危险性（GHS）

象形图	Health Hazard Harmful
信号词	Danger
危险声明	H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation H302: Harmful if swallowed H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled
预防措施声明	P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P284,P271,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P317,P337+P317,P332+P317,P319,P342+P316
WGK Germany	3
Reaxy-Rn	386015
Merck Index	1403
个人防护装备	dust mask type N95 (US),Eyeshields,Faceshields,Gloves

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参考文献

1. Gagan Chouhan,Dashan Wang,Howard Alper. (2007-11-16) Magnetic nanoparticle-supported proline as a recyclable and recoverable ligand for the CuI catalyzed arylation of nitrogen nucleophiles.. Chemical communications (Cambridge, England), ((45)(45)): (4809-4811). [PMID:18004449]
2. Koji Uwai,Noboru Konno,Yuka Yasuta,Mitsuhiro Takeshita. (2007-11-17) Electronic effects of para-substitution on acetophenones in the reaction of rat liver 3alpha-hydroxysteroid dehydrogenase.. Bioorganic & medicinal chemistry, 16 ((3)): (1084-1089). [PMID:18006320]
3. Franziska Schneider,Bernd Ondruschka. (2008-08-15) Mechanochemical solid-state Suzuki reactions using an in situ generated base.. ChemSusChem, 1 ((7)): (622-625). [PMID:18702163]
4. Daniel Duncan,Eric G Hope,Kuldip Singh,Alison M Stuart. (2011-01-26) A recyclable perfluoroalkylated PCP pincer palladium complex.. Dalton transactions (Cambridge, England : 2003), 40 ((9)): (1998-2005). [PMID:21264422]
5. Lidiane S Araújo,Edna Kagohara,Thaís P Garcia,Vivian H Pellizari,Leandro H Andrade. (2011-06-16) Screening of microorganisms producing cold-active oxidoreductases to be applied in enantioselective alcohol oxidation. An Antarctic survey.. Marine drugs, 9 ((5)): (889-905). [PMID:21673897]
6. Kunpeng Li,Rongzhen Zhang,Yan Xu,Zhimeng Wu,Jing Li,Xiaotian Zhou,Jiawei Jiang,Haiyan Liu,Rong Xiao. (2017-06-10) Sortase A-mediated crosslinked short-chain dehydrogenases/reductases as novel biocatalysts with improved thermostability and catalytic efficiency.. Scientific reports, 7 ((1)): (3081-3081). [PMID:28596548]
7. R Tung,L M Lichtenstein. (1982-05-01) In vitro histamine release from basophils of asthmatic and atopic individuals in D2O.. Journal of immunology (Baltimore, Md. : 1950), 128 ((5)): (2067-2072). [PMID:6174620]

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