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2-过氧化丁酮

规格或纯度: 约30%于邻苯二甲酸二甲酯中
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货号 (SKU) 包装规格 是否现货 价格 数量
B105747-25ml 25ml 现货 Stock Image
B105747-100ml 100ml 现货 Stock Image
B105747-500ml 500ml 现货 Stock Image
B105747-2.5L 2.5L 现货 Stock Image

基本描述

规格或纯度 约30%于邻苯二甲酸二甲酯中
英文名称 2-Butanone peroxide
别名 过氧化甲乙酮
英文别名 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane;Methyl ethyl ketone peroxide; Ethyl methyl ketone peroxide(ca. 50% in Dimethyl Phthalate)
应用 不饱和聚酯树脂常温固化引发剂.
储存温度 2-8°C储存
运输条件 冰袋运输
产品介绍

具有宜人气味。在室温下稳定上,当温度高于100℃时即发生爆炸。不饱和聚酯树脂常温固化引发剂.

2-Butanone peroxide is an analyte useful in a variety of quantification applications, such as direct electrochemical catalysis of immobilized Hb in an ethanol-water mixture. 2-Butanone peroxide is also useful for oxidation of nucleoside phosphites into phosphates.

名称和标识符

分子式


化学和物理性质

密度 1.053

安全信息

一般危化品 一般危化品
象形图
ghs08

Health Hazard

ghs05

Corrosive

ghs02

Flammable

信号词 Danger
危险声明 H314: Causes severe skin burns and eye damage
H412: Harmful to aquatic life with long lasting effects
H242: Heating may cause a fire
H361d: Suspected of damaging the unborn child
预防措施声明 P305+P351+P338,P273,P280,P370+P378,P210,P303+P361+P353

