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硫酸铍 四水合物

规格或纯度: 99%
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货号 (SKU) 包装规格 是否现货 价格 数量
B106712-5g 5g 现货 Stock Image
B106712-25g 25g 现货 Stock Image
B106712-100g 100g 现货 Stock Image

基本描述

规格或纯度 99%
英文名称 Beryllium sulfate tetrahydrate
别名 硫酸铍
运输条件 常规运输
产品介绍

极毒!在100℃失去二分子结晶水,在400℃失去全部结晶水。溶于水,不溶于乙醇,微溶于浓硫酸。加热至高温时分解为氧化铍和三氧化硫。 用于研究铍与二羧酸酯的螯合作用,以了解铍的生理化学。

Usually used in study of the dicarboxylate chelation of beryllium in an attempt to understand its physiological chemistry.

名称和标识符

EC号 236-842-2
IUPAC Name beryllium;sulfate;tetrahydrate
INCHI InChI=1S/Be.H2O4S.4H2O/c;1-5(2,3)4;;;;/h;(H2,1,2,3,4);4*1H2/q+2;;;;;/p-2
InChi Key DIMYTQPLZWDZFE-UHFFFAOYSA-L
Canonical SMILES [Be+2].O.O.O.O.[O-]S(=O)(=O)[O-]
分子式

BeSO4·4H2O

UN Number 1566
PubChem CID 62672
分子量 177.14

化学和物理性质

溶解性 Soluble in water (425 mg/ml at 25 °C). Insoluble in alcohol.
密度 1.713

安全信息

一般危化品 一般危化品
象形图
ghs06

Toxic

ghs08

Health Hazard

ghs09

Environmental Hazard

信号词 Danger
危险声明 H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
H301: Toxic if swallowed
H411: Toxic to aquatic life with long lasting effects
H317: May cause an allergic skin reaction
H330: Fatal if inhaled
H372: Causes damage to organs through prolonged or repeated exposure
H350i: May cause cancer by inhalation
H350: May cause cancer
预防措施声明 P261,P305+P351+P338,P273,P280,P302+P352,P321,P405,P501,P264,P260,P284,P271,P270,P304+P340,P403+P233,P272,P333+P313,P362+P364,P391,P330,P320,P203,P264+P265,P301+P316,P318,P337+P317,P332+P317,P316,P319
WGK Germany 3
RTECS DS5000000
个人防护装备 Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges

