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2-氨基嘧啶

规格或纯度: 98%
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货号 (SKU) 包装规格 是否现货 价格 数量
A109732-10g
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A109732-25g
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A109732-100g
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A109732-250g
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A109732-500g
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六元杂环化合物 嘧啶类
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基本描述

规格或纯度 98%
英文名称 2-Aminopyrimidine
别名 2-嘧啶胺,2-嘧啶基胺
英文别名 2-AMINOPYRIMIDINE|pyrimidin-2-amine|109-12-6|2-Pyrimidinamine|Pyrimidin-2-ylamine|Aminopyrimidine|2-Pyrimidiylamine|Pyrimidine, 2-amino-|2-amino-pyrimidine|1,2-Dihydro-2-iminopyrimidine|153824-54-5|Pyrimidinamine|2(1H)-Pyrimidinimine (9CI)|2(1H)-Pyrimidin
应用 用于有机合成，作医药中间体、生化试剂。
储存温度 避光
运输条件 常规运输
产品介绍

易溶于水、醇、丙酮和氯仿，微溶于乙醚、苯。易升华。


名称和标识符

EC号 203-648-4
IUPAC Name pyrimidin-2-amine
INCHI InChI=1S/C4H5N3/c5-4-6-2-1-3-7-4/h1-3H,(H2,5,6,7)
InChi Key LJXQPZWIHJMPQQ-UHFFFAOYSA-N
Canonical SMILES C1=CN=C(N=C1)N
WGK Germany 3
RTECS UV6326000
PubChem CID 7978
分子量 95.1
Beilstein号 107014
Reaxy-Rn 107014

化学和物理性质

溶解性 可溶于水；可溶于甲醇
密度 1.216
闪点(℉) 103 °C
闪点(℃) 103°C
沸点 158°C
熔点 127°C

安全和危险性（GHS）

象形图
ghs07

Harmful
信号词 Warning
危险声明 H315: Causes skin irritation
H319: Causes serious eye irritation
H303: May be harmful if swallowed
预防措施声明 P305+P351+P338,P280,P302+P352,P312,P264,P362+P364
WGK Germany 3
RTECS UV6326000
Reaxy-Rn 107014
个人防护装备 dust mask type N95 (US),Eyeshields,Gloves