参考文献

1. T Akaike,K Sato,S Ijiri,Y Miyamoto,M Kohno,M Ando,H Maeda.  (1992-04-01)  Bactericidal activity of alkyl peroxyl radicals generated by heme-iron-catalyzed decomposition of organic peroxides..  Archives of biochemistry and biophysics,  294  ((1)):  (55-63).  [PMID:1312811]
2. M Blazquez,P Laurent-Puig,D Chataigner,J C Delchier.  (1991-01-01)  [Caustic esophago-gastric and liver lesions caused by ingestion of a plastic resin hardener]..  Gastroenterologie clinique et biologique,  15  ((6-7)):  (554-555).  [PMID:1916136]
3. P J Karhunen,I Ojanper?,K Lalu,E Vuori.  (1990-05-01)  Peripheral zonal hepatic necrosis caused by accidental ingestion of methyl ethyl ketone peroxide..  Human & experimental toxicology,  ((3)):  (197-200).  [PMID:2375889]
4. M Ando.  (1986-06-01)  [An organic peroxide, methyl ethyl ketone peroxide, damage to cytochrome P-450 peroxidase and microsomal enzymes activity]..  Nihon eiseigaku zasshi. Japanese journal of hygiene,  41  ((2)):  (587-592).  [PMID:3020288]
5. J Chaudiere,M Clement,D Gerard,J M Bourre.  (1988-01-01)  Brain alterations induced by vitamin E deficiency and intoxication with methyl ethyl ketone peroxide..  Neurotoxicology,  ((2)):  (173-179).  [PMID:3205427]
6. R E Mittleman,L A Romig,E Gressmann.  (1986-01-01)  Suicide by ingestion of methyl ethyl ketone peroxide..  Journal of forensic sciences,  31  ((1)):  (312-320).  [PMID:3944573]
7. M Ando,A L Tappel.  (1985-12-01)  Methyl ethyl ketone peroxide damage to cytochrome P-450 peroxidase activities..  Toxicology and applied pharmacology,  81  ((3 Pt 1)):  (517-524).  [PMID:4082198]
8. A Prez-Martnez,C Gutirrez-Junquera,J Gonzlvez-Piera,A Marco-Macin,J R Rubio-Guijarro,M Moya-Marchante.  (1998-02-07)  Oesophageal stenosis in a child caused by ingestion of methyl ethyl ketone peroxide..  European journal of pediatrics,  156  ((12)):  (976-977).  [PMID:9453386]
9. D Chataigner,R Garnier,A Reygagne,M Blasquez,M L Efthymiou.  (1992-10-01)  [Chemical burns of the upper digestive tract and cytolytic hepatitis following ingestion of a mixture of methyl ethyl ketone peroxide, diacetone alcohol and diisobutyl phthalate]..  Journal de toxicologie clinique et experimentale,  12  ((4-5)):  (205-206).  [PMID:1295970]
10. M Bhushan,N M Craven,M H Beck.  (1998-11-17)  Contact allergy to methyl ethyl ketone peroxide and cobalt in the manufacture of fibreglass-reinforced plastics..  Contact dermatitis,  39  ((4)):  (203-203).  [PMID:9817235]
11. Ron-Hsin Chang,Chi-Min Shu,Yih-Shing Duh,Jih-Mirn Jehng.  (2006-09-05)  Calorimetric studies on the thermal hazard of methyl ethyl ketone peroxide with incompatible substances..  Journal of hazardous materials,  141  ((3)):  (762-768).  [PMID:16949744]
12. Yan-Fu Lin,Jo-Ming Tseng,Tsung-Chih Wu,Chi-Min Shu.  (2007-11-09)  Effects of acetone on methyl ethyl ketone peroxide runaway reaction..  Journal of hazardous materials,  153  ((3)):  (1071-1077).  [PMID:17988795]
13. C C G van Enckevort,D J Touw,L-J Vleming.  (2008-01-02)  N-acetylcysteine and hemodialysis treatment of a severe case of methyl ethyl ketone peroxide intoxication..  Clinical toxicology (Philadelphia, Pa.),  46  ((1)):  (74-78).  [PMID:18167039]
14. Jing Zhang,Wei Wu,Gang Qian,Xing-Gui Zhou.  (2010-06-18)  Continuous synthesis of methyl ethyl ketone peroxide in a microreaction system with concentrated hydrogen peroxide..  Journal of hazardous materials,  181  ((1-3)):  (1024-1030).  [PMID:20554382]
15. M V S Subbalaxmi,S Abkari,V R Srinivasan,A Krishnaprasad.  (2010-10-19)  Methyl ethyl ketone peroxide ingestion: a rare cause of corrosive chemical poisoning..  The National medical journal of India,  23  ((3)):  (150-151).  [PMID:20949717]
16. L Stewart,M H Beck.  (1992-01-01)  Contact sensitivity to methyl ethyl ketone peroxide in a paint sprayer..  Contact dermatitis,  26  ((1)):  (52-53).  [PMID:1534735]
17. D L Warren,D J Reed.  (1991-02-15)  Modification of hepatic vitamin E stores in vivo. I. Alterations in plasma and liver vitamin E content by methyl ethyl ketone peroxide..  Archives of biochemistry and biophysics,  285  ((1)):  (45-52).  [PMID:1990980]
18. F T Fraunfelder,D J Coster,R Drew,F W Fraunfelder.  (1990-12-15)  Ocular injury induced by methyl ethyl ketone peroxide..  American journal of ophthalmology,  110  ((6)):  (635-640).  [PMID:2248327]
19. M Ando,A L Tappel.  (1985-11-01)  Effect of dietary vitamin E on methyl ethyl ketone peroxide damage to microsomal cytochrome P-450 peroxidase..  Chemico-biological interactions,  55  ((3)):  (317-326).  [PMID:4075438]
20. G V Skúladóttir,D Shi-Hua,A E Brodie,D J Reed,R C Wander.  (1994-05-01)  Effects of dietary oils and methyl ethyl ketone peroxide on in vivo lipid peroxidation and antioxidants in rat heart and liver..  Lipids,  29  ((5)):  (351-357).  [PMID:8015366]
21. N Bates,C P Driver,A Bianchi.  (2001-08-03)  Methyl ethyl ketone peroxide ingestion: toxicity and outcome in a 6-year-old child..  Pediatrics,  108  ((2)):  (473-476).  [PMID:11483819]
22. Keiko Minamoto,Megumi Nagano,Tsukasa Inaoka,Makoto Futatsuka.  (2002-03-29)  Allergic contact dermatitis due to methyl ethyl ketone peroxide, cobalt naphthenate and acrylates in the manufacture of fibreglass-reinforced plastics..  Contact dermatitis,  46  ((1)):  (58-59).  [PMID:11918594]
23. Jo-Ming Tseng,Ying-Yu Chang,Teh-Sheng Su,Chi-Min Shu.  (2006-08-15)  Study of thermal decomposition of methyl ethyl ketone peroxide using DSC and simulation..  Journal of hazardous materials,  142  ((3)):  (765-770).  [PMID:16905247]
24. Jen-Hao Chi,Sheng-Hung Wu,Chi-Min Shu.  (2009-07-22)  Thermal explosion analysis of methyl ethyl ketone peroxide by non-isothermal and isothermal calorimetric applications..  Journal of hazardous materials,  171  ((1-3)):  (1145-1149).  [PMID:19619941]
25. M N Bozdemir,M Yildiz,E S Seyhanli,S Gurbuz,I Kilicaslan,T Karlidag.  (2011-04-22)  Narrowing of airway caused by ingestion of methyl ethyl ketone peroxide..  Human & experimental toxicology,  30  ((12)):  (2002-2006).  [PMID:21508070]

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