参考文献

1. E A Ojo-Amaize,M S Agopian,J B Peter.  (1994-03-01)  Novel in vitro method for identification of individuals at risk for beryllium hypersensitivity..  Clinical and diagnostic laboratory immunology,  ((2)):  (164-171).  [PMID:7496939]
2. E A Ojo-Amaize,M S Agopian,J B Peter.  (1994-03-01)  Novel in vitro method for identification of individuals at risk for beryllium hypersensitivity..  Clinical and diagnostic laboratory immunology,  ((2)):  (164-171).  [PMID:7496939]
3. S Pfeifer,R Bartlett,J Strausz,S Haller,J Müller-Quernheim.  (1994-08-01)  Beryllium-induced disturbances of the murine immune system reflect some phenomena observed in sarcoidosis..  International archives of allergy and immunology,  104  ((4)):  (332-339).  [PMID:8038611]
4. D Zissu,S Binet,C Cavelier.  (1996-03-01)  Patch testing with beryllium alloy samples in guinea pigs..  Contact dermatitis,  34  ((3)):  (196-200).  [PMID:8833464]
5. P Victoratos,M Yiangou,N Avramidis,L Hadjipetrou.  (1997-10-27)  Regulation of cytokine gene expression by adjuvants in vivo..  Clinical and experimental immunology,  109  ((3)):  (569-578).  [PMID:9328138]
6. S S Tinkle,L S Newman.  (1997-12-31)  Beryllium-stimulated release of tumor necrosis factor-alpha, interleukin-6, and their soluble receptors in chronic beryllium disease..  American journal of respiratory and critical care medicine,  156  ((6)):  (1884-1891).  [PMID:9412570]
7. A P Fontenot,M Torres,W H Marshall,L S Newman,B L Kotzin.  (2000-10-26)  Beryllium presentation to CD4+ T cells underlies disease-susceptibility HLA-DP alleles in chronic beryllium disease..  Proceedings of the National Academy of Sciences of the United States of America,  97  ((23)):  (12717-12722).  [PMID:11050177]
8. N M Lehnert,R K Gary,B L Marrone,B E Lehnert.  (2001-03-14)  Inhibition of normal human lung fibroblast growth by beryllium..  Toxicology,  160  ((1-3)):  (119-127).  [PMID:11246132]
9. A P Fontenot,L S Newman,B L Kotzin.  (2001-06-21)  Chronic beryllium disease: T cell recognition of a metal presented by HLA-DP..  Clinical immunology (Orlando, Fla.),  100  ((1)):  (4-14).  [PMID:11414740]
10. P Joseph,T Muchnok,T Ong.  (2001-09-25)  Gene expression profile in BALB/c-3T3 cells transformed with beryllium sulfate..  Molecular carcinogenesis,  32  ((1)):  (28-35).  [PMID:11568973]
11. Andrew P Fontenot,Lisa A Maier,Scott J Canavera,Tara B Hendry-Hofer,Mark Boguniewicz,Elizabeth A Barker,Lee S Newman,Brian L Kotzin.  (2002-03-22)  Beryllium skin patch testing to analyze T cell stimulation and granulomatous inflammation in the lung..  Journal of immunology (Baltimore, Md. : 1950),  168  ((7)):  (3627-3634).  [PMID:11907128]
12. Andrew P Fontenot,Scott J Canavera,Laia Gharavi,Lee S Newman,Brian L Kotzin.  (2002-11-20)  Target organ localization of memory CD4(+) T cells in patients with chronic beryllium disease..  The Journal of clinical investigation,  110  ((10)):  (1473-1482).  [PMID:12438445]
13. Anu Chaudhary,Nancy N Sauer,Goutam Gupta.  (2004-08-07)  Beryllium-specific immune response in primary cells from healthy individuals..  Toxicology,  201  ((1-3)):  (9-19).  [PMID:15297015]
14. Kristin K Nelson,Sita Subbaram,Kip M Connor,Jaya Dasgupta,Xiao-Fang Ha,Tzu-Ching Meng,Nicholas K Tonks,J Andres Melendez.  (2006-03-30)  Redox-dependent matrix metalloproteinase-1 expression is regulated by JNK through Ets and AP-1 promoter motifs..  The Journal of biological chemistry,  281  ((20)):  (14100-14110).  [PMID:16569638]
15. Chadi H Stephan,Sébastien Sauvé,Michel Fournier,Pauline Brousseau.  (2008-09-13)  Use of proliferation tests to evaluate the effects of complexing agents on beryllium toxicity..  Journal of applied toxicology : JAT,  29  ((1)):  (27-35).  [PMID:18785683]