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参考文献

1. Teruyoshi Kitamura,Atushi Hikita,Hironori Ishikawa,Akira Fujimoto.  (2005-06-28)  Photoinduced amino-imino tautomerization reaction in 2-aminopyrimidine and its methyl derivatives with acetic acid..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  62  ((4-5)):  (1157-1164).  [PMID:15978861]
2. Ye-Xiang Xie,Shao-Feng Pi,Jian Wang,Du-Lin Yin,Jin-Heng Li.  (2006-10-10)  2-aminopyrimidine-4,6-diol as an efficient ligand for solvent-free copper-catalyzed N-arylations of imidazoles with aryl and heteroaryl halides..  The Journal of organic chemistry,  71  ((21)):  (8324-8327).  [PMID:17025338]
3. S A Abdel-Latif,H B Hassib,Y M Issa.  (2006-11-07)  Studies on some salicylaldehyde Schiff base derivatives and their complexes with Cr(III), Mn(II), Fe(III), Ni(II) and Cu(II)..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  67  ((3-4)):  (950-957).  [PMID:17084104]
4. Adel M Awadallah,Jalal A Zahra.  (2008-02-09)  Reaction of nitrilimines with 2-substituted aza-heterocycles. Synthesis of pyrrolo[1,2-a]pyridine and pyrimido[2,1-d]1,2,3,5- tetrazine..  Molecules (Basel, Switzerland),  13  ((1)):  (170-176).  [PMID:18259139]
5. Robert J Altenbach,Ronald M Adair,Brian M Bettencourt,Lawrence A Black,Shannon R Fix-Stenzel,Sujatha M Gopalakrishnan,Gin C Hsieh,Huaqing Liu,Kennan C Marsh,Michael J McPherson,Ivan Milicic,Thomas R Miller,Timothy A Vortherms,Usha Warrior,Jill M Wetter,Neil Wishart,David G Witte,Prisca Honore,Timothy A Esbenshade,Arthur A Hancock,Jorge D Brioni,Marlon D Cowart.  (2008-09-25)  Structure-activity studies on a series of a 2-aminopyrimidine-containing histamine H4 receptor ligands..  Journal of medicinal chemistry,  51  ((20)):  (6571-6580).  [PMID:18811133]
6. Graham Smith,Urs D Wermuth,Jonathan M White.  (2009-03-07)  Zero-, one- and two-dimensional hydrogen-bonded structures in the 1:1 proton-transfer compounds of 4,5-dichlorophthalic acid with the monocyclic heteroaromatic Lewis bases 2-aminopyrimidine, nicotinamide and isonicotinamide..  Acta crystallographica. Section C, Crystal structure communications,  65  ((Pt 3)):  (o103-o107).  [PMID:19265221]
7. Manuel Tzouros,Axel P?hler.  (2009-03-26)  A targeted proteomics approach to the identification of peptides modified by reactive metabolites..  Chemical research in toxicology,  22  ((5)):  (853-862).  [PMID:19317514]
8. Paul S Humphries,Jennifer A Lafontaine,Charles S Agree,David Alexander,Ping Chen,Quyen-Quyen T Do,Lilian Y Li,Elizabeth A Lunney,Ranjan J Rajapakse,Karen Siegel,Sergei L Timofeevski,Tianlun Wang,David M Wilhite.  (2009-03-31)  Synthesis and SAR of 4-substituted-2-aminopyrimidines as novel c-Jun N-terminal kinase (JNK) inhibitors..  Bioorganic & medicinal chemistry letters,  19  ((8)):  (2099-2102).  [PMID:19327989]
9. Nicholas R Perl,Nathan D Ide,Sudeep Prajapati,Hahdi H Perfect,Sergio G Durón,David Y Gin.  (2010-01-26)  Annulation of thioimidates and vinyl carbodiimides to prepare 2-aminopyrimidines, competent nucleophiles for intramolecular alkyne hydroamination. Synthesis of (-)-crambidine..  Journal of the American Chemical Society,  132  ((6)):  (1802-1803).  [PMID:20095555]
10. Jinho Lee,Kyoung-Hee Kim,Shinwu Jeong.  (2011-06-21)  Discovery of a novel class of 2-aminopyrimidines as CDK1 and CDK2 inhibitors..  Bioorganic & medicinal chemistry letters,  21  ((14)):  (4203-4205).  [PMID:21684737]
11. Erick A Lindsey,Roberta J Worthington,Cristina Alcaraz,Christian Melander.  (2012-02-04)  2-Aminopyrimidine as a novel scaffold for biofilm modulation..  Organic & biomolecular chemistry,  10  ((13)):  (2552-2561).  [PMID:22301774]
12. Rajani Giridhar,Riyaj S Tamboli,R Ramajayam,Dhaval G Prajapati,M R Yadav.  (2012-02-14)  Assessment of antiplatelet activity of 2-aminopyrimidines..  European journal of medicinal chemistry,  50  ():  (428-432).  [PMID:22326145]
13. Kamaljit Singh,Hardeep Kaur,Kelly Chibale,Jan Balzarini,Susan Little,Prasad V Bharatam.  (2012-03-31)  2-Aminopyrimidine based 4-aminoquinoline anti-plasmodial agents. Synthesis, biological activity, structure-activity relationship and mode of action studies..  European journal of medicinal chemistry,  52  ():  (82-97).  [PMID:22459876]
