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9-蒽醇

规格或纯度: 98%

CAS编号: 1468-95-7
分子式: C₁₅H₁₂O
分子量: 208.26
Beilstein号: 1873402
EC号: 215-998-5
MDL号: MFCD00001264
PubChem编号: 73848

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货号 (SKU)	包装规格	是否现货	价格	数量
A101362-5g	5g	现货
A101362-10g	10g	现货
A101362-25g	25g	现货
A101362-50g	50g	现货
A101362-100g	100g	现货
A101362-250g	250g	现货

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含氧化合物蒽类

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基本描述

规格或纯度	98%
英文名称	9-Anthracenemethanol
别名	9-蒽甲醇；9-(羟甲基)蒽
英文别名	9-(Hydroxymethyl)anthracene; 9-Anthracenemethanol
应用	9-Anthracenemethanol was used in the preparation of 9-anthracenylmethyl-1-piperazinecarboxylate
运输条件	常规运输
产品介绍	应用 9-蒽甲醇可用于：作为制备9-蒽甲基-1-哌嗪羧酸酯的起始原料，充当HPLC测定异氰酸酯的试剂。 Diels-Alder 反应,与二甲基乙炔-二羧酸酯反应生成内酯衍生物。作为δ-戊内酯开环聚合反应引发剂，合成聚（(δ-戊内酯)。作为合成聚合物载体蒽的起始材料，在环加成反应中充当亲二烯体清除剂。 9-Anthracenemethanol participates in ring-opening polymerization of L-lactide catalyzed by alumoxane. It undergoes proton exchange reaction with potassium tert-butoxide to yield potassium 9-anthracenemethoxide 9-Anthracenemethanol was used in the preparation of 9-anthracenylmethyl-1-piperazinecarboxylate

名称和标识符

EC号	215-998-5
IUPAC Name	anthracen-9-ylmethanol
INCHI	InChI=1S/C15H12O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9,16H,10H2
InChi Key	JCJNNHDZTLRSGN-UHFFFAOYSA-N
Canonical SMILES	C1=CC=C2C(=C1)C=C3C=CC=CC3=C2CO
分子式	C₁₅H₁₂O
PubChem CID	73848
Beilstein号	1873402
分子量	208.26

化学和物理性质

溶解性	Soluble in hot methanol very faint turbidity.Insoluble in water
密度	1.214
熔点	158-164°C

安全信息

象形图	Health Hazard Harmful
信号词	Warning
危险声明	H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation H341: Suspected of causing genetic defects H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled
预防措施声明	P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P281,P271,P270,P304+P340,P403+P233,P362+P364,P330,P203,P264+P265,P301+P317,P318,P317,P337+P317,P332+P317,P319
WGK Germany	3
个人防护装备	Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter

参考文献

1. C E Cerniglia,W L Campbell,P P Fu,J P Freeman,F E Evans. (1990-03-01) Stereoselective fungal metabolism of methylated anthracenes.. Applied and environmental microbiology, 56 ((3)): (661-668). [PMID:2317041]
2. A Czich,I Bartsch,S Dogra,S Hornhardt,H R Glatt. (1994-06-01) Stable heterologous expression of hydroxysteroid sulphotransferase in Chinese hamster V79 cells and their use for toxicological investigations.. Chemico-biological interactions, 92 ((1-3)): (119-128). [PMID:8033247]
3. H Glatt,K Pauly,A Piée-Staffa,A Seidel,S Hornhardt,A Czich. (1994-06-01) Activation of promutagens by endogenous and heterologous sulfotransferases expressed in continuous cell cultures.. Toxicology letters, 72 ((1-3)): (13-21). [PMID:8202924]
4. L S Von Tungeln,P P Fu. (1986-07-01) Stereoselective metabolism of 9-methyl-, 9-hydroxymethyl- and 9,10-dimethylanthracenes: absolute configurations and optical purities of trans-dihydrodiol metabolites.. Carcinogenesis, 7 ((7)): (1135-1141). [PMID:3719909]
5. Yasuhiro Ando,Yusuke Haba,Kazutaka Soma,Yuko Hiraoka,Tetsuya Takatsu. (2007-08-19) Rapid preparation of fluorescent 9-anthrylmethyl esters for fatty acid analysis of small amount of triacylglycerols.. Lipids, 42 ((10)): (955-960). [PMID:17694342]
6. Dipak Samanta,Sandip Mukherjee,Yogesh P Patil,Partha Sarathi Mukherjee. (2012-08-18) Self-assembled Pd6 open cage with triimidazole walls and the use of its confined nanospace for catalytic Knoevenagel- and Diels-Alder reactions in aqueous medium.. Chemistry (Weinheim an der Bergstrasse, Germany), 18 ((39)): (12322-12329). [PMID:22899180]
7. Shuang Bai,Meili Hou,Xiaoxiao Shi,Jiucun Chen,Xiaoqian Ma,Yong-E Gao,Yajun Wang,Peng Xue,Yuejun Kang,Zhigang Xu. (2018-05-19) Reduction-active polymeric prodrug micelles based on α-cyclodextrin polyrotaxanes for triggered drug release and enhanced cancer therapy.. Carbohydrate polymers, 193 (): (153-162). [PMID:29773367]
8. Alok Kumar Tripathi,Sushma Kundu,Ranjan Das. (2018-12-06) Distance-dependent formation of electronic charge-transfer states in the ground states of anthracene and pyrene covalently linked to a TEMPO free radical.. Physical chemistry chemical physics : PCCP, 21 ((1)): (77-88). [PMID:30515493]
9. J W Flesher,J Horn,A F Lehner. (1998-10-29) 9-Sulfooxymethylanthracene is an ultimate electrophilic and carcinogenic form of 9-hydroxymethylanthracene.. Biochemical and biophysical research communications, 251 ((1)): (239-243). [PMID:9790938]
10. Chen-Yu Li,Chen-Yen Tsai,Chia-Her Lin,Bao-Tsan Ko. (2011-02-02) Synthesis, structural characterization and reactivity of aluminium complexes supported by benzotriazole phenoxide ligands: air-stable alumoxane as an efficient catalyst for ring-opening polymerization of L-lactide.. Dalton transactions (Cambridge, England : 2003), 40 ((9)): (1880-1887). [PMID:21283858]
11. Shanshan Kou,Hu Zhou,Guodong Tang,Rongqing Li,Yu Zhang,Jianying Zhao,Changmei Wei. (2012-08-14) Experimental and DFT studies on the vibrational and electronic spectra of 9-anthracenemethanol.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 96 (): (768-775). [PMID:22885894]
12. Tamuka Chidanguro,Danielle R Blank,Alexandra Garrett,Cassandra M Reese,Jacob M Schekman,Xinjun Yu,Derek L Patton,Neil Ayres,Yoan C Simon. (2018-06-23) Fabrication of single-chain nanoparticles through the dimerization of pendant anthracene groups via photochemical upconversion.. Dalton transactions (Cambridge, England : 2003), 47 ((26)): (8663-8669). [PMID:29931004]
13. Patrick Morkus,Mehdi Zolfaghari,Salman Alizadeh Kordkandi,Jake Nease,Carlos D M Filipe,David R Latulippe. (2019-12-04) A Rapid Assay to Assess Nitrification Inhibition Using a Panel of Bacterial Strains and Partial Least Squares Modeling.. Environmental science & technology, 54 ((1)): (184-194). [PMID:31790215]

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