16. Priyatham Gorjala,Ronald K Gary.  (2010-06-16)  Beryllium sulfate induces p21 CDKN1A expression and a senescence-like cell cycle arrest in susceptible cancer cell types..  Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine,  23  ((6)):  (1061-1073).  [PMID:20549306]
17. Marguerite K McDonald,Edward J Miracco,Junjun Chen,Yizhou Xie,Eugene G Mueller.  (2010-12-15)  The handling of the mechanistic probe 5-fluorouridine by the pseudouridine synthase TruA and its consistency with the handling of the same probe by the pseudouridine synthases TruB and RluA..  Biochemistry,  50  ((3)):  (426-436).  [PMID:21142053]
18. C A Bobka,L A Stewart,G J Engelken,L E Golitz,L S Newman.  (1997-06-01)  Comparison of in vivo and in vitro measures of beryllium sensitization..  Journal of occupational and environmental medicine,  39  ((6)):  (540-547).  [PMID:9211212]
19. J Schreiber,G Zissel,U Greinert,J Galle,K H Schulz,M Schlaak,J Müller-Quernheim.  (1999-07-20)  [Diagnosis of chronic berylliosis]..  Pneumologie (Stuttgart, Germany),  53  ((4)):  (193-198).  [PMID:10409861]
20. S S Tinkle,L A Kittle,L S Newman.  (1999-08-24)  Partial IL-10 inhibition of the cell-mediated immune response in chronic beryllium disease..  Journal of immunology (Baltimore, Md. : 1950),  163  ((5)):  (2747-2753).  [PMID:10453017]
21. N Keshava,G Zhou,M Spruill,M Ensell,T M Ong.  (2001-10-27)  Carcinogenic potential and genomic instability of beryllium sulphate in BALB/c-3T3 cells..  Molecular and cellular biochemistry,  222  ((1-2)):  (69-76).  [PMID:11678613]
22. Richard T Sawyer,David R Dobis,Mark Goldstein,Leonard Velsor,Lisa A Maier,Andrew P Fontenot,Lori Silveira,Lee S Newman,Brian J Day.  (2005-03-08)  Beryllium-stimulated reactive oxygen species and macrophage apoptosis..  Free radical biology & medicine,  38  ((7)):  (928-937).  [PMID:15749389]
23. Kirsten J Taylor-McCabe,Zaolin Wang,Nancy N Sauer,Babetta L Marrone.  (2006-02-01)  Proteomic analysis of beryllium-induced genotoxicity in an Escherichia coli mutant model system..  Proteomics,  ((5)):  (1663-1675).  [PMID:16447159]
24. Shannan Rodriguez,Yuliya A Kunde,T Mark McCleskey,Elizabeth Hong-Geller.  (2008-06-10)  Upregulation of I-CAM1 in response to beryllium exposure in small airway epithelial cells..  Toxicology letters,  179  ((3)):  (140-147).  [PMID:18539414]
25. Wolfram W Rudolph,Dieter Fischer,Gert Irmer,Cory C Pye.  (2009-08-13)  Hydration of beryllium(II) in aqueous solutions of common inorganic salts. A combined vibrational spectroscopic and ab initio molecular orbital study..  Dalton transactions (Cambridge, England : 2003),  (33)  ((33)):  (6513-6527).  [PMID:19672497]
26. Shannon Silva,Kumkum Ganguly,Theresa M Fresquez,Goutam Gupta,T Mark McCleskey,Anu Chaudhary.  (2009-11-07)  Beryllium alters lipopolysaccharide-mediated intracellular phosphorylation and cytokine release in human peripheral blood mononuclear cells..  Journal of occupational and environmental hygiene,  ((12)):  (775-782).  [PMID:19894180]
27. Fabiana Paladini,Elisa Cocco,Ilaria Potolicchio,Henrieta Fazekasova,Giovanna Lombardi,Maria Teresa Fiorillo,Rosa Sorrentino.  (2010-10-27)  Divergent effect of cobalt and beryllium salts on the fate of peripheral blood monocytes and T lymphocytes..  Toxicological sciences : an official journal of the Society of Toxicology,  119  ((2)):  (257-269).  [PMID:20974702]
28. Mark A Vincent,Ian H Hillier.  (2011-01-20)  The structure and interaction energies of the weak complexes of CHClF2 and CHF3 with HCCH: a test of density functional theory methods..  Physical chemistry chemical physics : PCCP,  13  ((10)):  (4388-4392).  [PMID:21246115]
29. Andreas J Bircher.  (2011-05-14)  Patch tests with beryllium salts..  Contact dermatitis,  64  ((6)):  (363-364).  [PMID:21564131]

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