14. N Prabavathi,A Nilufer,V Krishnakumar,L Akilandeswari.  (2012-06-12)  Spectroscopic, electronic structure and natural bond analysis of 2-aminopyrimidine and 4-aminopyrazolo[3,4-d]pyrimidine: a comparative study..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  96  ():  (226-241).  [PMID:22683558]
15. Maya Tutughamiarso,Guido Wagner,Ernst Egert.  (2012-07-20)  Cocrystals of 5-fluorocytosine. I. Coformers with fixed hydrogen-bonding sites..  Acta crystallographica. Section B, Structural science,  68  ((Pt 4)):  (431-443).  [PMID:22810913]
16. Andrej Pevec,.  (2015-06-19)  Synthesis and Structural Study of Some Pyrimidinium Hexafluoridosilicates..  Acta chimica Slovenica,  62  ((2)):  ( 297-303 ).  [PMID:26085410]
17. Teodor Silviu Balaban,Richard Goddard,Myriam Linke-Schaetzel,Jean-Marie Lehn.  (2003-04-03)  2-Aminopyrimidine directed self-assembly of zinc porphyrins containing bulky 3,5-di-tert-butylphenyl groups..  Journal of the American Chemical Society,  125  ((14)):  (4233-4239).  [PMID:12670245]
18. A A?tmambetov,Z Menlimuratova.  (2003-04-24)  [Interaction of synthetic analogues of natural chalcones and flavones with guanidine]..  Bioorganicheskaia khimiia,  29  ((2)):  (198-199).  [PMID:12708320]
19. Rogier A Smits,Rob Leurs,Iwan J P de Esch.  (2009-05-30)  Major advances in the development of histamine H4 receptor ligands..  Drug discovery today,  14  ((15-16)):  (745-753).  [PMID:19477292]
20. Miguel Angel Vilchis-Reyes,Alejandro Zentella,Miguel Angel Martínez-Urbina,Angel Guzmán,Omar Vargas,María Teresa Ramírez Apan,José Luis Ventura Gallegos,Eduardo Díaz.  (2009-11-03)  Synthesis and cytotoxic activity of 2-methylimidazo[1,2-a]pyridine- and quinoline-substituted 2-aminopyrimidine derivatives..  European journal of medicinal chemistry,  45  ((1)):  (379-386).  [PMID:19879023]
21. Markus K Dahlgren,Christopher T Oberg,Erika A Wallin,P?r G Janson,Mikael Elofsson.  (2010-07-27)  Synthesis of 2-(2-aminopyrimidine)-2,2-difluoroethanols as potential bioisosters of salicylidene acylhydrazides..  Molecules (Basel, Switzerland),  15  ((6)):  (4423-4438).  [PMID:20657451]
22. Xusheng Wang,Hongdeng Qiu,Xia Liu,Shengxiang Jiang.  (2011-06-11)  [Separation of bases, phenols and pharmaceuticals on ionic liquid-modified silica stationary phase with pure water as mobile phase]..  Se pu = Chinese journal of chromatography,  29  ((3)):  (269-272).  [PMID:21657060]
23. Nimisha Singh,Sarvesh Kumar Pandey,Namrata Anand,Richa Dwivedi,Shyam Singh,Sudhir Kumar Sinha,Vinita Chaturvedi,Natasa Jaiswal,Arvind Kumar Srivastava,Priyanka Shah,M Imran Siddiqui,Rama Pati Tripathi.  (2011-07-09)  Synthesis, molecular modeling and bio-evaluation of cycloalkyl fused 2-aminopyrimidines as antitubercular and antidiabetic agents..  Bioorganic & medicinal chemistry letters,  21  ((15)):  (4404-4408).  [PMID:21737274]
24. Namrata Anand,Priyanka Singh,Anindra Sharma,Sameer Tiwari,Vandana Singh,Diwakar K Singh,Kishore K Srivastava,B N Singh,Rama Pati Tripathi.  (2012-08-03)  Synthesis and evaluation of small libraries of triazolylmethoxy chalcones, flavanones and 2-aminopyrimidines as inhibitors of mycobacterial FAS-II and PknG..  Bioorganic & medicinal chemistry,  20  ((17)):  (5150-5163).  [PMID:22854194]
25. Sabine Schultes,Harald Engelhardt,Luc Roumen,Obbe P Zuiderveld,Eric E J Haaksma,Iwan J P de Esch,Rob Leurs,Chris de Graaf.  (2012-11-20)  Combining quantum mechanical ligand conformation analysis and protein modeling to elucidate GPCR-ligand binding modes..  ChemMedChem,  8  ((1)):  (49-53).  [PMID:23161844]
26. Manishkumar D Joshi,Tianhao Li,Qiqing Zhong,Jared L Anderson.  (2013-08-21)  Using glucaminium-based ionic liquids for improving the separation of 2-aminopyrimidine-5-ylboronic acid and its pinacol ester by high performance liquid chromatography..  Journal of chromatography. A,  1308  ():  (161-165).  [PMID:23958694]
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